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Author: George M. Benedikt
Publisher: Cambridge University Press
ISBN: 0080950426
Category : Science
Languages : en
Pages : 398
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Book Description
It has been estimated that within just ten years, over half of all polyolefins will be made by using metallocene catalysts. This ground-breaking volume from PDL brings togetherùfor the first timeùwork from dozens of world-renowned experts on the subject. Fifty chapters of peer-reviewed content offer insights into applications in automotive components, food packaging, insulating films, non-woven fabrics and medical markets, among others.
Author: George M. Benedikt
Publisher: Cambridge University Press
ISBN: 0080950426
Category : Science
Languages : en
Pages : 398
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Book Description
It has been estimated that within just ten years, over half of all polyolefins will be made by using metallocene catalysts. This ground-breaking volume from PDL brings togetherùfor the first timeùwork from dozens of world-renowned experts on the subject. Fifty chapters of peer-reviewed content offer insights into applications in automotive components, food packaging, insulating films, non-woven fabrics and medical markets, among others.
Author: J. Karger-Kocsis
Publisher: Springer Science & Business Media
ISBN: 9401144214
Category : Science
Languages : en
Pages : 988
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Book Description
My heart sank when I was approached by Dr Hastings and by Professor Briggs (Senior Editor of Materials Science and Technology and Series Editor of Polymer Science and Technology Series at Chapman & Hall, respectively) to edit a book with the provisional title Handbook of Poly propylene. My reluctance was due to the fact that my former book [1] along with that of Moore [2], issued in the meantime, seemed to cover the information demand on polypropylene and related systems. Encour aged, however, by some colleagues (the new generation of scientists and engineers needs a good reference book with easy information retrieval, and the development with metallocene catalysts deserves a new update!), I started on this venture. Having some experience with polypropylene systems and being aware of the current literature, it was easy to settle the titles for the book chapters and also to select and approach the most suitable potential contributors. Fortunately, many of my first-choice authors accepted the invitation to contribute. Like all editors of multi-author volumes, I recognize that obtaining contributors follows an S-type curve of asymptotic saturation when the number of willing contributors is plotted as a function of time. The saturation point is, however, never reached and as a consequence, Dear Reader, you will also find some topics of some relevance which are not explicitly treated in this book (but, believe me, I have considered them).
Author: Walter Kaminsky
Publisher: Springer Science & Business Media
ISBN: 3642601782
Category : Technology & Engineering
Languages : en
Pages : 674
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Book Description
45 years after the discovery of transition metals and organometallics as cocatalysts for the polymerization of olefins and for organic synthesis, these compounds have not lost their fascination. The birthday of Karl Ziegler, the great pioneer in this metalorganic catalysis, is now 100 years ago. Polyolefins and polydienes produced by Ziegler-Natta catalysis are the most important plastics and elastomers. New impulses for the polymerization of olefins have been brought about by highly active metallocenes and other single site catalysts. Just by changing the ligands of the organometallic compounds, the structure of the polymers produced can be tailored in a wide manner. In invited lectures and posters, relevant aspects of the metalorganic catalysts for synthesis and polymerization are discussed in this book. This includes mechanism and kinetics, stereochemistry, material properties, and industrial applications.
Author: Walter Kaminsky
Publisher: Wiley-VCH
ISBN: 9783527317424
Category : Technology & Engineering
Languages : en
Pages : 0
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Book Description
With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.
Author: Ray Hoff
Publisher: John Wiley & Sons
ISBN: 1119242215
Category : Technology & Engineering
Languages : en
Pages : 895
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Book Description
Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization
Author: Yury Kissin
Publisher: Elsevier
ISBN: 0080557996
Category : Technology & Engineering
Languages : en
Pages : 607
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Book Description
During the past 30 years, the field of alkene polymerization over transition metal catalysts underwent several major changes:1. The list of commercial heterogeneous Ziegler-Natta catalysts for the synthesis of polyethylene and stereoregular polyolefins was completely renewed affording an unprecedented degree of control over the polymer structure.2. Research devoted to metallocene and other soluble transition-metal catalysis has vastly expanded and has shifted toward complexes of transition metals with multidentate ligands.3. Recent developments in gel permeation chromatography, temperature-rising fractionation, and crystallization fractionation provided the first reliable information about differences between various active centers in transition-metal catalysts.4. A rapid development of high-resolution 13C NMR spectroscopy resulted in greatly expanded understanding of the chemical and steric features of polyolefins and alkene copolymers. These developments require a new review of all aspects of alkene polymerization reactions with transition-metal catalysts. The first chapter in the book is an introductory text for researchers who are entering the field. It describes the basic principles of polymerization reactions with transition-metal catalysts, the types of catalysts, and commercially manufactured polyolefins. The next chapter addresses the principal issue of alkene polymerization catalysis: the existence of catalyst systems with single and multiple types of active centers. The subsequent chapters are devoted to chemistry and stereochemistry of elemental reaction steps, structures of catalyst precursors and reactions leading to the formation of active centers, kinetics of polymerization reactions, and their mechanisms.The book describes the latest commercial polymerization catalysts for the synthesis of polyethylenes and polypropylene The book provides a detailed description of the multi-center nature of commercial Ziegler-Natta catalysts. The book devotes specialized chapters to the most important aspects of transition metal polymerization catalysts: the reactions leading to the formation of active centers, the chemistry and stereochemistry of elemental polymerization steps, reaction kinetics, and the polymerization mechanism. The book contains an introductory chapter for researchers who are entering the field of polymerization catalysis. It describes the basic principles of polymerization reactions with transition-metal catalysts and the types of commercially manufactured polyolefins and copolymersThe book contains over 2000 references, the most recent up to end of 2006.
Author: Gerhard Fink
Publisher: Springer Science & Business Media
ISBN: 3642791360
Category : Technology & Engineering
Languages : en
Pages : 509
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Book Description
Forty years after Ziegler's discovery of the "Aufbaureaktion" and low-pressure ethene polymerization, transition metal catalyzed olefin and diolefin polymerization continues to represent one of the most active and exciting areas. Since the 1980s, outstanding scientific innovations and process improvements have revolutionized polyolefin technology and greatly simplified polymerization processes. Well-defined catalyst systems are now at hand and facilitate the understanding of basic reaction mechanisms and correlations between catalyst structures, polymer microstructures, and polymer properties. This book reviews some of the modern approaches in organometallic chemistry, Ziegler-Natta catalysis, polymerization processes, design of novel materials, and the modelling in catalyst and process development.
Author: Walter Kaminsky
Publisher: Springer
ISBN: 3642408052
Category : Technology & Engineering
Languages : en
Pages : 371
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Book Description
Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.
Author: John Scheirs
Publisher: Wiley
ISBN: 9780471999126
Category : Technology & Engineering
Languages : en
Pages : 600
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Book Description
With contributions from leading international experts, thisessential book gives comprehensive coverage of all areas ofmetallocene catalysts and metallocene-based polyolefins includingdetails of the very latest developments. The manufacture of polyolefins by metallocene catalysts representsa revolution in the polymer industry. The last five years inparticular have seen a dramatic increase in the volume of researchinto metallocenes and the maturing of metallocene technology. The following areas are covered in this comprehensive book:catalyst structure, comonomer incorporation, polymerizationmechanisms and conditions, reactor configurations, specialproperties, comparison with conventional polyolefins, rheologicaland processing behavior and fields of application. This is an invaluable book for plastics engineers, polymerchemists, physicists, materials scientists, and all those workingin the plastics manufacturing and processing industries.
Author: Walter Kaminsky
Publisher: Springer Science & Business Media
ISBN: 3642832768
Category : Science
Languages : en
Pages : 443
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Book Description
More than 30 years after the discovery of transition metals and organometal lics as catalysts for olefin polymerization these catalysts did not have lost their fascination. Since 1953 when Karl Ziegler has discovered the catalytic polymerization of ethylene leading to plastically formable polymers which are mechanically stable up to temperatures of about 100°C, synthetic polymers and rubbers have made their way right into private houses. This discovery has been a main impetus for the fast growing production of plastics. The stereoselective poly merization of propylene and other long-chain a-olefins first detected by Giulio Natta leads to an even broadened field of applications. Another enforcing factor were the developments of Standard Oil of Indiana and Phillipps Petroleum Company who engaged in the polymerization of a-olefins supported molybdenum, cobalt and later on chromium catalysts which clearly indicates the wide variety of suitable systems. This kind of research acknowledged merit when in 1963 the Nobel prize of chemistry was awarded to Ziegler and Natta. Although to a great extent there is a technical application for these catalysts, up to now the nature of the active centres and many reaction mechanisms are not completely known.
