Linear and nonlinear optical Zn(II)-metal-organic materials. Correlation between molecular structure, crystal structure and chemical-physical properties PDF Download
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Author: Bojidarka Ivanova
Publisher: GRIN Verlag
ISBN: 3668111367
Category : Science
Languages : en
Pages : 359
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Book Description
Research Paper (postgraduate) from the year 2015 in the subject Chemistry - Other, grade: Subventionierte Projekt, University of Dortmund (Institut für Umweltforschung , Lehrstuhl für Analytische Chemie), language: English, abstract: This book deals with chemistry and chemical-physical effects of Zn(II)-containing metal-organics with emergence as an interdisciplinary area of coordination chemistry, blending of optical and nonlinear optical materials research; optical fiber communication and optical computing technologies; data storage techniques; image processing; dynamic holography; printers; producing of harmonic generators; optical switching and limiting devices; fluorescence materials and more. In this context, the book collects new trends, and presents for first time more recent work in the field of applied oriented design of molecular scaffolds, synthesis, optical and nonlinear optical studies of coordination compounds of Zn(II)-ion. The book is divided into four chapters. The first Chapter 1 is designed to give readers a general overview on relevance of metal-organic materials containing metal ions with completed electronic d10 configurations to mentioned above areas of applied sciences. We have chosen to introduce relationship between molecular structure and properties of zinc tris(thiourea) sulphate and its derivatives in a short Chapter 2, because of those compounds are seriously tested for an industrial scale application as NLO-phores. Chapter 3 is devoted, principally, to a correlation between molecular structure, crystal structure and chemical physical effects of Zn(II)-containing metal-organic materials, mainly part of our research work. Chapter 4 concentrates on theoretical methodological formalism of most applicable quantum chemical methods, treating optical and non-linear optical phenomena, which are base on same thematic overall organization of this part of the book. The importance of this chapter is that it refers to basic computational chemistry methodology, associated with prediction of chemical-physical effects of metal-organics in gas- and condense phase, as a crucial step defining applied oriented chemical synthesis of new coordination compounds, thus producing results relevant to their real application as materials to optical and nonlinear optical technologies. Chapter 4 can serves as methodological reference point. But the content of the book, generally, can be useful to scientific research of MSc and PhD students in “Chemistry”, which work involves fields such as coordination chemistry, applied materials research, crystal engineering, and the fourth.
Author: Bojidarka Ivanova
Publisher: GRIN Verlag
ISBN: 3668111367
Category : Science
Languages : en
Pages : 359
Get Book Here
Book Description
Research Paper (postgraduate) from the year 2015 in the subject Chemistry - Other, grade: Subventionierte Projekt, University of Dortmund (Institut für Umweltforschung , Lehrstuhl für Analytische Chemie), language: English, abstract: This book deals with chemistry and chemical-physical effects of Zn(II)-containing metal-organics with emergence as an interdisciplinary area of coordination chemistry, blending of optical and nonlinear optical materials research; optical fiber communication and optical computing technologies; data storage techniques; image processing; dynamic holography; printers; producing of harmonic generators; optical switching and limiting devices; fluorescence materials and more. In this context, the book collects new trends, and presents for first time more recent work in the field of applied oriented design of molecular scaffolds, synthesis, optical and nonlinear optical studies of coordination compounds of Zn(II)-ion. The book is divided into four chapters. The first Chapter 1 is designed to give readers a general overview on relevance of metal-organic materials containing metal ions with completed electronic d10 configurations to mentioned above areas of applied sciences. We have chosen to introduce relationship between molecular structure and properties of zinc tris(thiourea) sulphate and its derivatives in a short Chapter 2, because of those compounds are seriously tested for an industrial scale application as NLO-phores. Chapter 3 is devoted, principally, to a correlation between molecular structure, crystal structure and chemical physical effects of Zn(II)-containing metal-organic materials, mainly part of our research work. Chapter 4 concentrates on theoretical methodological formalism of most applicable quantum chemical methods, treating optical and non-linear optical phenomena, which are base on same thematic overall organization of this part of the book. The importance of this chapter is that it refers to basic computational chemistry methodology, associated with prediction of chemical-physical effects of metal-organics in gas- and condense phase, as a crucial step defining applied oriented chemical synthesis of new coordination compounds, thus producing results relevant to their real application as materials to optical and nonlinear optical technologies. Chapter 4 can serves as methodological reference point. But the content of the book, generally, can be useful to scientific research of MSc and PhD students in “Chemistry”, which work involves fields such as coordination chemistry, applied materials research, crystal engineering, and the fourth.
Author: Xin-Tao Wu
Publisher: Springer
ISBN: 3642296211
Category : Science
Languages : en
Pages : 151
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Book Description
Xiao-Ming Jiang, Sheng-Ping Guo, Hui-Yi Zeng, Ming-Jian Zhang, Guo-Cong Guo: Large Crystal Growth and New Crystal Exploration of Mid-Infrared Second-Order Nonlinear Optical Materials.- Kechen Wu: Simulation and Design of Infrared Second-Order Nonlinear Optical Materials in Metal Cluster Compounds.- Chaoyang Tu: The Recent Development Of SRS and SRS SF- conversion Laser Crystal.- Hua-Jun Zhao, Xin-Tao Wu, Li-Ming Wu: Exploration of New Second-Order Nonlinear Optical Compounds Containing Main Group Elements.
Author: D.S. Chemla
Publisher: Elsevier
ISBN: 0323148158
Category : Science
Languages : en
Pages : 497
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Book Description
Nonlinear Optical Properties of Organic Molecules and Crystals, Volume 1 discusses the nonlinear optical effects in organic molecules and crystals, providing a classical distinction between quadratic and cubic processes. This book begins with a general overview of the basic properties of organic matter, followed by a review on the benefits derived from quantum-chemistry-based models and growth and characterization of high quality, bulk organic crystals and waveguided structures. A case study focusing on a specific material, namely urea, which exemplifies a situation in which transparency in the UV region has been purposely traded for nonlinear efficiency is also deliberated. This text concludes with a description of a type of trade-off between the unpredictable orientation of molecules in crystalline media, polarity of liquid-crystalline structures, and dominant electronic contribution to the electro-optic effect. This publication is beneficial to solid-state physicists and chemists concerned with nonlinear optical properties of organic molecules and crystals.
Author: D.S. Chemla
Publisher: Elsevier
ISBN: 0323157769
Category : Science
Languages : en
Pages : 285
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Book Description
Nonlinear Optical Properties of Organic Molecules and Crystals, Volume 2 deals with the nonlinear optical properties of organic molecules and crystals, with emphasis on cubic nonlinear optical effects and and the intermolecular bond. Topics covered include the basic structural and electronic properties of polydiacetylenes; cubic effects in polydiacetylene solutions and films; and degenerate third-order nonlinear optical susceptibility of polydiacetylenes. Dimensionality effects and scaling laws in nonlinear optical susceptibilities are also considered. This volume is comprised of seven chapters divided into two sections and begins with a discussion on the basic structural and electronic properties of polydiacetylenes as well as their methods of preparation. Cubic nonlinearities in polydiacetylene solutions and films are then examined, paying particular attention to polarization in one-dimensional media; multiple reflections of fundamental and harmonic waves; and harmonic generation in an absorbing medium. The following chapters focus on degenerate third-order nonlinear optical susceptibility of polydiacetylenes; dimensionality effects and scaling laws in nonlinear optical susceptibilities; polarizabilities and hyperpolarizabilities of long molecules; and resonant molecular optics. The final chapter analyzes the nonlinear optics of a wide range of compounds that are held together by intermolecular bonding and form supramolecular assemblies. This monograph will be a useful resource for physicists, physical and organic chemists, and those in the field of quantum electronics.
Author: Manthos G. Papadopoulos
Publisher: Springer Science & Business Media
ISBN: 1402048505
Category : Science
Languages : en
Pages : 676
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Book Description
This book assembles both theory and application in this field, to interest experimentalists and theoreticians alike. Part 1 is concerned with the theory and computing of non-linear optical (NLO) properties while Part 2 reviews the latest developments in experimentation. This book will be invaluable to researchers and students in academia and industry, particularlrly to anyone involved in materials science, theoretical and computational chemistry, chemical physics, and molecular physics.
Author: Xin-Tao Wu
Publisher: Springer
ISBN: 3642296181
Category : Science
Languages : en
Pages : 246
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Book Description
Wen-Dan Cheng, Chen-Sheng Lin, Wei-Long Uhang, Hao Zhang: Structural Designs and Property Characterizations for Second-Harmonic Generation Materials.- Fang Kong, Chuan-Fu Sun, Bing-Ping Yang, Jiang-Gao Mao: Second-order Non-linear Optical Materials based on Metal Iodates, Selenites and Tellurites.- Guo-Fu Wang: Structure, growth, nonlinear optics and laser properties of RX3(BO3)4 (R=Y, Gd, La; X=Al, Sc).- Chaoyang Tu, Zhaojie Zhu, Zhenyu You, Jianfu Li, Yan Wang, Alain Brenier: The Recent Development of Borate SF-conversion Laser Crystal.- Ning Ye: Structure design and crystal growth of UV nonlinear borate materials.- Yi-Zhi Huang, Li-Ming Wu, Mao-Chun Hong: Cation Effect in Doped BBO and Halogen Anion Effect in Pb2B5O9X (X– = I–, Br–, Cl–).
Author: R. A. Hann
Publisher: CRC Press
ISBN:
Category : Science
Languages : en
Pages : 448
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Book Description
This publication represents the proceedings of the Conference on Organic Materials for Non-Linear Optics, held in Oxford in June 1988. It was a truly international conference attended by over 160 delegates from academia, industry and government research establishments, who represented a wide range of scientific disciplines and included organic and organometallic chemists, theorists and experimental physicists and device engineers.
Author: Rashid A. Ganeev
Publisher: Springer
ISBN: 9400760221
Category : Science
Languages : en
Pages : 258
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Book Description
This book is mostly concerned on the experimental research of the nonlinear optical characteristics of various media, low- and high-order harmonic generation in different materials, and formation, and nonlinear optical characterization of clusters. We also demonstrate the inter-connection between these areas of nonlinear optics. Nonlinear optical properties of media such as optical limiting can be applied in various areas of science and technology. To define suitable materials for these applications, one has to carefully analyse the nonlinear optical characteristics of various media, such as the nonlinear refractive indices, coefficients of nonlinear absorption, saturation absorption intensities, etc. Knowing the nonlinear optical parameters of materials is also important for describing the propagation effects, self-interaction of intense laser pulses, and optimisation of various nonlinear optical processes. Among those processes one can admit the importance of the studies of the frequency conversion of coherent laser sources. The area of interest for nonlinear optical characterization of materials is also closely related with new field of nanostructures formation and application during laser-matter interaction. We show how the nonlinear optical analysis of materials leads to improvement of their high-order nonlinear optical response during the interaction with strong laser fields. Ablation-induced nanoparticles formation is correlated with their applications as efficient sources of coherent short-wavelength photons. From other side, recent achievements of harmonic generation in plasmas are closely related with the knowledge of the properties of materials in the laser plumes. All of these studies are concerned with the low-order nonlinear optical features of various materials. The novelty of the approach developed in present book is related with inter-connection of those studies with each other.
Author: F.A. Lévy
Publisher: Springer Science & Business Media
ISBN: 9401014337
Category : Science
Languages : en
Pages : 374
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Book Description
In the last ten years, the chemistry and physics of materials with layered structures became an intensively investigated field in the study of the solid state. Research into physical properties of these crystals and especially investigations of their physical anisotropy related to the structural anisotropy has led to remarkable and perplexing results. Most of the layered materials exist in several polytypic modifications and can include stacking faults. The crystal structures are therefore complex and it became apparent that there was a great need for a review of the crystallographic data of materials approximating two-dimensional solids. This second volume in the series 'Physics and Chemistry of Materials with Layered Structures' has been written by specialists of different classes of layered materials. Structural data are reviewed and the most important relations between the structure and the chemical and physical properties are emphasized. The first three contributions are devoted to the transition metal dichalcogenides whose physical properties have been investigated in detail. The crystallographic data and crystal growth conditions are presented in the first paper. The second paper constitutes an incisive review of the phase transformations and charge density waves which have been observed in the metallic dichalcogenides. In two contributions the layered structures of newer ternary compounds are de scribed and the connection between structure and non-stoichiometry is discussed.
Author:
Publisher: Academic Press
ISBN: 0123743966
Category : Science
Languages : en
Pages : 2785
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Book Description
From the Introduction: Nanotechnology and its underpinning sciences are progressing with unprecedented rapidity. With technical advances in a variety of nanoscale fabrication and manipulation technologies, the whole topical area is maturing into a vibrant field that is generating new scientific research and a burgeoning range of commercial applications, with an annual market already at the trillion dollar threshold. The means of fabricating and controlling matter on the nanoscale afford striking and unprecedented opportunities to exploit a variety of exotic phenomena such as quantum, nanophotonic and nanoelectromechanical effects. Moreover, researchers are elucidating new perspectives on the electronic and optical properties of matter because of the way that nanoscale materials bridge the disparate theories describing molecules and bulk matter. Surface phenomena also gain a greatly increased significance; even the well-known link between chemical reactivity and surface-to-volume ratio becomes a major determinant of physical properties, when it operates over nanoscale dimensions. Against this background, this comprehensive work is designed to address the need for a dynamic, authoritative and readily accessible source of information, capturing the full breadth of the subject. Its six volumes, covering a broad spectrum of disciplines including material sciences, chemistry, physics and life sciences, have been written and edited by an outstanding team of international experts. Addressing an extensive, cross-disciplinary audience, each chapter aims to cover key developments in a scholarly, readable and critical style, providing an indispensible first point of entry to the literature for scientists and technologists from interdisciplinary fields. The work focuses on the major classes of nanomaterials in terms of their synthesis, structure and applications, reviewing nanomaterials and their respective technologies in well-structured and comprehensive articles with extensive cross-references. It has been a constant surprise and delight to have found, amongst the rapidly escalating number who work in nanoscience and technology, so many highly esteemed authors willing to contribute. Sharing our anticipation of a major addition to the literature, they have also captured the excitement of the field itself in each carefully crafted chapter. Along with our painstaking and meticulous volume editors, full credit for the success of this enterprise must go to these individuals, together with our thanks for (largely) adhering to the given deadlines. Lastly, we record our sincere thanks and appreciation for the skills and professionalism of the numerous Elsevier staff who have been involved in this project, notably Fiona Geraghty, Megan Palmer and Greg Harris, and especially Donna De Weerd-Wilson who has steered it through from its inception. We have greatly enjoyed working with them all, as we have with each other.
