Modern Ylide Chemistry PDF Download
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Author: Viktoria H. Gessner
Publisher: Springer
ISBN: 3319895451
Category : Science
Languages : en
Pages : 167
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Book Description
This volume covers recent advances in the chemistry of ylidic compounds with focus on their application in the design of ligands with unique donor properties, the development of novel organic transformations as well as the use of ylides in homogenous catalysis. Thereby, this volume particularly aims at the community of organic and organometallic chemists engaged in synthetic chemistry and catalysis as well as in the use of special ligands for the stabilization of unusual main group element species and the “transition-metal free” activation of element-element/hydrogen bonds. These fields of research are highly active and vivid research areas to which ylide chemistry has only recently started to contribute, but has already led to fascinating developments in most different directions. This volume highlights these recent developments, thus giving not only an overview over the past achievements, but also possibilities for future applications. To this end, the chapters selected in this volume combine different aspects of ylide chemistry, starting with theoretical aspects in ligand design followed by synthetic organic methods, catalytic transformations and complex chemistry.
Author: Viktoria H. Gessner
Publisher: Springer
ISBN: 3319895451
Category : Science
Languages : en
Pages : 167
Get Book Here
Book Description
This volume covers recent advances in the chemistry of ylidic compounds with focus on their application in the design of ligands with unique donor properties, the development of novel organic transformations as well as the use of ylides in homogenous catalysis. Thereby, this volume particularly aims at the community of organic and organometallic chemists engaged in synthetic chemistry and catalysis as well as in the use of special ligands for the stabilization of unusual main group element species and the “transition-metal free” activation of element-element/hydrogen bonds. These fields of research are highly active and vivid research areas to which ylide chemistry has only recently started to contribute, but has already led to fascinating developments in most different directions. This volume highlights these recent developments, thus giving not only an overview over the past achievements, but also possibilities for future applications. To this end, the chapters selected in this volume combine different aspects of ylide chemistry, starting with theoretical aspects in ligand design followed by synthetic organic methods, catalytic transformations and complex chemistry.
Author: Julio Alvarez-Builla
Publisher: John Wiley & Sons
ISBN: 3527332014
Category : Science
Languages : en
Pages : 2531
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Book Description
Eine Fülle von Information zum attraktiven Preis bietet Ihnen dieses vierbändige Handbuch der Heterocyclenchemie.
Author: Michael P. Doyle
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 680
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Book Description
This much-needed resource brings together a wealth of procedures for the synthesis and practical use of diazocarbonyl compounds. It features methods for the preparation of important catalysts and for applications of diazocarbonyl compounds within each of the main transformation categories-including in-depth coverage of cyclopropanation, C-H and X-H insertion, Wolff rearrangement, ylide formation, aromatic cycloaddition and substitution, and many other useful reactions. Written by leading experts in the field, this book contains cutting-edge material on highly enantioselective transformations, and presents new ways of thinking about diazocarbonyl compounds and their applications, from donor-acceptor cyclopropanes in organic synthesis to macrocyclic cyclopropanation. Complete with illustrative examples of procedures in each chapter, clear diagrams, and a detailed bibliography, this practical reference gives readers the tools they need to put diazocarbonyl compounds to work for their own projects-an invaluable source of guidance for synthetic organic chemists, chemical scientists, and advanced students.
Author: Peer Kirsch
Publisher: John Wiley & Sons
ISBN: 3527651373
Category : Science
Languages : en
Pages : 457
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Book Description
The second edition of this classic reference work has been completely revised and updated, as well as being enlarged by 20% to reflect the latest developments in synthetic organic fluorine chemistry, taking into account new applications in materials science and medicinal chemistry. The new developments in transition-metal-catalyzed methods for the introduction of fluorine and fluorinated groups are discussed. In addition, new chapters have been added on such important applications as organic electronics (OLEDs) and fluorinated dyes. Appendices containing synthetic procedures and conversions round off this comprehensive work. This work is a valuable reference for fluorine chemists that also provides nonspecialists with an introduction to the field. From reviews of the first edition: ''... a well-produced book with attractive graphics, photos and schemes. Throughout the book, coloured electrostatic maps of small organofluorine compounds are used toillustrate charge distributions. These are effective as well as attractive. I would point any organic chemist to this book who wants to learn about and do some fluorine chemistry. It provides uncluttered descriptions and a clear orientation to the literature in this important area of the organic chemistry.'' CHEMBIOCHEM - A European Journal of Chemical Biology
Author: Carlo Gatti
Publisher: Springer Science & Business Media
ISBN: 9048138353
Category : Science
Languages : en
Pages : 800
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Book Description
Focusing on developments from the past 10-15 years, this volume presents an objective overview of the research in charge density analysis. The most promising methodologies are included, in addition to powerful interpretative tools and a survey of important areas of research.
Author: W. Carruthers
Publisher: Cambridge University Press
ISBN: 1107567459
Category : Political Science
Languages : en
Pages : 506
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Book Description
Textbook on modern methods of organic synthesis.
Author: Jie Jack Li
Publisher: OUP USA
ISBN: 0195187989
Category : Science
Languages : en
Pages : 219
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Book Description
1. FUNDAMENTAL TECHNIQUES. 2. FUNCTIONAL GROUP MANIPULATIONS. 3. OXIDATION. 4. REDUCTION. 5. CARBON-CARBON BOND FORMATION. 6. PROTECTING GROUPS.
Author: Vincent Porte
Publisher: American Chemical Society
ISBN: 0841299323
Category : Science
Languages : en
Pages : 167
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Book Description
In the vast landscape of organic chemistry, sulfur-containing compounds play a pivotal role in pharmaceuticals, industrial processes, and a wide range of chemical transformations, where they often enable selective and otherwise challenging functionalization reactions. This primer aims not only to elucidate the fundamental characteristics of sulfoxides and sulfur ylides but also to address key challenges encountered in their chemistry. By examining the influence of molecular structure on reactivity, the authors uncover valuable insights that underpin the utilization of these compounds. The Versatile Organic Chemistry of Sulfur(IV) is conceived as a precursor to our more extensive review, tailored to provide foundational knowledge for readers seeking entry into the more specialized material presented therein. The authors‘ goal for this primer is to equip both novices and seasoned practitioners with an understanding that transcends theoretical concepts, fostering an environment ripe for exploration and innovation.
Author: Robert A. Moss
Publisher: John Wiley & Sons
ISBN: 1118730267
Category : Science
Languages : en
Pages : 506
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Book Description
Presents the most innovative results in carbene chemistry, setting the foundation for new discoveries and applications The discovery of stable carbenes has reinvigorated carbene chemistry research, with investigators seeking to develop carbenes into new useful catalysts and ligands. Presenting the most innovative and promising areas of carbene research over the past decade, this book explores newly discovered structural, catalytic, and organometallic aspects of carbene chemistry, with an emphasis on new and emerging synthetic applications. Contemporary Carbene Chemistry features contributions from an international team of pioneering carbene chemistry researchers. Collectively, these authors have highlighted the most interesting and promising areas of investigation in the field. The book is divided into two parts: Part 1, Properties and Reactions of Carbenes, explores new findings on carbene stability, acid-base behavior, and catalysis. Carbenic structure and reactivity are examined in chapters dedicated to stable carbenes, carbodicarbenes, carbenes as guests in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited state precursors. Theoretical concerns are addressed in chapters on computational methods and dynamics applied to carbene reactions. Part 2, Metal Carbenes, is dedicated to the synthetic dimensions of carbenes, particularly the reactions and catalytic properties of metal carbenes. The authors discuss lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold. All the chapters conclude with a summary of the current situation, new challenges on the horizon, and promising new research directions. A list of key reviews and suggestions for further reading also accompanies every chapter. Each volume of the Wiley Series on Reactive Intermediates in Chemistry and Biology focuses on a specific reactive intermediate, offering a broad range of perspectives from leading experts that sets the stage for new applications and further discoveries.
Author: A. William Johnson
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 626
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Book Description
Provides overview of ylide and imine chemistry of phosphorous. Contains over 3,150 references. Focuses on their application, particularly in organic synthesis. Presents up-to-date understanding of structure, bonding and behavior of each type of ylide. Covers ylide preparations, handling and decomposition. Features theoretical descriptions of the bonding in ylides and the reactions of phosphorous ylides with transition metal compounds.
