Late Transition Metal Amido and Pyrrolyl Complexes PDF Download
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Author: Michael Sean Driver
Publisher:
ISBN:
Category :
Languages : en
Pages : 426
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Book Description
Author: Michael Sean Driver
Publisher:
ISBN:
Category :
Languages : en
Pages : 426
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Book Description
Author: Manoj K. Kolel-Veetil
Publisher:
ISBN:
Category : Metal complexes
Languages : en
Pages : 470
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Book Description
Author: Björn Birger Askevold
Publisher:
ISBN:
Category :
Languages : en
Pages : 177
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Author: Christopher R. Yeisley
Publisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 68
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Author: Fei Peng
Publisher:
ISBN:
Category : Organometallic chemistry
Languages : en
Pages : 140
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Author: Andrew William Holland
Publisher:
ISBN:
Category :
Languages : en
Pages : 502
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Author: Richard Michael Kessler
Publisher:
ISBN:
Category :
Languages : en
Pages : 316
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Author: Preeyanuch Sangtrirutnugul
Publisher:
ISBN:
Category :
Languages : en
Pages : 684
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 8
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The synthesis and reactions of late-transition-metal oxo and imido complexes was explored. The deprotonation of platinum(II) hydroxo complexes yielded new oxo complexes. Attempted deprotonation of Cp*Rh(III) hydroxo complexes did not give oxo complexes but complex mixtures probably resulting from reduction of the Rh(III) center. The reaction of Na/Hg with (Cp*RhCl2)2 gave the very reactive Rh(II) dimer, (Cp*RhCl)2. Rhodium(I) imido complexes with the bis(dimethylphosphino)methane ligand were prepared and found to be similar to the previously prepared bis(diphenylphosphino)methane complexes. Attempts to prepare bis(diphenylphosphino)methylamine, bis(diphenylphosphino)phenylamine, PMe{sub e} and NO analogues were not successful. Attempts to prepare Cp*Rh(III) imido complexes resulted in amido complexes and reduction. Rhodium (III) tris(3.5-dimethylpyrazoyl)borate analogues are reduction resistant but have not yet yielded imido complexes. The first imido complexes of Au were prepared by treating a Au oxo complex with amines or isocyanates. Dimeric Cp*Rh dioxygen and nitrosobenzene complexes were prepared by insertion into the Rh-Rh bond of (Cp*RhCl)2. The dioxygen complex activates a C-H bond of the Cp* ligand on treatment with PMe3. Imido and oxo complexes nitrene and oxygen atom transfer product in reactions with CO. A novel electrophilic ring addition was observed with sterically protected aryl imido complexes. 15 refs.
Author: Louis S. Hegedus
Publisher: University Science Books
ISBN: 9780935702934
Category : Organic compounds
Languages : en
Pages : 428
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Book Description
A text for use in a one-semester course for upper-level students familiar with basic organic chemistry, or as a survey course for practicing organic chemists. Chapters 1 and 2 present a brief overview of the formalisms and mechanisms required to understand the processes discussed in chapters 3-10, which deal with the application of transition metal organometallic chemistry to organic synthesis with specific attention to applications with complex molecules. Updates and expands chapters 13-20 of Principles and Applications of Organotransition Metal Chemistry, 2nd ed. (1987). Published by University Science Books, 20 Edgehill Rd., Mill Valley, CA 94941. Annotation copyright by Book News, Inc., Portland, OR
