Author: W. Roy Mason
Publisher: John Wiley & Sons
ISBN: 0470139226
Category : Science
Languages : en
Pages : 237
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Book Description
The book is a technical guide for chemists and spectroscopists, and presents a concise description of magnetic circular dichroism (MCD) spectroscopy and how it has advanced the interpretation of molecular electronic spectra. Provides a practical guide to utilizing MCD spectroscopy for chemists starting in the field Written by an expert with over twenty years of experience in the field Helps the reader to visualize the optical spectroscopic effects presented by MCD measurements Includes practical considerations for experimental MCD measurements based on the author's experience Written as a general discussion of the subject matter, with illustrative examples provided and discussed in the case studies to show the breadth of application of MCD measurements.
Author: Nagao Kobayashi
Publisher: Royal Society of Chemistry
ISBN: 1847558690
Category : Science
Languages : en
Pages : 217
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Book Description
CD and MCD spectroscopy can provide key information about the conformations and electronic states of chromophore containing molecules. However, the theory has remained too challenging and inaccessible for many organic chemists and biochemists and only a few researchers have carried out detailed quantitative analyzes of their spectral data. This is not surprising as people who excel at spectroscopic theory usually lack the skills set required to design and synthesize the molecules that would be most appropriate for describing and explaining the theory of CD and MCD spectroscopy. Most of the books that have been written on the subject have, therefore, been based on very dense sets of mathematical equations. This timely book rectifies that situation by summarizing the relationship between the different types of spectra and by describing in detail the qualitative and quantitative methods which can readily be used to analyze CD and MCD spectral data. During the last decade the authors have successfully synthesized several molecules to illustrate key points related to the theory of CD and MCD spectroscopy, resulting in this definitive book providing key practical knowledge in a readily accessible style. It is aimed primarily at organic chemists and biochemists and provides the required reading for researchers active in the field. In the introduction, the book describes the types of information that can be derived from CD and MCD spectroscopy. After a detailed explanation of the theory of electronic absorption spectroscopy, it then provides practical in depth examples of the various analytical methods that can be carried out with CD and MCD spectral data. This makes the theory of these techniques much more accessible for researchers who do not specialize in physical chemistry.
Author: Jeroen A. van Bokhoven
Publisher: John Wiley & Sons
ISBN: 1118844238
Category : Science
Languages : en
Pages : 940
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Book Description
X-Ray Absorption and X-ray Emission Spectroscopy: Theory and Applications During the last two decades, remarkable and often spectacular progress has been made in the methodological and instrumental aspects of x-ray absorption and emission spectroscopy. This progress includes considerable technological improvements in the design and production of detectors especially with the development and expansion of large-scale synchrotron reactors All this has resulted in improved analytical performance and new applications, as well as in the perspective of a dramatic enhancement in the potential of x-ray based analysis techniques for the near future. This comprehensive two-volume treatise features articles that explain the phenomena and describe examples of X-ray absorption and emission applications in several fields, including chemistry, biochemistry, catalysis, amorphous and liquid systems, synchrotron radiation, and surface phenomena. Contributors explain the underlying theory, how to set up X-ray absorption experiments, and how to analyze the details of the resulting spectra. X-Ray Absorption and X-ray Emission Spectroscopy: Theory and Applications: Combines the theory, instrumentation and applications of x-ray absorption and emission spectroscopies which offer unique diagnostics to study almost any object in the Universe. Is the go-to reference book in the subject for all researchers across multi-disciplines since intense beams from modern sources have revolutionized x-ray science in recent years Is relevant to students, postdocurates and researchers working on x-rays and related synchrotron sources and applications in materials, physics, medicine, environment/geology, and biomedical materials
Author: Susan B. Piepho
Publisher: Wiley-Interscience
ISBN:
Category : Psychology
Languages : en
Pages : 678
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Book Description
Author: Nina Berova
Publisher: John Wiley & Sons
ISBN: 9780471330035
Category : Science
Languages : en
Pages : 916
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Book Description
Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Moleküle. CD-Effekte lassen sich in Abhängigkeit von der Wellenlänge messen und spektroskopisch auswerten. Dieser Band erläutert Theorie und Anwendung der CD-Spektroskopie insbesondere für Biomoleküle. Ausführlich behandelt werden Anwendungen auf den Gebieten der organischen Stereochemie und der Biopolymere. Geschrieben von anerkannten Spezialisten! (06/00)
Author: Alison Rodger
Publisher: Oxford University Press, USA
ISBN: 9780198558972
Category : Science
Languages : en
Pages : 170
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Book Description
This book provides an introduction to all those who wish to use the complementary spectroscopic techniques of optical activity (circular dichroism, CD) and optical anisotropy (linear dichroism, LD) for the study of the structure of molecules and interactions between molecules in solution. It emphasizes these techniques and how to use them for both low and high molecular weight molecules. The book begins by describing the principles behind CD and LD and how these techniques can be used in the laboratory without using advanced maths or quantum mechanics. The next chapters describe how both techniques may be applied to the study of biological macromolecules and give a detailed description of how they may be used on small molecules to investigate molecular and electronic structure. The final part contains theoretical derivations of all the equations required for the applications described previously. Specific molecular examples are used to illustrate concepts and to show the reader how to use the techniques in chemical and biological systems. Circular Dichroism and Linear Dichroism is an easy guide to what a prospective user of CD needs to know and explains how LD is not merely an exotic technique only to be practiced by experienced spectroscopists, but may be routinely and usefully employed as an aid to molecular structure determination.
Author: A.S. Schlachter
Publisher: Springer Science & Business Media
ISBN: 9401108684
Category : Science
Languages : en
Pages : 400
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Book Description
Soft X-rays are a powerful probe of matter. They interact selectively with electrons in atoms and molecules and can be used to study atomic physics, chemical reactions, surfaces and solids, and biological entities. Over the past 20 years, synchrotrons have emerged as powerful sources of soft X-rays for experimental use. A new, third generation of synchrotron light sources is scheduled to start operation over the next few years, beginning in 1993. These facilities are distinguished by their ultra-low emittance electron beams and by their undulators -- precisely engineered magnetic devices that cause the electrons passing through them to produce highly coherent X-rays and ultraviolet light of unprecedented spectral brightness. This volume emphasizes third-generation sources that produce light in the 10 eV--10 KeV energy range. It describes potential applications ranging from the purely scientific to the commercially viable and includes chapters on the practical aspects of designing undulators and beam line optics. Unique in its coverage, the book is a vital addition to the library of any scientist who needs information on the world's most advanced imaging and spectroscopic techniques. (ABSTRACT) This volume emphasizes the applications of new third generation synchrotron radiation sources that produce light in the ultraviolet and soft X-ray range of the spectrum. The unprecedented brightness of this light enables experiments to be conducted with greatly increased spatial and spectral resolution. Scientists can exploit these properties for imaging and spectroscopic applications that until now were impossible or impractical. Prominent researchers in the field describe these applications and others made possible by the light's pulsed time structure and polarization. The volume also includes chapters on the practical aspects of designing undulators and beam line optics.
Author: Eric Beaurepaire
Publisher: Springer Science & Business Media
ISBN: 3540332413
Category : Science
Languages : en
Pages : 472
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Book Description
This volume contains the edited lectures of the fourth Mittelwihr school on "Magnetism and Synchrotron Radiation". This series of events introduces graduate students and nonspecialists from related disciplines to the field of magnetism and magnetic materials with emphasis on synchrotron radiation as an experimental tool of investigation. These lecture notes present in particular the state of the art regarding the analysis of magnetic properties of new materials.
Author: Bengt Nordén
Publisher: Royal Society of Chemistry
ISBN: 1788018214
Category : Science
Languages : en
Pages : 305
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Book Description
This book provides an introduction to optical anisotropy (linear dichroism, LD) and optical activity (circular dichroism, CD) as techniques for the study of structures and interactions of molecules in solution. The book covers the use of these techniques for both small and large molecular systems with particular emphasis being placed on proteins and nucleic acids. CD is a well-established technique and this book aims to explain how it can be used simply and effectively for new entrants to the field as well as covering more advanced techniques for experts. LD is often seen as a rather exotic method intended only for experienced spectroscopists. This book demonstrates that it is an approach with real utility that may be used by both students and scientists from graduate level onwards to give simple answers, which are not available from any other technique, to structural and kinetic questions. Much of the emphasis is on flow orientation of samples in solution phase. The book first describes the techniques and the information they can provide; it then goes on to give specific details on how to actually implement them, including a wide range of examples showing how LD and CD can help with * protein and nucleic acid secondary structure elucidation; * analysis of the formation and rearrangements of fibrous proteins and membrane proteins; * identification of the absolute configuration of small molecules; * determination of the orientation of small molecules in anisotropic media; * assignment of transition moment polarizations; * investigation of binding strengths and geometries of ligand-macromolecule complexes; * 3-D structure determination from LD, molecular replacement and MD modeling. The advantages of combined LD/CD studies are also outlined with examples of DNA/drug complexes and protein insertion into membranes. Taken together the book represents a comprehensive text on the theory and application of LD and CD in the chemical and biological sciences.
Author: Frank de Groot
Publisher: CRC Press
ISBN: 1420008420
Category : Science
Languages : en
Pages : 512
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Book Description
Core level spectroscopy has become a powerful tool in the study of electronic states in solids. From fundamental aspects to the most recent developments, Core Level Spectroscopy of Solids presents the theoretical calculations, experimental data, and underlying physics of x-ray photoemission spectroscopy (XPS), x-ray absorption spectroscopy (XAS), x
