Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes PDF Download
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Author: Mark Greenhalgh
Publisher: Springer
ISBN: 3319336630
Category : Science
Languages : en
Pages : 306
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Book Description
This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million.
Author: Mark Greenhalgh
Publisher: Springer
ISBN: 3319336630
Category : Science
Languages : en
Pages : 306
Get Book
Book Description
This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million.
Author: Jianbo Wang
Publisher: Springer
ISBN: 364231824X
Category : Science
Languages : en
Pages : 276
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Book Description
Stereoselective Synthesis of Tetrasubstituted Alkenes via Torquoselectivity-Controlled Olefination of Carbonyl Compounds with Ynolates, by Mitsuru Shindo and Kenji Matsumoto.- Stereoselective Synthesis of Z-Alkenes, by Woon-Yew Siau, Yao Zhang and Yu Zhao.- Stereoselective Synthesis of Mono-fluoroalkenes, by Shoji Hara.- Recent Advances in Stereoselective Synthesis of 1,3-Dienes, by Michael De Paolis, Isabelle Chataigner and Jacques Maddaluno.- Selective Olefination of Carbonyl Compounds via Metal-Catalyzed Carbene Transfer from Diazo Reagents, by Yang Hu and X. Peter Zhang.- Selective Alkene Metathesis in the Total Synthesis of Complex Natural Product, by Xiaoguang Lei and Houhua Li.- Olefination Reactions of Phosphorus-Stabilized Carbon Nucleophiles, by Yonghong Gu and Shi-Kai Tian.- Alkene Synthesis Through Transition Metal-Catalyzed Cross-Coupling of N-Tosylhydrazones, by Yan Zhang and Jianbo Wang.
Author: Uwe Schneider
Publisher: Royal Society of Chemistry
ISBN: 178801118X
Category : Technology & Engineering
Languages : en
Pages : 431
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Book Description
Considering the limited resources of our planet, earth-abundant elements will have to be explored increasingly in the future. This book highlights the uses of the most earth-abundant elements in catalysis and will be of interest to graduates, academic researchers and practitioners in catalysis.
Author: Peng-Fei Xu
Publisher: John Wiley & Sons
ISBN: 1118016025
Category : Science
Languages : en
Pages : 440
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Book Description
Demonstrates the advantages of catalytic cascade reactions for synthesizing natural products and pharmaceuticals Riding the wave of green chemistry, catalytic cascade reactions have become one of the most active research areas in organic synthesis. During a cascade reaction, just one reaction solvent, one workup procedure, and one purification step are needed, thus significantly increasing synthetic efficiency. Featuring contributions from an international team of pioneers in the field, Catalytic Cascade Reactions demonstrates the versatility and application of these reactions for synthesizing valuable compounds. The book examines both organocatalysis and transition-metal catalysis reactions, bringing readers up to date with the latest discoveries and activities in all major areas of catalytic cascade reaction research. Catalytic Cascade Reactions begins with three chapters dedicated to organocatalytic cascade reactions, exploring amines, Brønsted acids, and the application of organocatalytic cascade reactions in natural product synthesis and drug discovery. Next, the book covers: Gold-catalyzed cascade reactions Cascade reactions catalyzed by ruthenium, iron, iridium, rhodium, and copper Palladium-catalyzed cascade reactions of alkenes, alkynes, and allenes Application of transition-metal catalyzed cascade reactions in natural product synthesis and drug discovery Engineering mono- and multifunctional nanocatalysts for cascade reactions Multiple-catalyst-promoted cascade reactions All chapters are thoroughly referenced, providing quick access to important original research findings and reviews so that readers can explore individual topics in greater depth. Drawing together and analyzing published findings scattered across the literature, this book provides a single source that encapsulates our current understanding of catalytic cascade processes. Moreover, it sets the stage for the development of new catalytic cascade reactions and their applications.
Author:
Publisher: Newnes
ISBN: 008097743X
Category : Science
Languages : en
Pages : 9815
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Book Description
The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively
Author: Peng-Fei Xu
Publisher: John Wiley & Sons
ISBN: 1118356632
Category : Science
Languages : en
Pages : 440
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Book Description
Demonstrates the advantages of catalytic cascade reactionsfor synthesizing natural products and pharmaceuticals Riding the wave of green chemistry, catalytic cascade reactionshave become one of the most active research areas in organicsynthesis. During a cascade reaction, just one reaction solvent,one workup procedure, and one purification step are needed, thussignificantly increasing synthetic efficiency. Featuring contributions from an international team of pioneersin the field, Catalytic Cascade Reactions demonstrates theversatility and application of these reactions for synthesizingvaluable compounds. The book examines both organocatalysis andtransition-metal catalysis reactions, bringing readers up to datewith the latest discoveries and activities in all major areas ofcatalytic cascade reaction research. Catalytic Cascade Reactions begins with three chaptersdedicated to organocatalytic cascade reactions, exploring amines,Brønsted acids, and the application of organocatalytic cascadereactions in natural product synthesis and drug discovery. Next,the book covers: Gold-catalyzed cascade reactions Cascade reactions catalyzed by ruthenium, iron, iridium,rhodium, and copper Palladium-catalyzed cascade reactions of alkenes, alkynes, andallenes Application of transition-metal catalyzed cascade reactions innatural product synthesis and drug discovery Engineering mono- and multifunctional nanocatalysts for cascadereactions Multiple-catalyst-promoted cascade reactions All chapters are thoroughly referenced, providing quick accessto important original research findings and reviews so that readerscan explore individual topics in greater depth. Drawing together and analyzing published findings scatteredacross the literature, this book provides a single source thatencapsulates our current understanding of catalytic cascadeprocesses. Moreover, it sets the stage for the development of newcatalytic cascade reactions and their applications.
Author: Bernd Plietker
Publisher: John Wiley & Sons
ISBN: 3527623280
Category : Science
Languages : en
Pages : 295
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Book Description
This first comprehensive book to cover this exciting field also deals with the biological aspects, such as enzymes with iron. Following an introduction, this handy reference and handbook goes on to deal with reductions, oxidations of C, H- and C=C bonds, oxidative allylic oxygenation and amination, the oxidation of heteroatoms, cross coupling reactions, aromatic and nucleophilic substitutions, addition to carbonyl compounds, and cyclisations as well as ring opening reactions. The chapters are clearly classified according to the reaction type, allowing readers to quickly locate the desired information.
Author: Ramon Rios Torres
Publisher: John Wiley & Sons
ISBN: 1118308638
Category : Science
Languages : en
Pages : 422
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Book Description
The Pauson-Khand reaction is an important reaction in the field of organic chemistry. It involves the transition-metal catalysed cycloaddition of an alkyne, an alkene and carbon monoxide, to produce cyclopentenones. The importance of this reaction originates from its high value in transforming simple components into the synthetically useful cyclopentenone unit, in which a high degree of molecular complexity can be achieved in a single step, with impressive stereochemical and regiochemical control. The Pauson-Khand Reaction investigates the nature and many variations of this reaction. Topics covered include: the mechanisms of Pauson‐Khand-type reactions non chiral intramolecular and intermolecular versions of Pauson‐Khand reactions asymmetric Pauson‐Khand reaction using chiral auxiliaries the enantioselective Pauson‐Khand reaction Pauson‐Khand reactions catalysed by metals other than cobalt unconventional Pauson‐Khand reactions the Pauson‐Khand reaction in total synthesis Presenting a comprehensive overview of this fundamental reaction, The Pauson-Khand Reaction will find a place on the bookshelves of any organic or organometallic chemist.
Author: Bernd Plietker
Publisher: Springer Science & Business Media
ISBN: 3642146694
Category : Science
Languages : en
Pages : 227
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Book Description
Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.
Author: A. C. Knipe
Publisher: John Wiley & Sons
ISBN: 1118941799
Category : Science
Languages : en
Pages : 1023
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Book Description
Organic Reaction Mechanisms 2014, the 50th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2014. The following classes of organic reaction mechanisms are comprehensively reviewed: Reaction of Aldehydes and Ketones and their Derivatives Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives Oxidation and Reduction Carbenes and Nitrenes Nucleophilic Aromatic Substitution Electrophilic Aromatic Substitution Carbocations Nucleophilic Aliphatic Substitution Carbanions and Electrophilic Aliphatic Substitution Elimination Reactions Polar Addition Reactions Cycloaddition Reactions Molecular Rearrangements An experienced team of authors compile these reviews every year, so that the reader can rely on a continuing quality of selection and presentation. This volume includes a 5-year cumulative index.
