Kinetic Modeling of Hydrocarbon Autoignition at Low and Intermediate Temperatures in a Rapid Compression Machine PDF Download
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Author:
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Category :
Languages : en
Pages :
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Book Description
A computer model is used to examine oxidation of hydrocarbon fuels in a rapid compression machine. For one of the fuels studied, n-heptane, significant fuel consumption is computed to take place during the compression stroke under some operating conditions, while for the less reactive n-pentane, no appreciable fuel consumption occurs until after the end of compression. The third fuel studied, a 60 PRF mixture of iso-octane and n-heptane, exhibits behavior that is intermediate between that of n-heptane and n-pentane. The model results indicate that computational studies of rapid compression machine ignition must consider fuel reaction during compression in order to achieve satisfactory agreement between computed and experimental results.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
A computer model is used to examine oxidation of hydrocarbon fuels in a rapid compression machine. For one of the fuels studied, n-heptane, significant fuel consumption is computed to take place during the compression stroke under some operating conditions, while for the less reactive n-pentane, no appreciable fuel consumption occurs until after the end of compression. The third fuel studied, a 60 PRF mixture of iso-octane and n-heptane, exhibits behavior that is intermediate between that of n-heptane and n-pentane. The model results indicate that computational studies of rapid compression machine ignition must consider fuel reaction during compression in order to achieve satisfactory agreement between computed and experimental results.
Author:
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ISBN:
Category :
Languages : en
Pages : 36
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Book Description
In this work, numerical and experimental techniques are used to investigate the effect of the position of the double bond on the ignition properties of pentene and hexene linear isomers. A wide-range kinetic model for the oxidation of C5-C6 linear alkenes has been developed. Literature rapid compression machine data were used to validate the model at low temperatures and new shock tube experiments were performed in order to assess the behavior of the considered alkenes in the high temperature region. Some interesting inversions in the relative reactivity of the isomers were detected. The model successfully reproduced the measured behavior and allowed to explain the reason of these reactivity changes. The information gathered will be applied to the development of the kinetic mechanisms of larger unsaturated surrogate components.
Author: H Zhao
Publisher: Elsevier
ISBN: 184569354X
Category : Technology & Engineering
Languages : en
Pages : 557
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Book Description
Homogeneous charge compression ignition (HCCI)/controlled auto-ignition (CAI) has emerged as one of the most promising engine technologies with the potential to combine fuel efficiency and improved emissions performance, offering reduced nitrous oxides and particulate matter alongside efficiency comparable with modern diesel engines. Despite the considerable advantages, its operational range is rather limited and controlling the combustion (timing of ignition and rate of energy release) is still an area of on-going research. Commercial applications are, however, close to reality.HCCI and CAI engines for the automotive industry presents the state-of-the-art in research and development on an international basis, as a one-stop reference work. The background to the development of HCCI / CAI engine technology is described. Basic principles, the technologies and their potential applications, strengths and weaknesses, as well as likely future trends and sources of further information are reviewed in the areas of gasoline HCCI / CAI engines; diesel HCCI engines; HCCI / CAI engines with alternative fuels; and advanced modelling and experimental techniques. The book provides an invaluable source of information for scientific researchers, R&D engineers and managers in the automotive engineering industry worldwide. Presents the state-of-the-art in research and development on an international basis An invaluable source of information for scientific researchers, R&D engineers and managers in the automotive engineering industry worldwide Looks at one of the most promising engine technologies around
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Category :
Languages : en
Pages : 8
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Book Description
Detailed kinetic models of pyrolysis and combustion of hydrocarbon fuels are nowadays widely used in the design of internal combustion engines and these models are effectively applied to help meet the increasingly stringent environmental and energetic standards. In previous studies by the combustion community, such models not only contributed to the understanding of pure component combustion, but also provided a deeper insight into the combustion behavior of complex mixtures. One of the major challenges in this field is now the definition and the development of appropriate surrogate models able to mimic the actual features of real fuels. Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. Their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. Aside the most commonly used surrogates containing iso-octane and n-heptane only, the so called Primary Reference Fuels (PRF), new mixtures have recently been suggested to extend the reference components in surrogate mixtures to also include alkenes and aromatics. It is generally agreed that, including representative species for all the main classes of hydrocarbons which can be found in real fuels, it is possible to reproduce very effectively in a wide range of operating conditions not just the auto-ignition propensity of gasoline or Diesel fuels, but also their physical properties and their combustion residuals [1]. In this work, the combustion behavior of several components relevant to gasoline surrogate formulation is computationally examined. The attention is focused on the autoignition of iso-octane, hexene and their mixtures. Some important issues relevant to the experimental and modeling investigation of such fuels are discussed with the help of rapid compression machine data and calculations. Following the model validation, the behavior of mixtures is discussed on the basis of computational results.
Author:
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Category :
Languages : en
Pages : 14
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Book Description
The use of gasoline in homogeneous charge compression ignition engines (HCCI) and in duel fuel diesel - gasoline engines, has increased the need to understand its compression ignition processes under engine-like conditions. These processes need to be studied under well-controlled conditions in order to quantify low temperature heat release and to provide fundamental validation data for chemical kinetic models. With this in mind, an experimental campaign has been undertaken in a rapid compression machine (RCM) to measure the ignition of gasoline mixtures over a wide range of compression temperatures and for different compression pressures. By measuring the pressure history during ignition, information on the first stage ignition (when observed) and second stage ignition are captured along with information on the phasing of the heat release. Heat release processes during ignition are important because gasoline is known to exhibit low temperature heat release, intermediate temperature heat release and high temperature heat release. In an HCCI engine, the occurrence of low-temperature and intermediate-temperature heat release can be exploited to obtain higher load operation and has become a topic of much interest for engine researchers. Consequently, it is important to understand these processes under well-controlled conditions. A four-component gasoline surrogate model (including n-heptane, iso-octane, toluene, and 2-pentene) has been developed to simulate real gasolines. An appropriate surrogate mixture of the four components has been developed to simulate the specific gasoline used in the RCM experiments. This chemical kinetic surrogate model was then used to simulate the RCM experimental results for real gasoline. The experimental and modeling results covered ultra-lean to stoichiometric mixtures, compressed temperatures of 640-950 K, and compression pressures of 20 and 40 bar. The agreement between the experiments and model is encouraging in terms of first-stage (when observed) and second-stage ignition delay times and of heat release rate. The experimental and computational results are used to gain insight into low and intermediate temperature processes during gasoline ignition.
Author:
Publisher: Elsevier
ISBN: 0444640886
Category : Technology & Engineering
Languages : en
Pages : 1034
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Book Description
Mathematical Modelling of Gas-Phase Complex Reaction Systems: Pyrolysis and Combustion, Volume 45, gives an overview of the different steps involved in the development and application of detailed kinetic mechanisms, mainly relating to pyrolysis and combustion processes. The book is divided into two parts that cover the chemistry and kinetic models and then the numerical and statistical methods. It offers a comprehensive coverage of the theory and tools needed, along with the steps necessary for practical and industrial applications. Details thermochemical properties and "ab initio" calculations of elementary reaction rates Details kinetic mechanisms of pyrolysis and combustion processes Explains experimental data for improving reaction models and for kinetic mechanisms assessment Describes surrogate fuels and molecular reconstruction of hydrocarbon liquid mixtures Describes pollutant formation in combustion systems Solves and validates the kinetic mechanisms using numerical and statistical methods Outlines optimal design of industrial burners and optimization and dynamic control of pyrolysis furnaces Outlines large eddy simulation of turbulent reacting flows
Author:
Publisher:
ISBN:
Category : Power resources
Languages : en
Pages : 462
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Author: Mickael Chomier
Publisher:
ISBN:
Category : Chemical kinetics
Languages : en
Pages : 72
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Book Description
The objective of this thesis is to understand the influence of the non-ideal effects in Rapid Compression Machines (RCM), namely the vortex roll-up and mass flow into the crevice, on autoignition. The effect of the vortex roll-up is studied computationally using CFD simulations of autoignition in a RCM. Whereas, the effect of the crevice mass flow is investigated experimentally by studying isooctane autoignition. Over the last two decades, experimental data of the nature of species evolution profiles and ignition delays from RCMs has been used to develop and validate chemical kinetic mechanisms at low-to-intermediate temperatures and elevated pressures. A significant portion of this overall dataset is from RCMs that had not employed a creviced piston to contain the roll-up vortex. The detrimental influence of the roll-up vortex and the thermokinetic interactions due to the resulting temperature non-homogeneity during the negative temperature coefficient (ntc) regime have been documented in the literature. However, the adequacy of the homogeneous modeling of RCMs without creviced pistons during reactive conditions has not been investigated. In this work, computational fluid dynamics simulations of an RCM without a creviced piston are conducted for autoignition of n-heptane over the entire ntc regime over a range of compressed pressures from 5 to 18 bar. The results from the CFD simulations highlight the non-homogeneity of autoignition and reveal significant quantitative discrepancy in comparison to homogeneous modeling, particularly for the hot ignition delay in the ntc regime. Specifically, the roll-up vortex induced temperature non-homogeneity leads to diminution of the ntc behavior. The experimental data from RCMs without creviced piston needs to be taken with caution for quantitative validation and refinement of kinetic mechanism, particularly at conditions when ntc behavior is highly pronounced. Rapid Compression Machines (RCMs) often employ creviced pistons to suppress the formation of the roll-up vortex. However, the use of a creviced piston promotes mass flow into the crevice when heat release takes place in the main combustion chamber. This multi-dimensional effect is not accounted for in the prevalent volumetric expansion approach for modeling RCMs. The method of crevice containment, on the other hand, avoids post-compression mass flow into the crevice. In order to assess the effect of the crevice mass flow on ignition in a RCM, experiments were conducted for autoignition of isooctane in a RCM with creviced piston in the temperature range of 680-940 K and at compressed pressures of ~15.5 and 20.5 bar in two ways. In one situation, post-compression mass flow to the crevice is avoided by crevice containment and in other it is allowed. Experiments show that the crevice mass flow can lead to significantly longer ignition delays. Experimental data from both scenarios is modeled using adiabatic volumetric expansion approach and an available kinetic mechanism. The simulated results show less pronounced effect of crevice mass flow on ignition delay and highlight the deficiency of the volumetric expansion method owing to its inability to describe coupled physical-chemical processes in the presence of heat release. Results indicate that it is important to include crevice mass flow in the physical model for improved modeling of experimental data from RCMs for consistent interpretation of chemical kinetics. The use of crevice containment, however, avoids the issue of mass flow altogether and offers an alternative and sound approach.
Author: M.A. Nettleton
Publisher: Springer Science & Business Media
ISBN: 9400931492
Category : Medical
Languages : en
Pages : 266
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Book Description
My introduction to the fascinating phenomena associated with detonation waves came through appointments as an external fellow at the Department of Physics, University College of Wales, and at the Department of Mechanical Engineering, University of Leeds. Very special thanks for his accurate guidance through the large body of information on gaseous detonations are due to Professor D. H. Edwards of University College of Wales. Indeed, the onerous task of concisely enumerating the key features of unidimensional theories of detonations was undertaken by him, and Chapter 2 is based on his initial draft. When the text strays to the use of we, it is a deserved acknow ledgement of his contribution. Again, I should like to thank Professor D. Bradley of Leeds University for his enthusiastic encouragement of my efforts at developing a model of the composition limits of detonability through a relationship between run-up distance and composition of the mixture. The text has been prepared in the context of these fellowships, and I am grateful to the Central Electricity Generating Board for its permission to accept these appointments.
Author: Michael A. Liberman
Publisher: Springer Science & Business Media
ISBN: 3540787593
Category : Science
Languages : en
Pages : 368
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Book Description
Most of the material covered in this book deals with the fundamentals of chemistry and physics of key processes and fundamental mechanisms for various combustion and combustion related phenomena in gaseous combustible mixture. It provides the reader with basic knowledge of burning processes and mechanisms of reaction wave propagation. The combustion of a gas mixture (flame, explosion, detonation) is necessarily accompanied by motion of the gas. The process of combustion is therefore not only a chemical phenomenon but also one of gas dynamics. The material selection focuses on the gas phase and with premixed gas combustion. Premixed gas combustion is of practical importance in engines, modern gas turbine and explosions, where the fuel and air are essentially premixed, and combustion occurs by the propagation of a front separating unburned mixture from fully burned mixture. Since premixed combustion is the most fundamental and potential for practical applications, the emphasis in the present work is be placed on regimes of premixed combustion. This text is intended for graduate students of different specialties, including physics, chemistry, mechanical engineering, computer science, mathematics and astrophysics.
