Kinetic Modeling of Photodegradation of Water-Soluble Polymers in Batch Photochemical Reactor

Kinetic Modeling of Photodegradation of Water-Soluble Polymers in Batch Photochemical Reactor PDF Author: Dina Hamad
Publisher:
ISBN:
Category : Electronic books
Languages : en
Pages : 0

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Book Description
Synthetic water-soluble polymers, well-known refractory pollutants, are abundant in wastewater effluents since they are extensively used in industry in a wide range of applications. These polymers can be effectively degraded by advanced oxidation processes (AOPs). This entry thoroughly covers the development of the photochemical kinetic model of the polyvinyl alcohol (PVA) degradation in UV/H2O2 advanced oxidation batch process that describes the disintegration of the polymer chains in which the statistical moment approach is considered. The reaction mechanism used to describe the photo-degradation of polymers comprises photolysis, polymer chain scission, and mineralization reactions. The impact of operating conditions on the process performance is evaluated. Characterization of the polymer average molecular weights, total organic carbon, and hydrogen peroxide concentrations as essential factors in developing a reliable photochemical model of the UV/H2O2 process is discussed. The statistical moment approach is applied to model the molar population balance of live and dead polymer chains taking into account the probabilistic chain scissions of the polymer. The photochemical kinetic model provides a comprehensive understanding of the impact of the design and operational variables.

Kinetic Modeling of Photodegradation of Water-Soluble Polymers in Batch Photochemical Reactor

Kinetic Modeling of Photodegradation of Water-Soluble Polymers in Batch Photochemical Reactor PDF Author: Dina Hamad
Publisher:
ISBN:
Category : Electronic books
Languages : en
Pages : 0

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Book Description
Synthetic water-soluble polymers, well-known refractory pollutants, are abundant in wastewater effluents since they are extensively used in industry in a wide range of applications. These polymers can be effectively degraded by advanced oxidation processes (AOPs). This entry thoroughly covers the development of the photochemical kinetic model of the polyvinyl alcohol (PVA) degradation in UV/H2O2 advanced oxidation batch process that describes the disintegration of the polymer chains in which the statistical moment approach is considered. The reaction mechanism used to describe the photo-degradation of polymers comprises photolysis, polymer chain scission, and mineralization reactions. The impact of operating conditions on the process performance is evaluated. Characterization of the polymer average molecular weights, total organic carbon, and hydrogen peroxide concentrations as essential factors in developing a reliable photochemical model of the UV/H2O2 process is discussed. The statistical moment approach is applied to model the molar population balance of live and dead polymer chains taking into account the probabilistic chain scissions of the polymer. The photochemical kinetic model provides a comprehensive understanding of the impact of the design and operational variables.

Kinetic Modeling for Environmental Systems

Kinetic Modeling for Environmental Systems PDF Author: Rehab Abdel Rahman
Publisher: BoD – Books on Demand
ISBN: 1789847265
Category : Technology & Engineering
Languages : en
Pages : 101

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Book Description
The continuous increase in human activities affects the environment in notable ways; these effects need to be monitored and controlled when appropriate to ensure the sustainability of our lives. Environmental pollution is one of the major problems associated with human activities as a result of routine and accidental releases. Currently, pollution prevention, control, and affected environment remediation receive great attention globally. This attention has led to a continuous increase in research efforts that aim to understand, simulate, and predict important processes that affect pollutant generation and migration. Optimization of chemical and physical reactions within different waste treatment technologies and remediation projects are the focus of many research projects worldwide. This book presents some kinetic models that could be used to support pollution prevention, control, and environmental assessments of human activities.

Advanced Oxidation Processes for Micropollutant Remediation

Advanced Oxidation Processes for Micropollutant Remediation PDF Author: Mohammad Khalid
Publisher: CRC Press
ISBN: 1000906590
Category : Technology & Engineering
Languages : en
Pages : 255

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Book Description
Advanced Oxidation Processes for Micropollutant Remediation covers current state-of-the-art in advanced oxidation processes (AOP) for removal of micropollutants from industrial and pharmaceutical wastewater. It covers various AOP-based techniques like Fenton process, ozonation, hydrogen peroxide, ultraviolet radiation, electrochemical oxidation, ultrasonic irradiation, and other hybrid technologies. It focuses on aspects like impact of micropollutants on the ecosystems, different types of AOPs, their principles, applications, and challenges in implementing these techniques and their future perspectives. Features: Presents state-of-the-art in advanced oxidation processes (AOP) techniques along with hybrid technologies Covers latest advances in technological know-how for remediation of wastewater soiled with micropollutants Discusses pressing environmental pollution issues associated with AOPs needed for wastewater remediation Presents future perspective as well as techno-economic analysis in implementing various AOPs Reviews strategies to limit the micropollutants in water bodies This book is aimed at graduate students and researchers in chemical and industrial engineering, environmental science, and wastewater treatment.

Heterogeneous Photocatalysis

Heterogeneous Photocatalysis PDF Author: M. Schiavello
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 218

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Book Description
Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.

Advanced Oxidation Processes for Water and Wastewater Treatment

Advanced Oxidation Processes for Water and Wastewater Treatment PDF Author: Simon Parsons
Publisher: IWA Publishing
ISBN: 1843390175
Category : Science
Languages : en
Pages : 370

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Book Description
The suitability of Advanced Oxidation Processes (AOPs) for pollutant degradation was recognised in the early 1970s and much research and development work has been undertaken to commercialise some of these processes. AOPs have shown great potential in treating pollutants at both low and high concentrations and have found applications as diverse as ground water treatment, municipal wastewater sludge destruction and VOCs control. Advanced Oxidation Processes for Water and Wastewater Treatment is an overview of the advanced oxidation processes currently used or proposed for the remediation of water, wastewater, odours and sludge. The book contains two opening chapters which present introductions to advanced oxidation processes and a background to UV photolysis, seven chapters focusing on individual advanced oxidation processes and, finally, three chapters concentrating on selected applications of advanced oxidation processes. Advanced Oxidation Processes for Water and Wastewater Treatment will be invaluable to readers interested in water and wastewater treatment processes, including professionals and suppliers, as well as students and academics studying in this area. Dr Simon Parsons is a Senior Lecturer in Water Sciences at Cranfield University with ten years' experience of industrial and academic research and development.

Advanced Oxidation Processes for Water Treatment

Advanced Oxidation Processes for Water Treatment PDF Author: Mihaela I. Stefan
Publisher: IWA Publishing
ISBN: 1780407181
Category : Science
Languages : en
Pages : 712

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Book Description
Advanced Oxidation Processes (AOPs) rely on the efficient generation of reactive radical species and are increasingly attractive options for water remediation from a wide variety of organic micropollutants of human health and/or environmental concern. Advanced Oxidation Processes for Water Treatment covers the key advanced oxidation processes developed for chemical contaminant destruction in polluted water sources, some of which have been implemented successfully at water treatment plants around the world. The book is structured in two sections; the first part is dedicated to the most relevant AOPs, whereas the topics covered in the second section include the photochemistry of chemical contaminants in the aquatic environment, advanced water treatment for water reuse, implementation of advanced treatment processes for drinking water production at a state-of-the art water treatment plant in Europe, advanced treatment of municipal and industrial wastewater, and green technologies for water remediation. The advanced oxidation processes discussed in the book cover the following aspects: - Process principles including the most recent scientific findings and interpretation. - Classes of compounds suitable to AOP treatment and examples of reaction mechanisms. - Chemical and photochemical degradation kinetics and modelling. - Water quality impact on process performance and practical considerations on process parameter selection criteria. - Process limitations and byproduct formation and strategies to mitigate any potential adverse effects on the treated water quality. - AOP equipment design and economics considerations. - Research studies and outcomes. - Case studies relevant to process implementation to water treatment. - Commercial applications. - Future research needs. Advanced Oxidation Processes for Water Treatment presents the most recent scientific and technological achievements in process understanding and implementation, and addresses to anyone interested in water remediation, including water industry professionals, consulting engineers, regulators, academics, students. Editor: Mihaela I. Stefan - Trojan Technologies - Canada

Dissertation Abstracts International

Dissertation Abstracts International PDF Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 862

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Book Description


Antimicrobial Resistance in Wastewater Treatment Processes

Antimicrobial Resistance in Wastewater Treatment Processes PDF Author: Patricia L. Keen
Publisher: John Wiley & Sons
ISBN: 1119192439
Category : Science
Languages : en
Pages : 390

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Book Description
Antimicrobial resistance is arguably the greatest threat to worldwide human health. This book evaluates the roles of human water use, treatment and conservation in the development and spread of antimicrobial resistance. Designed as a companion volume to Antimicrobial Resistance in the Environment (Wiley-Blackwell, 2012), this book is a multi-disciplinary synthesis of topics related to antimicrobial resistance and wastewater treatment processes. Antimicrobial Resistance in Wastewater Treatment Processes assembles detailed discussions written by many of the world's best-known experts in microbiology, civil engineering, chemistry, environmental science, public health and related fields. The book presents a collection of subjects that includes: Current knowledge of the role of the environment in development and spread of antimicrobial resistance Chemical analysis of antibiotics in environmental samples Molecular methods for analysis of antimicrobial resistance genes Advanced wastewater treatment processes and antimicrobial resistance effects Public perception of risk related to health consequences of antimicrobial resistance Public health implications of antimicrobial resistance with focus on wastewater treatment processes Antimicrobial resistance has gained a foothold in the global consciousness as a serious public health threat. There is a much greater appreciation for the role of the environment in the dissemination of antimicrobial resistance and the effects of pollutants that can potentially promote development of resistance in bacteria. Contaminants released from wastewater treatment plants are a concern. In Antimicrobial Resistance in Wastewater Treatment Processes, readers will be guided through examinations of the current science related to this important health issue.

Photocatalytic Reaction Engineering

Photocatalytic Reaction Engineering PDF Author: Hugo de Lasa
Publisher: Springer Science & Business Media
ISBN: 0387275916
Category : Science
Languages : en
Pages : 194

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Book Description
Heterogeneous photocatalysis is a novel technique for water purification. Publications on photocatalysis span a relatively recent period of not more than 25 years. This is a technique that, according to our extensive experience on the development of laboratory scale and pilot plant units, has great promise to eliminate water and air pollutants. Photocatalysis offers much more than competitive techniques where pollutants are transferred from phases; photocatalysis can achieve complete mineralization of pollutants leaving non-toxic species such as CO2 and H2O and can be exploited at close to room temperature and ambient pressure.

Heterogeneous Photocatalysis

Heterogeneous Photocatalysis PDF Author: Mario J. Muñoz-Batista
Publisher: Springer Nature
ISBN: 3030494926
Category : Science
Languages : en
Pages : 301

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Book Description
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. The chapter "Mechanochemical Forces as a Synthetic Tool for Zero and One-Dimensional Titanium Oxide-Based Nano-photocatalysts" is available open access under a CC BY 4.0 License via link.springer.com.