Magnetism Diagrams for Transition Metal Ions PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Magnetism Diagrams for Transition Metal Ions PDF full book. Access full book title Magnetism Diagrams for Transition Metal Ions by E. König. Download full books in PDF and EPUB format.
Author: E. König
Publisher: Springer Science & Business Media
ISBN: 1461330033
Category : Science
Languages : en
Pages : 560
Get Book Here
Book Description
I.- 1. Introduction.- 2. Conventional Magnetism Diagrams and Their Limitations. Present State of the Art.- 3. Tensor Operator Algebra for Point Groups.- 3.1. Tensor Operators and the Wigner-Eckart Theorem.- 3.2. 3-? and 6-? Symbols.- 3.3. Tensor Operators in Subgroups of SO(3).- 3.4. Kronecker and Scalar Products of Tensor Operators.- 3.5. Tensor Operators of the Ligand Field.- 4. The Weak-Field Method.- 4.1. The Hamiltonian, States, and Wave Functions.- 4.2. The Various Coefficients.- 4.3. Matrix Elements.- 4.4. Calculation of Magnetic Susceptibility.- 5. The Intermediate-Field Method.- 5.1.
Author: E. König
Publisher: Springer Science & Business Media
ISBN: 1461330033
Category : Science
Languages : en
Pages : 560
Get Book Here
Book Description
I.- 1. Introduction.- 2. Conventional Magnetism Diagrams and Their Limitations. Present State of the Art.- 3. Tensor Operator Algebra for Point Groups.- 3.1. Tensor Operators and the Wigner-Eckart Theorem.- 3.2. 3-? and 6-? Symbols.- 3.3. Tensor Operators in Subgroups of SO(3).- 3.4. Kronecker and Scalar Products of Tensor Operators.- 3.5. Tensor Operators of the Ligand Field.- 4. The Weak-Field Method.- 4.1. The Hamiltonian, States, and Wave Functions.- 4.2. The Various Coefficients.- 4.3. Matrix Elements.- 4.4. Calculation of Magnetic Susceptibility.- 5. The Intermediate-Field Method.- 5.1.
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872002
Category : Science
Languages : en
Pages : 482
Get Book Here
Book Description
An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author: E Konig
Publisher:
ISBN: 9781461330042
Category :
Languages : en
Pages : 572
Get Book Here
Book Description
Author: P B Ayscough
Publisher: Royal Society of Chemistry
ISBN: 1847553397
Category : Science
Languages : en
Pages : 376
Get Book Here
Book Description
Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author: David W. Oxtoby
Publisher: Harcourt Brace College Publishers
ISBN: 9780030247521
Category :
Languages : en
Pages : 244
Get Book Here
Book Description
PRINCIPLES OF MODERN CHEMISTRY has dominated the honors and high mainstream general chemistry courses and is considered the standard for the course. The fifth edition is a substantial revision that maintains the rigor of previous editions but reflects the exciting modern developments taking place in chemistry today. Authors David W. Oxtoby and H. P. Gillis provide a unique approach to learning chemical principles that emphasizes the total scientific process'from observation to application'placing general chemistry into a complete perspective for serious-minded science and engineering students. Chemical principles are illustrated by the use of modern materials, comparable to equipment found in the scientific industry. Students are therefore exposed to chemistry and its applications beyond the classroom. This text is perfect for those instructors who are looking for a more advanced general chemistry textbook.
Author: Satishchandra Balkrishna Ogale
Publisher: John Wiley & Sons
ISBN: 3527654887
Category : Technology & Engineering
Languages : en
Pages : 478
Get Book Here
Book Description
Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive. Based on recent research, experts in the field describe novel materials, their properties and applications for energy systems, semiconductors, electronics, catalysts and thin films. This monograph is divided into 6 parts which allows the reader to find their topic of interest quickly and efficiently. * Magnetic Oxides * Dopants, Defects and Ferromagnetism in Metal Oxides * Ferroelectrics * Multiferroics * Interfaces and Magnetism * Devices and Applications This book is a valuable asset to materials scientists, solid state chemists, solid state physicists, as well as engineers in the electric and automotive industries.
Author: Stephen Blundell
Publisher: OUP Oxford
ISBN: 0191586641
Category : Science
Languages : en
Pages : 272
Get Book Here
Book Description
An understanding of the quantum mechanical nature of magnetism has led to the development of new magnetic materials which are used as permanent magnets, sensors, and information storage. Behind these practical applications lie a range of fundamental ideas, including symmetry breaking, order parameters, excitations, frustration, and reduced dimensionality. This superb new textbook presents a logical account of these ideas, staring from basic concepts in electromagnetsim and quantum mechanics. It outlines the origin of magnetic moments in atoms and how these moments can be affected by their local environment inside a crystal. The different types of interactions which can be present between magnetic moments are described. The final chapters of the book are devoted to the magnetic properties of metals, and to the complex behaviour which can occur when competing magnetic interactions are present and/or the system has a reduced dimensionality. Throughout the text, the theorectical principles are applied to real systems. There is substantial discussion of experimental techniques and current reserach topics. The book is copiously illustrated and contains detailed appendices which cover the fundamental principles.
Author: Kevin S. Verley
Publisher: Nova Publishers
ISBN: 9781604560473
Category : Science
Languages : en
Pages : 356
Get Book Here
Book Description
Coordination chemistry is the study of compounds formed between metal ions and other neutral or negatively charged molecules. Coordination chemistry includes areas of inorganic solid state chemistry, organometallic chemistry and bioinorganic chemistry, as well as applications to analytical chemistry, catalysis, industrial chemistry and materials science.
Author: Barbara Sieklucka
Publisher: John Wiley & Sons
ISBN: 3527339531
Category : Science
Languages : en
Pages : 508
Get Book Here
Book Description
A comprehensive overview of this rapidly expanding interdisciplinary field of research. After a short introduction to the basics of magnetism and molecular magnetism, the text goes on to cover specific properties of molecular magnetic materials as well as their current and future applications. Design strategies for acquiring molecular magnetic materials with desired physical properties are discussed, as are such multifunctional materials as high Tc magnets, chiral and luminescent magnets, magnetic sponges as well as photo- and piezo-switching magnets. The result is an excellent resource for materials scientists, chemists, physicists and crystal engineers either entering or already working in the field.
Author: Joachim Stöhr
Publisher: Springer Science & Business Media
ISBN: 3540302832
Category : Science
Languages : en
Pages : 827
Get Book Here
Book Description
This text book gives a comprehensive account of magnetism, one of the oldest yet most vibrant fields of physics. It spans the historical development, the physical foundations and the continuing research underlying the subject. The book covers both the classical and quantum mechanical aspects of magnetism and novel experimental techniques. Perhaps uniquely, it discusses spin transport and magnetization dynamics phenomena associated with atomically and spin engineered nano-structures against the backdrop of spintronics and magnetic storage and memory applications. The book is for students, and serves as a reference for scientists in academia and research laboratories.
