Author: Nadja Wulff
Publisher: Cuvillier Verlag
ISBN: 373694909X
Category : Science
Languages : en
Pages : 167
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Book Description
In organic chemistry the simultaneous solubility of hydrophobic and hydrophilic reactants in a common solvent is an ubiquitous problem. Often either an expensive or a toxic solvent is needed. Alternatively, polar and non polar components are mixed into macroemulsions permitting them to react across the internal interface. However, macroemulsions display a comparatively small interfacial area. Thus, the reaction rate is low. Microemulsions feature an inherent vast interfacial area which facilitates significantly higher reaction rates. Furthermore, they allow a rather simple monitoring of the reaction kinetics by observing changes in the phase behavior. In this work the advantages of microemulsions as efficient reaction media for the photochemically induced Paternò Büchi reaction of pyruvic acid and 1 octene are elucidated. The amphiphilic reaction product 3 hexyl 2 methyloxetane 2 carboxylic acid influences the phase behavior of the microemulsion system significantly. With increasing UV exposure time the point of highest efficiency was shifted to lower temperatures and, interestingly, an increase of efficiency was detected. Hence, the newly created amphiphile acts as an efficient, hydrophobic cosurfactant. Additionally, with small angle neutron scattering and freeze fracture electron microscopy it was shown that the bicontinuous microstructure survives the UV irradiation. Another route towards green organic chemistry was opened by characterization of two new sustainable biosurfactants (mannosylerythritollipids (MEL) and cellobioselipids (CL)) in microemulsions.
Author: Jean-Philippe Goddard
Publisher: John Wiley & Sons
ISBN: 111969504X
Category : Science
Languages : en
Pages : 167
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Book Description
Biphasic Chemistry and The Solvent Case examines recent improvements in reaction conditions, in order to affirm the role of chemistry in the sustainable field. This book shows that those who work within the chemistry industry support limits for the use of toxic or flammable solvents, since it reduces the purifications to simple filtrations. Thanks to commercial scavengers, solid phase syntheses are now available to all. Fluorine biphasic catalysis enables extremely efficient catalyst recycling and has a high applicability potential at the industrial level. This book also reviews the many studies that have shown that water is a solvent of choice for most synthetic reactions. Particular traits can be obtained and the effects on thermodynamics make it possible to operate at lower temperatures, thereby achieving energy savings. Finally the great diversity of application of the reactions without solvents is illustrated.
Author: Masayoshi Okubo
Publisher: Springer Science & Business Media
ISBN: 9783540229230
Category : Technology & Engineering
Languages : en
Pages : 388
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Book Description
In this special volume on polymer particles, recent trends and developments in the synthesis of nano- to micron-sized polymer particles by radical polymerization (Emulsion, Miniemulsion, Microemulsion, and Dispersion Polymerizations) of vinyl monomers in environmentally friendly heterogeneous aqueous and supercritical carbon dioxide fluid media are reviewed by prominent worldwide researchers. In addition to the important challenges and possibilities with regards to design and preparation of functionalized polymer particles of controlled size, the topics described are of great current interest due to the increased awareness of environmental issues.
Author: Brian D. Ross
Publisher: Academic Press
ISBN: 0128163879
Category : Science
Languages : en
Pages : 1872
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Book Description
The detection and measurement of the dynamic regulation and interactions of cells and proteins within the living cell are critical to the understanding of cellular biology and pathophysiology. The multidisciplinary field of molecular imaging of living subjects continues to expand with dramatic advances in chemistry, molecular biology, therapeutics, engineering, medical physics and biomedical applications. Molecular Imaging: Principles and Practice, Volumes 1 and 2, Second Edition provides the first point of entry for physicians, scientists, and practitioners. This authoritative reference book provides a comprehensible overview along with in-depth presentation of molecular imaging concepts, technologies and applications making it the foremost source for both established and new investigators, collaborators, students and anyone interested in this exciting and important field. - The most authoritative and comprehensive resource available in the molecular-imaging field, written by over 170 of the leading scientists from around the world who have evaluated and summarized the most important methods, principles, technologies and data - Concepts illustrated with over 600 color figures and molecular-imaging examples - Chapters/topics include, artificial intelligence and machine learning, use of online social media, virtual and augmented reality, optogenetics, FDA regulatory process of imaging agents and devices, emerging instrumentation, MR elastography, MR fingerprinting, operational radiation safety, multiscale imaging and uses in drug development - This edition is packed with innovative science, including theranostics, light sheet fluorescence microscopy, (LSFM), mass spectrometry imaging, combining in vitro and in vivo diagnostics, Raman imaging, along with molecular and functional imaging applications - Valuable applications of molecular imaging in pediatrics, oncology, autoimmune, cardiovascular and CNS diseases are also presented - This resource helps integrate diverse multidisciplinary concepts associated with molecular imaging to provide readers with an improved understanding of current and future applications
Author: George Wheeler
Publisher: Getty Publications
ISBN: 0892368152
Category : Alkoxysilanes
Languages : en
Pages : 215
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Book Description
Stone is one of the oldest building materials, and its conservation ranks as one of the most challenging in the field. The use of alkoxysilanes in the conservation of stone can be traced as far back as 1861, when A. W. von Hoffman suggested their use for the deteriorating limestone on the Houses of Parliament in London. Alkoxysilane-based formulations have since become the material of choice for the consolidation of stone outdoors.^l This volume, the first to cover comprehensively alkoxysilanes in stone consolidation, synthesizes the subject's vast and extensive literature, which ranges from production of alkoxysilanes in the nineteenth century to the extensive contributions from sol-gel science in the 1980s and 90s. Included are a historical overview, an annotated bibliography, and discussions of the following topics: the chemistry and physics of alkoxysilanes and their gels; the influence of stone type; commercial and noncommercial formulations; practice; lab and field evaluation of service life; and recent developments. This book is designed for conservators, scientists, and preservation architects in the field of stone conservation and will also serve as an indispensable introduction to the subject for students of art conservation and historic preservation.
Author: Dimiter N. Petsev
Publisher: Elsevier
ISBN: 0080472656
Category : Science
Languages : en
Pages : 781
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Book Description
Emulsions: Structure, Stability and Interactions is the perfect handbook for scientists looking to obtain up-to-date knowledge about the fundamentals of emulsion science, and those looking to familiarize themselves with the subject in greater detail. As a 'stand-alone' source of information, it is also ideal for solving the practical issues encountered daily in the field of emulsion science. While each chapter presents a concise review on a specific topic, the book offers a consistent presentation of the important physical concepts relevant to emulsions. Some of the topics covered include statistical mechanics of fluid interfaces, the structure of fluid interfaces determined by neutron scattering, hydrodynamic interactions and stability of emulsion films, theory of emulsion flocculation, coalescence kinetics of Brownian emulsions, and Brownian dynamics simulation of emulsion stability. - Full and comprehensive presentations - Rigorous approach to each topic, providing in-depth information - Acts as a 'stand-alone' source of information
Author: Grégorio Crini
Publisher: Springer
ISBN: 3319921118
Category : Science
Languages : en
Pages : 395
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Book Description
This is the first volume on adsorption using green adsorbents and is written by international contributors who are the leading experts in the adsorption field. The first volume provides an overview of fundamentals and design of adsorption processes. For people who are new to the field, the book starts by two overview chapters presenting the principles and properties of wastewater treatment and adsorption processes. The book also provides a comprehensive source of knowledge on acid-base properties of biosorbents. It discusses fractal-like kinetic models for fluid-solid adsorption, reports on the chemical characterization of oxidized activated carbons for metal removal, and the use of magnetic biosorbents in water treatment. Furthermore, the thermodynamic properties of metals adsorption by green adsorbents, and biosorption of polycyclic aromatic hydrocarbons and organic pollutants are reviewed, and finally the recent trends and impact of nanomaterials as green adsorbent and potential catalysts for environmental applications are summarized. The audience for this book includes students, environmentalists, engineers, water scientists, civil and industrial personnel who wish to specialize in adsorption technology. Academically, this book will be of use to students in chemical and environmental engineering who wish to learn about adsorption and its fundamentals. It has also been compiled for practicing engineers who wish to know about recent developments on adsorbent materials in order to promote further research toward improving and developing newer adsorbents and processes for the efficient removal of pollutants from industrial effluents. It is hoped that the book will serve as a readable and useful presentation not only for undergraduate and postgraduate students but also for the water scientists and engineers and as a convenient reference handbook in the form of numerous recent examples and appended information.
Author: Teofil Jesionowski
Publisher: MDPI
ISBN: 3039213970
Category : Science
Languages : en
Pages : 204
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Book Description
The book deals with novel aspects and perspectives in metal oxide and hybrid material fabrication. The contributions are mainly focused on the search for a new group of advanced materials with designed physicochemical properties, especially an expanded porous structure and defined surface activity. The proposed technological procedures result in an enhanced activity of the synthesized hybrid materials, which is of great importance when considering their potential fields of application. The use of such materials in different technological disciplines, including aspects associated with environmental protection, allows for the verification of the proposed synthesis method. Thus, it can be stated that those aspects are of interdisciplinary character and may be located at the interface of three scientific disciplines—chemistry, materials science, and engineering—as well as environmental protection. Furthermore, the presented scientific scope is in some way an answer to the continuous demand for such types of materials and opens new perspectives for their practical use
Author: William M. Nelson
Publisher: Oxford University Press
ISBN: 0198035764
Category : Science
Languages : en
Pages : 402
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Book Description
The aim of this book is to introduce the use of green solvents throughout chemistry and to provide a comprehensive reference for solvents currently applicable in green chemistry. The first section covers solvents in chemical perspective, and the second section is a guide to green solvents. Overall, this volume defines characteristics of green solvents and their current usage, and explores their importance ecologically and economically. It includes a full range of commercial, industrial, and academic green solvents, and discusses solvents in specific commercial and non-commercial practices. Green Solvents for Chemistry differs from other works on solvents in that only solvents for green chemistry are included along with their chemical properties and toxicological issues.
Author: John A. Gladysz
Publisher: John Wiley & Sons
ISBN: 3527604499
Category : Science
Languages : de
Pages : 624
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Book Description
Edited by the leading experts John Gladysz, Dennis Curran, and István Horváth, this handbook is the first to summarize all the essential aspects of this emerging field of chemistry. Whether the reader is seeking an introduction to the concept of fluorous biphase catalysis, summaries of partition coefficients involving fluorous and organic solvents, or information on the latest fluorous mixture separation techniques, this authoritative compilation of contributions, written by the world's top authors, provides key information needed for successfully working with the diverse and fascinating families of fluorous molecules. The large number of reliable experimental procedures in particular makes this the ideal guide for newcomers wanting to use this elegant method in the laboratory. In addition, experts will also find a wealth of important information concisely contained in one ready reference. The result is an indispensable resource for everyone currently working or intending to work in this field.
