MESOMORPHIC ORDER IN POLYMERS AND POLYMERIZATION IN LIQUID CRYSTALLINE MEDIA- PAPERS PRESENTED AT A SYMPOSIUM- 174TH MEETING- ACS, DIVISION OF POLYMER CHEMISTRY. PDF Download
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Languages : en
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Author:
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Author: Alexandre Blumstein
Publisher:
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Category : Science
Languages : en
Pages : 280
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Author: Alexandre Blumstein
Publisher:
ISBN:
Category :
Languages : en
Pages : 264
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Author: Alexandre Blumstein
Publisher: Elsevier
ISBN: 0323154840
Category : Science
Languages : en
Pages : 349
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Book Description
Liquid Crystalline Order in Polymers examines the topic of liquid crystalline order in systems containing rigid synthetic macromolecular chains. Each chapter of the book provides a review of one important area of the field. Chapter 1 discusses scattering in polymer systems with liquid crystalline order. It also introduces the field of liquid crystals. Chapter 2 treats the origin of liquid crystalline order in macromolecules by describing the in-depth study of conformation of such macromolecules in their unassociated state. The chapters that follow describe successively the liquid crystalline order in polymers with mesogenic side groups and rigid backbones, in polypeptides, and in block copolymers. Chapter 7 discusses the rheology of such systems. The last two chapters examine liquid crystalline order in biological materials and mesomorphic order in the realm of polymers with inorganic backbones. This book is intended to provide the polymer scientist, the materials scientist, and the biologist with a valuable source of information.
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Languages : en
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Author: Valery P. Shibaev
Publisher: Springer Science & Business Media
ISBN: 1461383331
Category : Technology & Engineering
Languages : en
Pages : 378
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Book Description
Among the various new directions in modern polymer science, the design and investigation of liquid crystal (LC) polymers have been the ones growing most actively and fruitfully. In spite of that, the possible formation of an anisotropic LC phase was only demonstrated theoretically for the first time in the 1950s by Onsager [1] and Flory [2], and then experimentally verified in the studies with polypeptides solutions. In essence, the studies of these LC lyotropic systems did not deviate from the theme of purely academic interest. It was at the beginning of the 1970s that the experimental "explosion" occurred, when aromatic polyamides were synthesized and their ability to form LC solutions in certain very aggressive solvents was discovered. The search for practical applications of such LC systems was crowned with the successful creation of the new generation of ultrastrong high-modulus ther mostable fibers, such as the Kevlar, due to the high degree of order of the macromolecules in the anisotropic LC state. In fact, these investigations coincided with the swift emergence on the practical "scene" of thermotropic low-molar-mass liquid crystals, with the use of these materials in microelectronics and electro optics (figures and let ters indicators, displays in personal computers, and flat TV, etc.). Polymer scientists also began to develop methods of synthesizing thermotropic LC polymers by incorporating mesogenic fragments in the main (main-chain LC polymers) or side branchings of the macromolecules (side-chain or comb shaped polymers).
Author: A.A. Collyer
Publisher: Springer Science & Business Media
ISBN: 9401118701
Category : Science
Languages : en
Pages : 486
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Book Description
The subject of liquid crystals and their use in electronic displays and in non-linear optical systems has become of tremendous importance during the last decade; and the incorporation of liquid crystal units into polymeric materials has led to a group of new materials with diverse properties. Some of these properties have been utilized in new products and some have yet to be used. Much published work has appeared that deals with specific materials or particular applications, and it was felt that a book was needed to examine and explain the underlying principles governing the diverse properties of these liquid crystal polymers, LCPs. The current work describes the diverse nature of LCPs, their synthesis, characterization, properties and finally their applications. It describes the manner in which liquid crystallinity or mesomorphism occurs in small molecules, monomer liquid crystals and polymer liquid crystals. Chapter 1 gives a classification of the various ways in which the meso gens may be connected to the polymer chains. Currently, the bulk of LCP material is based on main chain or longitudinal LCPs for use in engineering applications. The side chain or comb polymers are intended for use in electronics and opto-electronic systems and as surfactants. Many other variants and possibilities exist but their properties have not yet been fully studied or used. In this respect it is hoped that the current work will indicate future possibilities as well as discussing current opinion. v Preface vi Chapters 2 and 3 describe methods of characterizing the mesophases.
Author: Constantinos M. Paleos
Publisher: CRC Press
ISBN: 9782881245381
Category : Biopolymers
Languages : en
Pages : 470
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Book Description
Summarizes the current state of the art concerning the effect of organization of monomers on the polymerization process. Some of the techniques covered that bring about such ordering include thermotropic and lyotropic liquid crystalline media, gas-water and gas-solid interfaces, micelles and microemulsions. Potential applications range from novel composite media to biopolymer synthesis. Annotation copyright by Book News, Inc., Portland, OR
Author: A. M. Donald
Publisher: Cambridge University Press
ISBN: 9780521580014
Category : Science
Languages : en
Pages : 616
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Book Description
A 2006 edition explaining the underlying science and applications of liquid crystalline polymers.
Author: Xin-Jiu Wang
Publisher: World Scientific
ISBN: 9789812384102
Category : Science
Languages : en
Pages : 398
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Book Description
This textbook consists of six chapters. The first chapter highlights the concept of liquid crystals, including chemical structure, phase classification, defect and texture, and continuum theory. It has been carefully written to meet the needs of readers who do not specialize in liquid crystals. The second chapter is related to the theoretical description of liquid crystalline polymers, networks, and gels, which deals with subjects such as the formation of liquid crystallinity in the polymer system, the phase transition and phase diagram, the molecular weight effect, chain conformation, physics properties, etc. In Chapter 3, the molecular engineering of liquid crystalline polymers is introduced. The molecular composition and the molecular weight play essential roles in the molecular design, which are reviewed in detail. In addition, some unusual liquid crystalline polymers are discussed. Chapter 4 is devoted to the phase identification of liquid crystalline polymers. The techniques involved cover polarizing microscopy, thermal analysis, X-ray diffraction, and other areas. Chapters 5 and 6 summarize the properties and applications of liquid crystalline polymers: Chapter 5 deals mainly with mechanical performance in fiber and composites; Chapter 6 presents the elasticity, viscosity and rheology of liquid crystalline polymers, as well as other important properties.
