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Author: Renata Reisfeld
Publisher: Springer Science & Business Media
ISBN: 3642666965
Category : Science
Languages : en
Pages : 235
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Book Description
The possibility of stimulated light emission was discussed by Einstein in 1917, eight years before the quantum-mechanical description of energy levels of many-electron systems. Though it is imperative to use samples having optical properties greatly different from the stan dard continuous spectrum of opaque objects ("black body" radia tion) it is not always necessary to restrict the study to monatomic entities. Thus, spectral lines can be obtained (in absorption and in emission) from lanthanide compounds, containing from one to thir teen 4f electrons going from trivalent cerium to ytterbium, that are nearly as sharp as the ones from gaseous atoms. However, the presence of adjacent atoms modifies the simple picture of an isolated electron configuration, and in particular, it is possible to pump excited levels efficiently by energy transfer from species with intense absorption bands, such as the inter-shell transitions of other lanthanides and of thallium(I), lead(II) and bismuth(III) or the electron transfer bands of the uranyl ion or other complexes. On the other hand, it is possible to diminuish the mUlti-phonon relaxation (competing with sharp line luminescence) by selecting vitreous or crystalline materials with low phonon energies. Obviously, one cannot circumvent the conservation of energy by lasers, but they may have unprecedented consequences for the future by allowing nuclear fusion of light elements, effects of non-linear optics and time-resolved spectroscopy, besides the more conventional applications of coherent light beams with negligible angular extension.
Author: Renata Reisfeld
Publisher: Springer Science & Business Media
ISBN: 3642666965
Category : Science
Languages : en
Pages : 235
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Book Description
The possibility of stimulated light emission was discussed by Einstein in 1917, eight years before the quantum-mechanical description of energy levels of many-electron systems. Though it is imperative to use samples having optical properties greatly different from the stan dard continuous spectrum of opaque objects ("black body" radia tion) it is not always necessary to restrict the study to monatomic entities. Thus, spectral lines can be obtained (in absorption and in emission) from lanthanide compounds, containing from one to thir teen 4f electrons going from trivalent cerium to ytterbium, that are nearly as sharp as the ones from gaseous atoms. However, the presence of adjacent atoms modifies the simple picture of an isolated electron configuration, and in particular, it is possible to pump excited levels efficiently by energy transfer from species with intense absorption bands, such as the inter-shell transitions of other lanthanides and of thallium(I), lead(II) and bismuth(III) or the electron transfer bands of the uranyl ion or other complexes. On the other hand, it is possible to diminuish the mUlti-phonon relaxation (competing with sharp line luminescence) by selecting vitreous or crystalline materials with low phonon energies. Obviously, one cannot circumvent the conservation of energy by lasers, but they may have unprecedented consequences for the future by allowing nuclear fusion of light elements, effects of non-linear optics and time-resolved spectroscopy, besides the more conventional applications of coherent light beams with negligible angular extension.
Author: Renata Reisfeld
Publisher:
ISBN: 9783642666971
Category :
Languages : en
Pages : 240
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Book Description
Author: Michel J.F. Digonnet
Publisher: CRC Press
ISBN: 0824741641
Category : Technology & Engineering
Languages : en
Pages : 956
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Book Description
A discussion of the theories, operating characteristics, and current technology of main fiber laser and amplifier devices based on rare-earth-doped silica and fluorozirconate fibers. It describes the principles, designs, and properties of the erbium-doped fiber amplifier and its role as the cornerstone component in optical communication systems. This second edition contains new and revised material reflecting major developments in academia and industry.
Author: Hotan Shalibeik
Publisher: Cuvillier Verlag
ISBN: 3867274673
Category : Light amplifiers
Languages : en
Pages : 197
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Book Description
Author: Guokui Liu
Publisher: Springer Science & Business Media
ISBN: 3540282092
Category : Science
Languages : en
Pages : 567
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Book Description
Aimed at researchers and graduate students, this book provides up-to-date information about the electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties covers electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions of materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.
Author: A. R. Jha, Ph.D.
Publisher: CRC Press
ISBN: 1351674862
Category : Computers
Languages : en
Pages : 127
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Book Description
Deployment of Rare Earth Materials in Microware Devices, RF Transmitters, and Laser Systems describes the deployment of rare earth materials that offer significant improvement in the RF performance, reliability, weight, and size of microwave devices, RF transmitters, and laser systems. RF components, microware transmitters, laser systems, and special timing devices are described, with an emphasis on improvement in the performance parameters.
Author: Frank Träger
Publisher: Springer Science & Business Media
ISBN: 3642194095
Category : Science
Languages : en
Pages : 1704
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Book Description
This new edition features numerous updates and additions. Especially 4 new chapters on Fiber Optics, Integrated Optics, Frequency Combs and Interferometry reflect the changes since the first edition. In addition, major complete updates for the chapters: Optical Materials and Their Properties, Optical Detectors, Nanooptics, and Optics far Beyond the Diffraction Limit. Features Contains over 1000 two-color illustrations. Includes over 120 comprehensive tables with properties of optical materials and light sources. Emphasizes physical concepts over extensive mathematical derivations. Chapters with summaries, detailed index Delivers a wealth of up-to-date references.
Author: E. Roland Menzel
Publisher: CRC Press
ISBN: 9780824792657
Category : Science
Languages : en
Pages : 328
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Book Description
This work describes experimental techniques using laser spectroscopy and presents specific practical applications for this technology in many fields, including physics, engineering, chemistry, medicine and bioscience. The general spectroscopic features of molecules are delineated; transition metal and rare earth complexes are examined; and transition selection rules are explained.
Author: Vinny R. Sastri
Publisher: Elsevier
ISBN: 0080536689
Category : Science
Languages : en
Pages : 1005
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Book Description
In order to use rare earths successfully in various applications, a good understanding of the chemistry of these elements is of paramount importance. Nearly three to four decades have passed since titles such as The Rare Earths edited by F.H. Spedding and A.H. Daane, The chemistry of the Rare Earth Elements by N.E. Topp and Complexes of the Rare Earths by S.P. Sinha were published. There have been many international conferences and symposia on rare earths, as well as the series of volumes entitled Handbook of Physics and Chemistry of Rare Earths edited by K.A. Gschneidner and L. Eyring. Thus, there is a need for a new title covering modern aspects of rare earth complexes along with the applications. The present title consists of twelve chapters. 1. Introduction2. General aspects3. Stability of complexes4. Lanthanide complexes5. Structural chemistry of lanthanide compounds6. Organometallic complexes7. Kinetics and mechanisms of rare earths complexation8. Spectroscopy of lanthanide complexes9. Photoelectron spectroscopy of rare earths10. Lanthanide NMR shift reagents11. Environmental ecological biological aspects12. Applications The authors studied in schools headed by pioneers in rare earth chemistry, have a combined experience of one hundred and fifty years in inorganic chemistry, rare earth complex chemistry, nuclear and radiochemistry of rare earths and supramolecular chemistry. The present monograph is a product of this rich experience.
Author: Katja Rademaker
Publisher: Cuvillier Verlag
ISBN: 3865376525
Category :
Languages : en
Pages : 129
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Book Description
