Methodologies and Studies Directed Toward the Total Synthesis of Cucurbitacin I PDF Download
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Author: Nicholas A. Eddy
Publisher:
ISBN:
Category :
Languages : en
Pages : 418
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Book Description
Author: Nicholas A. Eddy
Publisher:
ISBN:
Category :
Languages : en
Pages : 418
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Author: Kendra D. Carter
Publisher:
ISBN:
Category :
Languages : en
Pages : 434
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Author: Thomas Elliott Jacks
Publisher:
ISBN:
Category :
Languages : en
Pages : 406
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Author: Spiros I. Liras
Publisher:
ISBN:
Category :
Languages : en
Pages : 268
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Author: Donna Denyse Johnson
Publisher:
ISBN:
Category : Cyclic peptides
Languages : en
Pages : 336
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Author: Qunying Dai
Publisher:
ISBN:
Category :
Languages : en
Pages : 120
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Book Description
Organic synthesis is one of the most challenging fields of chemistry while natural product synthesis is the most appealing field of organic synthesis. The purpose of this research was to develop efficient synthesis of natural products or molecules that mimic natural products with biological activities beneficial to human beings. The first chapter covered a direct synthesis approach to a potential anticoccidial compound. It was achieved by electrophilic substitution of 2,3,4-thibromobut-2-en-4-olide to 1,4-dimethoxynaphthalene as the key step. Following ceric ammonium nitrate oxidation got the desired 2-(3,4-dibromo-5-oxo-2,5-dihydrofuran-2-yl)-1,4-naphthoquinone. In the second chapter, we developed a new methodology of forming two new carbon-carbon bond using [(phenyisulfonyl)-methylene]dilithium. A number of 1,4 and, 5-dicarbonyl compounds reacted with the sulfonyl-stabilized dianion and led to the corresponding fused bicyclic compounds. This new route promises to open up an entirely new approach to the total synthesis of glycinoeclapin A. The third chapter covered the study toward the total synthesis of eleutherobin. We developed a direct synthetic approach to the skeleton of eleutherobin from a commercial available keton, 6-methyl-5-hepen-2-one. It was achieved in six steps. This pathway can enable medicinal researchers to synthesize diverse analogs of eleutherobin.
Author: Benjamin Eric Blass
Publisher:
ISBN:
Category :
Languages : en
Pages : 490
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Author: Steven P. Seitz
Publisher:
ISBN:
Category :
Languages : en
Pages : 547
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Author: Ronald Isamu Sato
Publisher:
ISBN:
Category :
Languages : en
Pages : 234
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Author: John ApSimon
Publisher: Wiley-Interscience
ISBN: 9780471032519
Category : Science
Languages : en
Pages : 624
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Book Description
Each volume reviews the total synthesis of a set of compounds looking at syntheses reported historically and at the practice current at the time of publication. From volume 1 focusing on carbohydrates, prostagladins, nucleic acids, antibiotics, naturally occurring oxygen ring compounds and pyrrole pigments, the series continues with coverage of aromatic steroids, monoterpenes, triterpenes, sesquiterpenes, cannabinoids, natural inophores, insect pheromones and alkaloids. Volumes revisit the total synthesis of key compounds such as carbohydrates, nucleic acids and pyrrole pigments several times during the series building a picture of the historic development of total synthesis techniques for these major groups. Chapters are edited by experts in their field to give a complete overview of the best in the field at the time.
