Kinetics of Free Radical Reactions Generated by Laser Flash Photolysis of Oh+Cl- and So4-+Cl- in the Aqueous Phase -chemical Mechanism, Kinetics Data and Their Implications PDF Download
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Author: Xiaoying Yu
Publisher:
ISBN:
Category :
Languages : en
Pages : 498
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Author: Xiaoying Yu
Publisher:
ISBN:
Category :
Languages : en
Pages : 498
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Book Description
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 850
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Author: Yong Liu
Publisher:
ISBN:
Category :
Languages : en
Pages : 404
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Author:
Publisher:
ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 816
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Author: Chao Yan
Publisher:
ISBN:
Category :
Languages : en
Pages : 198
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The kinetics of several free radical-radical reactions was studied using pulsed laser photolysis coupled to transient UV-vis absorption spectroscopy over the 292 – 714 K temperature range and the 1- 100 bar pressure range. Free radicals such as CH3, OH and Cl are generated by photodissociation of parent molecules; some other radicals such as CH3O2 and HO2 are generated in secondary reactions following the initial photodissociation. Different free radicals are monitored at different wavelengths depending on their UV absorption spectra. Quantitative measurements of the concentrations of free radicals relay upon the absolute intensity of photolysis laser light determined by well characterized in situ actinometry. Experimental temporal absorption profiles are fitted by numerical solutions of a system of differential equations (ODE) which correspond to the reaction mechanism.
Author:
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Category : Aeronautics
Languages : en
Pages : 1508
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Author:
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ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 434
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Theses on any subject submitted by the academic libraries in the UK and Ireland.
Author: Cornelie Bänsch
Publisher: Logos Verlag Berlin GmbH
ISBN: 3832546324
Category : Science
Languages : en
Pages : 196
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Book Description
Hydroxyl radicals (OH) play a key role in ignition processes and in the atmosphere. Thus, the detailed knowledge of the kinetics of OH reactions is crucial in combustion and atmospheric research. In this work, an experimental approach for time-resolved studies of OH radical reactions at high pressures with pulsed laser photolysis/laser-induced fluorescence was revised and the reactions of dimethyl ether, diethyl ether, and dimethoxymethane with OH radicals were investigated in detail. The results reveal a deeper insight into the reaction processes of ether compounds with OH in general, contributing to a better understanding of the combustion of different biofuels and fuel additives.
Author: Paola Calza
Publisher: Royal Society of Chemistry
ISBN: 1782620435
Category : Nature
Languages : en
Pages : 310
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Borne out of the current widespread interest in the pollution of water bodies, this book explores the latest research concerning the photochemical fate of organic pollutants in surface water. The main objective is to give insight into both the functioning of ecosystems and the behaviour of emerging pollutants in those ecosystems. Particular importance is dedicated to techniques that can be used in the field and in the laboratory for the detection of pollutants and of their transformation intermediates. The inclusion of photochemical processes that have not gained previous coverage will afford the reader novel insights, whilst the focus on modelling and transformation intermediates will ensure the title's relevance to academics, the chemical manufacturing industries and environmental assessment experts alike.
Author:
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 1120
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