Molecular Theory of Electric Double Layers PDF Download
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Author: Dimiter Nikolov Petsev
Publisher:
ISBN: 9780750322768
Category : Electric double layer
Languages : en
Pages : 0
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Book Description
The electrical double layer describes charge and potential distributions that form at the interface between electrolyte solutions and the surface of an object, and they play a fundamental role in chemical and electrochemical behaviour. Colloid science, electrochemistry, material science, and biology are a few examples where such interfaces play a crucial role. The focus of this book is on the application of modern liquid state theories to the properties of electric double layers, where it demonstrates the ability of statistical mechanical approaches, such as the classical density functional theory, to provide insights and details that will enable a better and more quantitative understanding of electric double layers. The book will be essential reading for advanced students and researchers in interfacial science and its numerous applications.
Author: Dimiter Nikolov Petsev
Publisher:
ISBN: 9780750322768
Category : Electric double layer
Languages : en
Pages : 0
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Book Description
The electrical double layer describes charge and potential distributions that form at the interface between electrolyte solutions and the surface of an object, and they play a fundamental role in chemical and electrochemical behaviour. Colloid science, electrochemistry, material science, and biology are a few examples where such interfaces play a crucial role. The focus of this book is on the application of modern liquid state theories to the properties of electric double layers, where it demonstrates the ability of statistical mechanical approaches, such as the classical density functional theory, to provide insights and details that will enable a better and more quantitative understanding of electric double layers. The book will be essential reading for advanced students and researchers in interfacial science and its numerous applications.
Author: Zi-Xiang Tang
Publisher:
ISBN:
Category :
Languages : en
Pages : 452
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Book Description
Author: Wolfgang Schmickler
Publisher: Springer Science & Business Media
ISBN: 3642049370
Category : Science
Languages : en
Pages : 273
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Book Description
Electrochemistry is an old branch of physical chemistry. Due to the development of surface sensitive techniques, and a technological interest in fuel cells and batteries, it has recently undergone a rapid development. This textbook treats the field from a modern, atomistic point of view while integrating the older, macroscopic concepts. The increasing role of theory is reflected in the presentation of the basic ideas in a way that should appeal to experimentalists and theorists alike. Special care is taken to make the subject comprehensible to scientists from neighboring disciplines, especially from surface science. The book is suitable for an advanced course at the master or Ph.D. level, but should also be useful for practicing electrochemists, as well as to any scientist who wants to understand modern electrochemistry.
Author: Qing Chang
Publisher: Academic Press
ISBN: 0128093196
Category : Technology & Engineering
Languages : en
Pages : 278
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Book Description
Colloid and Interface Chemistry for Water Quality Control provides basic but essential knowledge of colloid and interface science for water and wastewater treatment. Divided into two sections, chapters 1 to 8 presents colloid chemistry including simple history and basic concepts, diffusion and Brown Motion, sedimentation, osmotic pressure, optical properties, rheology properties, electric properties, emulsion, foam and gel, and so on; chapters 9 to provides interface chemistry theories including the surface of liquid, the surface of solution, and the surface of solid. This valuable book is the only one that presents colloid and interface chemistry from the water quality control perspective. This book was written for graduate students in the area of water treatment and environmental engineering, and it could be used as the reference for researchers and engineers in the same area. - Concise content makes this suitable for both teaching and learning - Focuses on water treatment technology and methods, links colloid and surface chemistry to water treatment applications - Not only addresses all the important physical-chemistry principles and theories, but also presents new developed knowledge on water treatment - Includes exercises, problems and solutions, which are very helpful for testing learning and understanding
Author: Marko M. Melander
Publisher: John Wiley & Sons
ISBN: 1119605636
Category : Science
Languages : en
Pages : 372
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Book Description
Atomic-Scale Modelling of Electrochemical Systems A comprehensive overview of atomistic computational electrochemistry, discussing methods, implementation, and state-of-the-art applications in the field The first book to review state-of-the-art computational and theoretical methods for modelling, understanding, and predicting the properties of electrochemical interfaces. This book presents a detailed description of the current methods, their background, limitations, and use for addressing the electrochemical interface and reactions. It also highlights several applications in electrocatalysis and electrochemistry. Atomic-Scale Modelling of Electrochemical Systems discusses different ways of including the electrode potential in the computational setup and fixed potential calculations within the framework of grand canonical density functional theory. It examines classical and quantum mechanical models for the solid-liquid interface and formation of an electrochemical double-layer using molecular dynamics and/or continuum descriptions. A thermodynamic description of the interface and reactions taking place at the interface as a function of the electrode potential is provided, as are novel ways to describe rates of heterogeneous electron transfer, proton-coupled electron transfer, and other electrocatalytic reactions. The book also covers multiscale modelling, where atomic level information is used for predicting experimental observables to enable direct comparison with experiments, to rationalize experimental results, and to predict the following electrochemical performance. Uniquely explains how to understand, predict, and optimize the properties and reactivity of electrochemical interfaces starting from the atomic scale Uses an engaging “tutorial style” presentation, highlighting a solid physicochemical background, computational implementation, and applications for different methods, including merits and limitations Bridges the gap between experimental electrochemistry and computational atomistic modelling Written by a team of experts within the field of computational electrochemistry and the wider computational condensed matter community, this book serves as an introduction to the subject for readers entering the field of atom-level electrochemical modeling, while also serving as an invaluable reference for advanced practitioners already working in the field.
Author: Lloyd L Lee
Publisher: World Scientific
ISBN: 9811233012
Category : Technology & Engineering
Languages : en
Pages : 295
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Book Description
Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.
Author: Fritz Scholz
Publisher: Springer
ISBN: 3662047578
Category : Science
Languages : en
Pages : 343
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Book Description
This laboratory book delivers hands-on advice to researchers in all fields of life and physical sciences already applying or intending to apply electro-analytical methods in their research. The authors represent in a strictly practice-oriented manner not only the necessary theoretical background but also substantial know-how on measurement techniques, interpretation of data, experimental setup and trouble shooting. The author and the editor are well-known specialists in their field.
Author: Konrad Bach
Publisher: Springer Science & Business Media
ISBN: 1468481452
Category : Science
Languages : en
Pages : 318
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Book Description
A number of apparently unrelated phenomena in biological systems (e.g., biopolymer aggregation, cell-cell interactions, ion transport across membranes) arise from the special properties of charged surfaces. A sym posium entitled "Electrical Double Layers in Biology", which took place at the Toronto meeting of the Electrochemical Society, 12-17 May 1985, focused on the common features of these phenomena. The papers presented at that symposium are collected here and they illustrate ways in which an under standing of electrical double layers can elucidate a problem in Biology. An example of this approach can be seen from the paper I presented on ion transport and excitation, where the "unusual" ion flows during nerve excitation are actually expected if one includes the effects of electrical double layers at membrane surfaces. Furthermore, the selectivity of the ion channels in these membranes can be better understood on this basis. Other presentations account for such observations as the changes in spacing between muscle proteins during contraction, the interactions of red cells to form rouleaux, the electrical properties of algal cell membranes, electrokinetic potentials during blood flow in arteries, etc. I trust that these papers will indicate the value of electrochemistry in the study of biological systems, an area of research usually called Bioelectrochemistry, and will encourage biologists to use these ideas when approaching related problems.
Author: G. A. Martynov
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 188
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Book Description
Author: Henk N.W. Lekkerkerker
Publisher: Springer Science & Business Media
ISBN: 9400712227
Category : Science
Languages : en
Pages : 245
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Book Description
Colloids are submicron particles that are ubiquitous in nature (milk, clay, blood) and industrial products (paints, drilling fluids, food). In recent decades it has become clear that adding depletants such as polymers or small colloids to colloidal dispersions allows one to tune the interactions between the colloids and in this way control the stability, structure and rheological properties of colloidal dispersions. This book offers a concise introduction to the fundamentals of depletion effects and their influence on the phase behavior of colloidal dispersions. Throughout the book, conceptual explanations are accompanied by experimental and computer simulation results. From the review by Kurt Binder: "They have succeeded in writing a monograph that is a very well balanced compromise between a very pedagogic introduction, suitable for students and other newcomers, and reviews of the advanced research trends in the field. Thus each chapter contains many and up to date references, but in the initial sections of the chapters, there are suggested exercises which will help the interested reader to recapitulate the main points of the treatment and to deepen his understanding of the subject. Only elementary knowledge of statistical thermodynamics is needed as a background for understanding the derivations presented in this book; thus this text is suitable also for advanced teaching purposes, useful of courses which deal with the physics for soft condensed matter. There does not yet exist any other book with a similar scope..... The readability of this book is furthermore enhanced by a list of symbols, and index of keywords, and last not least by a large number of figures, including many pedagogic sketches which were specifically prepared for this book. Thus, this book promises to be very useful for students and related applied sciences alike." Eur. Phys. J. E (2015) 38: 73
