Kinetics and mechanisms of the reduction of some platinum (IV) complexes by chromium (II). PDF Download
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Author: James Kenneth Beattie
Publisher:
ISBN:
Category : Chromium
Languages : en
Pages :
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Author: James Kenneth Beattie
Publisher:
ISBN:
Category : Chromium
Languages : en
Pages :
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Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 1390
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Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.
Author: David Wesley Carlyle
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 358
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Author: John S. Cardwell
Publisher:
ISBN:
Category : Chromium
Languages : en
Pages : 142
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Author:
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ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1396
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Author:
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Category :
Languages : en
Pages :
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Rate constants for the Pt(IV) + Sn(II) and the Pt(IV) + Cu(I) redox reactions have been measured under various conditions using spectrophotometric and amperometric methods respectively. Rate equations are given which describe the data for the two reactions. The rate of reduction of Pt(IV) by Sn(II) is much faster than the rate of formation of the 1:1 complex between Pt(II) and Sn(II). The rate of reduction by Sn(II) varies linearly with increasing chloride concentration in nitrate and sulphate solutions. A possible explanation is offered for the higher rates in perchlorate solutions. The data for the Pt(IV) + Cu(I) system indicate that the reaction proceeds via an intermediate containing Pt(III), but there is no evidence for the formation of Pt(III) in the reduction of Pt(IV) by Sn(II). The mechanisms for both reactions are discussed in terms of complementary and non-complementary processes.
Author: Joseph Richard Ward
Publisher:
ISBN:
Category : Hydrolysis
Languages : en
Pages : 222
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Author:
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ISBN:
Category : Dissertation abstracts
Languages : en
Pages : 872
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Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 998
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Author: Xerox University Microfilms
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 960
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