Kinetics and Dynamics of Oxidation Reactions Involving an Adsorbed CO Species. Second Year Annual Report, January 1, 1992--December 31, 1992 PDF Download
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Languages : en
Pages : 8
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Objectives were to formulate kinetic models/mechanistic sequences, and to develop bifunctional catalysts for selective oxidation of hdyrocarbons. Efforts are reported this year on 3 items: development of Fourier transform infrared emission spectroscopy to monitor near infrared (ir) under reaction conditions (ethylene oxidation on V2O5); kinetics study of methanol oxidation on supported Pt catalysts (methanol-rich feed the CO2 yield exhibits a maximum at an intermediate temperature); and comparative kinetics study of CO oxidation on Pt, Pd, and Rh. The ir spectra of V2O5 show a correlation between the ir features and the degree of surface oxidation. 4 figs. (DLC).
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Languages : en
Pages : 8
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Book Description
Objectives were to formulate kinetic models/mechanistic sequences, and to develop bifunctional catalysts for selective oxidation of hdyrocarbons. Efforts are reported this year on 3 items: development of Fourier transform infrared emission spectroscopy to monitor near infrared (ir) under reaction conditions (ethylene oxidation on V2O5); kinetics study of methanol oxidation on supported Pt catalysts (methanol-rich feed the CO2 yield exhibits a maximum at an intermediate temperature); and comparative kinetics study of CO oxidation on Pt, Pd, and Rh. The ir spectra of V2O5 show a correlation between the ir features and the degree of surface oxidation. 4 figs. (DLC).
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Category : Power resources
Languages : en
Pages : 754
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Category : Government reports announcements & index
Languages : en
Pages : 1834
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Category : Science
Languages : en
Pages : 704
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Author: Geological Survey (U.S.)
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Languages : en
Pages : 100
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Languages : en
Pages :
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Author: Bowker Editorial Staff
Publisher: R. R. Bowker
ISBN: 9780835231503
Category : Nature
Languages : en
Pages : 1792
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Category : Styrene
Languages : en
Pages : 176
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Category : Nitro compounds
Languages : en
Pages : 136
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Author: Ingmar Grenthe
Publisher: Elsevier Science & Technology
ISBN:
Category : Science
Languages : en
Pages : 744
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This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.
