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Author: A. Ben-Shaul
Publisher: Springer Science & Business Media
ISBN: 3642678262
Category : Science
Languages : en
Pages : 511
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Book Description
Lasers and chemical change is the study of radiation and molecules in dis equilibrium. The distinguishing feature of such systems is the extreme de parture from thermal equilibrium: the radiation is usually confined to a narrow frequency range, is well coll imated, and is far brighter than black body radiation; the chemical composition and also the distribution of mole cules over their different energy states are often markedly displaced from that expected at equilibrium. Such systems can be used as a source of laser radiation and, reversedly, lasers can rapidly and selectively displace mole cular systems from equilibrium. The subsequent evolution of the initially prepared state can then be monitored - again using lasers. One purpose of this book is to introduce the concepts required to d- cuss systems of radiation and molecules in disequilibrium. These include the physics of (laser) radiation and of radiation-matter interaction and molecular structure and spectroscopy. Excellent textbooks of these topics are available and our survey (in Chap. 3) is only intended to accent the es sential points, with special reference to atomic and molecular radiation physics. Considerably more attention is given to the topic of disequilibrium in chemical systems (Chap. 2). In particular we consider both inter- and intra molecular dynamics with special reference to energy requirements and energy disposal in chemical reactions and to what goes on in between - intramole cular energy migration.
Author: A. Ben-Shaul
Publisher: Springer Science & Business Media
ISBN: 3642678262
Category : Science
Languages : en
Pages : 511
Get Book
Book Description
Lasers and chemical change is the study of radiation and molecules in dis equilibrium. The distinguishing feature of such systems is the extreme de parture from thermal equilibrium: the radiation is usually confined to a narrow frequency range, is well coll imated, and is far brighter than black body radiation; the chemical composition and also the distribution of mole cules over their different energy states are often markedly displaced from that expected at equilibrium. Such systems can be used as a source of laser radiation and, reversedly, lasers can rapidly and selectively displace mole cular systems from equilibrium. The subsequent evolution of the initially prepared state can then be monitored - again using lasers. One purpose of this book is to introduce the concepts required to d- cuss systems of radiation and molecules in disequilibrium. These include the physics of (laser) radiation and of radiation-matter interaction and molecular structure and spectroscopy. Excellent textbooks of these topics are available and our survey (in Chap. 3) is only intended to accent the es sential points, with special reference to atomic and molecular radiation physics. Considerably more attention is given to the topic of disequilibrium in chemical systems (Chap. 2). In particular we consider both inter- and intra molecular dynamics with special reference to energy requirements and energy disposal in chemical reactions and to what goes on in between - intramole cular energy migration.
Author: A Ben-Shaul
Publisher:
ISBN: 9783642678271
Category :
Languages : en
Pages : 516
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Book Description
Author: Charles Bradley Moore
Publisher:
ISBN: 9780125054010
Category : Lasers
Languages : en
Pages : 416
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Book Description
Author: Jeffrey I. Steinfeld
Publisher: Springer Science & Business Media
ISBN: 1468438638
Category : Technology & Engineering
Languages : en
Pages : 283
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Book Description
The possibility of initiating chemical reactions by high-intensity laser exci tation has captured the imagination of chemists and physicists as well as of industrial scientists and the scientifically informed public in general ever since the laser first became available. Initially, great hopes were held that laser-induced chemistry would revolutionize synthetic chemistry, making possible "bond-specific" or "mode-specific" reactions that were impos sible to achieve under thermal equilibrium conditions. Indeed, some of the early work in this area, typically employing high-power continuous-wave sources, was interpreted in just this way. With further investigation, however, a more conservative picture has emerged, with the laser taking its place as one of a number of available methods for initiation of high-energy chemical transformations. Unlike a number of these methods, such as flash photolysis, shock tubes, and electron-beam radiolysis, the laser is capable of a high degree of spatial and molecular localization of deposited energy, which in turn is reflected in such applications as isotope enrichment or localized surface treatments. The use of lasers to initiate chemical processes has led to the discovery of several distinctly new molecular phenomena, foremost among which is that of multiple-photon excitation and dissociation of polyatomic molecules. This research area has received the greatest attention thus far and forms the focus of the present volume.
Author: C. Bradley Moore
Publisher: Elsevier
ISBN: 0323151604
Category : Science
Languages : en
Pages : 411
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Book Description
Chemical and Biochemical Applications of Lasers aims to give a general introduction to as well as an evaluation of the successful application of lasers in various areas, especially in the fields of chemistry and biochemistry. The book begins with a basic knowledge of general laser physics and the types of lasers, then moves on to more specific topics that include the Raman spectra of biological materials; laser spectroscopy of gas phase ions; and optical analogs of magnetic spectroscopy. The text also discusses the molecular beams; the energy flow in polyatomic molecules; and the different properties of molecules in relation to electronical excitation and quasi-electric light scattering. Studies of different chemical reactions are also included. The text is recommended for chemists, biochemists, and chemical physicists who want to know more about lasers and its applications to their respective fields. The book will also be helpful for those concerned with the chemical reactions lasers can bring about and for those who want to conduct further studies regarding laser uses.
Author: Nikolay G. Basov
Publisher: Springer
ISBN:
Category : Science
Languages : en
Pages : 396
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Book Description
The rapid development of lasers in the past few decades has led to their application in almost every field of science and technology. The idea that it should be possible to convert the energy released in chemical reactions of chemical lasers directly into coherent radiation resulted in the advent in the 1960s. These first chemical lasers, however, consumed much more energy to initiate the reaction than they emitted. The search for more ef ficient chemical lasing led to the utilization of chain reactions. However, care had to be taken to maintain the appropriate pressure. In 1970, it was demonstrated that the operation of chemical lasers at atmospheric pressure was also feasible, making it easier and cheaper to construct them. One of the advantages of chemical lasers is the wide range of radia tion wavelengths emitted by them: 1.3 - 26 ~m. The vibrational frequen cies of many molecules fall within this range so that they may convenient ly be used for the operation of such lasers. Progress in the development of chemical lasers is intimately con nected with advances in related fields such as gas dynamics, chemical reaction kinetics, and research into the energy relaxation and transfer processes in molecular systems.
Author: Karl L. Kompa
Publisher:
ISBN:
Category : Chemical bonds
Languages : en
Pages : 108
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Book Description
Author: Dieter Bäuerle
Publisher: Springer Science & Business Media
ISBN: 3642176135
Category : Science
Languages : en
Pages : 846
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Book Description
Laser Processing and Chemistry gives an overview of the fundamentals and applications of laser-matter interactions, in particular with regard to laser material processing. Special attention is given to laser-induced physical and chemical processes at gas-solid, liquid-solid, and solid-solid interfaces. Starting with the background physics, the book proceeds to examine applications of laser techniques in micro-machining, and the patterning, coating, and modification of material surfaces. This fourth edition has been revised and enlarged to cover new topics such as 3D microfabrication, advances in nanotechnology, ultrafast laser technology and laser chemical processing (LCP). Graduate students, physicists, chemists, engineers, and manufacturers alike will find this book an invaluable reference work on laser processing.
Author: Monique M. Martin
Publisher: Elsevier Science Limited
ISBN: 9780444516565
Category : Science
Languages : en
Pages : 569
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Book Description
This book reflects the heights of knowledge of ultrafast chemical processes attained in these early years of the 21st century : the latest research in femtosecond and picosecond molecular processes in Chemistry and Biology, carried out around the world, is described here in more than 110 articles. The results were presented and discussed at the VIth International Conference on Femtochemistry, in Paris, France, from July 6 to July 10, 2003. The articles published here were reviewed by referees selected from specialists in the Femtochemistry community, guaranteeing a collective responsability for the quality of the research reported in the next 564 pages. Femtochemistry is an ever-growing field, where new research areas are constantly opening up, and one which both stimulates and accompanies the development of ultrafast technologies. The increasing interest in femtobiology and chemistry at the frontier with biology is an obvious indicator of the present impact of life sciences in our society. New materials and reactions at surfaces are also some of the relatively new topics that promise rapid developments. New methodologies and technologies for probing and following in real time molecular dynamical phenomena have appeared within the last ten years or so. These methods, based on multidimensional IR spectroscopies, ultrafast X-ray and electron diffraction techniques, are well represented in this book. Of ever-improving performance, they are now applied to the characterization of structural dynamics of an increasing number of chemical and biological systems. This book reports the state of research in Femtochemistry and Femtobiology presented at Paris, at the Maison de la Chimie, in July 2003, representing the tenth anniversary of the conference. * Overview of the most recent research on ultrafast events * Application of new methodologies on chemical and biological systems * Contributions by key players in the field
Author: C. Bradley Moore
Publisher: Elsevier
ISBN: 0323157084
Category : Science
Languages : en
Pages : 299
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Book Description
Chemical and Biochemical Applications of Lasers, Volume II illustrates the current and potential applications of lasers in new fields of research in chemistry, biology, and other important fields. The book covers the laser spectroscopy of molecular jets; methods of high-resolution spectroscopy; vibrational relaxation in condensed phases; the distributions of quantum states encountered in chemical lasers and laser-induced chemical reactions; the hydrodynamics of biological systems; and developments in lasers such as the rare gas halide ultraviolet laser, which will find important new applications in chemistry and biology. Chemists, biologists, and physicists will find the book educational and insightful.
