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Author: Viktor Gutmann
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 322
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Author: Viktor Gutmann
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 322
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Author: D. B. Sowerby
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 352
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Author: C C Addison
Publisher: Royal Society of Chemistry
ISBN: 184755640X
Category : Science
Languages : en
Pages : 468
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Book Description
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author:
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Category :
Languages : en
Pages :
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Author: M. F. Lappert
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 380
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Author:
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages :
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Author: B. J. Aylett
Publisher: Springer Science & Business Media
ISBN: 9400957297
Category : Science
Languages : en
Pages : 532
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A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Author: M. F. Lappert
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 376
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Author:
Publisher:
ISBN:
Category : Organometallic compounds
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category : Chemistry, Inorganic
Languages : en
Pages : 336
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