Mixed-valence Complexes of Ruthenium and Osmium with 2, 7-Bis (2-pyridyl)-1, 8-naphthyridine ; Trischelated Complexes of Ruthenium with 2-(2-Pyridyl)-1, 8-naphthyridine and 5, 6-Dihydrodipyrido [2, 3-b: 3 ́, 2 ́-j]-1, 10-phenanthroline

Mixed-valence Complexes of Ruthenium and Osmium with 2, 7-Bis (2-pyridyl)-1, 8-naphthyridine ; Trischelated Complexes of Ruthenium with 2-(2-Pyridyl)-1, 8-naphthyridine and 5, 6-Dihydrodipyrido [2, 3-b: 3 ́, 2 ́-j]-1, 10-phenanthroline PDF Author: Elizabeth Binamira Soriaga
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Languages : en
Pages : 378

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Comprehensive Dissertation Index

Comprehensive Dissertation Index PDF Author:
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Category : Dissertations, Academic
Languages : en
Pages : 712

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Dissertation Abstracts International

Dissertation Abstracts International PDF Author:
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Category : Dissertations, Academic
Languages : en
Pages : 734

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American Doctoral Dissertations

American Doctoral Dissertations PDF Author:
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Category : Dissertation abstracts
Languages : en
Pages : 696

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Ruthenium and Osmium Polypyridyl Complexes for Light-emitting and Molecular Electronics Applications

Ruthenium and Osmium Polypyridyl Complexes for Light-emitting and Molecular Electronics Applications PDF Author: Samuel Flores-Torres
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ISBN: 9780542980848
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Languages : en
Pages : 164

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We have also prepared and characterized a series of multimetallic oligomers of Ru using the pi-conjugated bridging ligand tetra-2-pyridyl-1,4-pyrazine (tppz), as well as mixed-ligand complexes with terpyridine end-caps, and analyzed their electrochemical and spectroscopic properties, comparing them with modern computational electronic structure methods. The results suggest that the high degree of metal-metal inter-unit communication in these linear oligomers yields low HOMO-LUMO gaps, high delocalization, and the onset of "quasi-band" features, all indicative that these compounds should be excellent molecular wire materials.