Interfacial Electrochemistry

Interfacial Electrochemistry PDF Author: Wolfgang Schmickler
Publisher: Springer Science & Business Media
ISBN: 3642049370
Category : Science
Languages : en
Pages : 273

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Book Description
Electrochemistry is an old branch of physical chemistry. Due to the development of surface sensitive techniques, and a technological interest in fuel cells and batteries, it has recently undergone a rapid development. This textbook treats the field from a modern, atomistic point of view while integrating the older, macroscopic concepts. The increasing role of theory is reflected in the presentation of the basic ideas in a way that should appeal to experimentalists and theorists alike. Special care is taken to make the subject comprehensible to scientists from neighboring disciplines, especially from surface science. The book is suitable for an advanced course at the master or Ph.D. level, but should also be useful for practicing electrochemists, as well as to any scientist who wants to understand modern electrochemistry.

Interfacial Electrochemistry

Interfacial Electrochemistry PDF Author: Wolfgang Schmickler
Publisher: Springer Science & Business Media
ISBN: 3642049370
Category : Science
Languages : en
Pages : 273

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Book Description
Electrochemistry is an old branch of physical chemistry. Due to the development of surface sensitive techniques, and a technological interest in fuel cells and batteries, it has recently undergone a rapid development. This textbook treats the field from a modern, atomistic point of view while integrating the older, macroscopic concepts. The increasing role of theory is reflected in the presentation of the basic ideas in a way that should appeal to experimentalists and theorists alike. Special care is taken to make the subject comprehensible to scientists from neighboring disciplines, especially from surface science. The book is suitable for an advanced course at the master or Ph.D. level, but should also be useful for practicing electrochemists, as well as to any scientist who wants to understand modern electrochemistry.

Interfacial Electrochemistry

Interfacial Electrochemistry PDF Author: Andrzej Wieckowski
Publisher: Routledge
ISBN: 1351437569
Category : Science
Languages : en
Pages : 1008

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Book Description
This text probes topics and reviews progress in interfacial electrochemistry. It supplies chapter abstracts to give readers a concise overview of individual subjects and there are more than 1500 drawings, photographs, micrographs, tables and equations. The 118 contributors are international scholars who present theory, experimentation and applications.

Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry

Spectroscopic and Diffraction Techniques in Interfacial Electrochemistry PDF Author: C. GutiƩrrez
Publisher: Springer Science & Business Media
ISBN: 940113782X
Category : Science
Languages : en
Pages : 488

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Book Description
Electrochemistry is one of the oldest branches of Physical Chemistry. Having its foundations in the work of Faraday, Arrhenius and others, it evolved from the study of transport in electrolyte solutions to that of electrode kinetics. Kinetic methods are inherently unable to identify unequivocally the species involved in a reaction. Therefore, beginning in the 70s many spectroscopic and diffraction techniques were applied to the study of the electrode-electrolyte interface, in order to identify intermediary reaction species, and even the spatial arrangement of atoms or molecules at the interface. In order to disseminate these techniques, a NATO Advanced Sutdy Institute was held at Puerto de la Cruz, Tenerife (Canary Islands, Spain) from July 2 to 15, 1988. The Institute consisted of tutorial type lecutures, poster sessions, and round-table discussions. It was attended by over 65 participants from NATO-member countries, and others from Argentina and Japan. In the present volume most of the lectures presented at the Institute have been collected. At least one chapter is devoted to each technique. Emphasis has been made on case studies, rather than theory, which can be found in textbooks and other publications. Our purpose in this book is to help the electrochemists uninitiated in spectroscopic methods to decide which techniques would be suitable for application to their particular problems. We thank all the lecturers who contributed to this volume, and even those UHPs (Unrepentant Habitual Procrastinators) who did not in spite of our urgings to do so.

Catalysis in Electrochemistry

Catalysis in Electrochemistry PDF Author: Elizabeth Santos
Publisher: John Wiley & Sons
ISBN: 0470934735
Category : Science
Languages : en
Pages : 548

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Book Description
Catalysis in Electrochemistry: From Fundamental Aspects to Strategies for Fuel Cell Development is a modern, comprehensive reference work on catalysis in electrochemistry, including principles, methods, strategies, and applications. It points out differences between catalysis at gas/surfaces and electrochemical interfaces, along with the future possibilities and impact of electrochemical science on energy problems. This book contributes both to fundamental science; experience in the design, preparation, and characterization of electrocatalytic materials; and the industrial application of electrocatalytic materials for electrochemical reactions. This is an essential resource for scientists globally in academia, industry, and government institutions.

Analytical Electrochemistry

Analytical Electrochemistry PDF Author: Joseph Wang
Publisher: John Wiley & Sons
ISBN: 0471460796
Category : Science
Languages : en
Pages : 228

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Book Description
The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays

Solid State Electrochemistry

Solid State Electrochemistry PDF Author: Peter G. Bruce
Publisher: Cambridge University Press
ISBN: 9780521599498
Category : Science
Languages : en
Pages : 364

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Book Description
This book describes, for the first time in a modern text, the fundamental principles on which solid state electrochemistry is based. In this sense it is in contrast to other books in the field which concentrate on a description of materials. Topics include solid (ceramic) electrolytes, glasses, polymer electrolytes, intercalation electrodes, interfaces and applications. The different nature of ionic conductivity in ceramic, glassy and polymer electrolytes is described as are the thermodynamics and kinetics of intercalation reactions. The interface between solid electrolytes and electrodes is discussed and contrasted with the more conventional liquid state electrochemistry. The text provides an essential foundation of understanding for postgraduates or others entering the field for the first time and will also be of value in advanced undergraduate courses.

Handbook of Electrochemistry

Handbook of Electrochemistry PDF Author: Cynthia G. Zoski
Publisher: Elsevier
ISBN: 0444519580
Category : Science
Languages : en
Pages : 935

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Book Description
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Interfacial Catalysis

Interfacial Catalysis PDF Author: Alexander G. Volkov
Publisher: CRC Press
ISBN: 9780203910429
Category : Science
Languages : en
Pages : 690

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Book Description
A comprehensive volume on interfacial catalysis, this book includes contributions from an international group of specialists in chemistry, environmental science, informatics, physiology, nuclear energy, and physics. The editor has organized the material into the main topics of fundamental characteristics, phase transfer catalysis, reversed micelles, biological aspects, and interfacial photocatalysis. Individual topics include self-organized microheterogeneous structures, nanochemistry, interfacial catalysis in metal complexation, the role of water molecules in ion transfer at the oil/water interface, and ultrathin films in enhanced oil recovery.

Electrochemistry on Liquid/Liquid Interfaces

Electrochemistry on Liquid/Liquid Interfaces PDF Author: Petr Vanysek
Publisher: Springer Science & Business Media
ISBN: 3642489109
Category : Science
Languages : en
Pages : 111

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Book Description
A charge transfer across the interface between two immiscible liquid media has an important role both in nature and in man-designed applications. Ion transfer across the biological membranes, behavior of ion-selective electrodes with liquid membranes and similar sensors, extraction processes, phase transfer catalysis and applications in electroanalytical chemistry can serve as examples. Present interest in the interface between two immiscible electrolytes (liquid liquid or L/L interface) was originated by Koryta's idea (Koryta, Vanysek and Brezina 1976) that the interface between immiscible liquids could serve as a simple model for one half of a biological membrane in the contact with the surrounding electrolyte. It was also Koryta who started using the acronym ITIES (Interface between Two Immiscible Electrolyte Solutions) which generally encompasses all the phenomena discussed in this book. Physiological and electrochemical investigations have certainly well established tradition. In his classic experiments with frog thighs Luigi Galvani discovered in 1791 relationship between electricity and nerves and muscles. As outlined by Koryta and Stullk (1983) in the introduction to their book, the study of electrophysiological phenomena did not progress much for several decades and only a few experiments were performed. For instance M. Faraday (Williams, 1965) studied the electricity produced by an electric fish and Du Bois-Reymond (1848) suggested that the surface of biological formations have properties similar to the electrode of a galvanic cell. However, the properties of biological membrane could not be explained before the first concept of electrochemistry was postulated.

Redox Chemistry and Interfacial Behavior of Biological Molecules

Redox Chemistry and Interfacial Behavior of Biological Molecules PDF Author: Glenn Dryhurst
Publisher: Springer
ISBN: 9781461595366
Category : Science
Languages : en
Pages : 672

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Book Description
The papers in this book were presented at the Third International Symposium on Redox Mechanisms and Interfacial Properties of Molecules of Biological Importance held in Honolulu, Hawaii between October 19-23, 1987. This Symposium was held as part of the 172nd Meeting of The Electrochemical Society which was cosponsored by The Electrochemical Society of Japan with the cooperation of The Japan Society of Applied Physics. The aim of the Symposium was to bring together a group of electrochemists and bio-medical scientists with interests in electrochemistry from around the world to present their most current research results and/or to present up-to-date reviews of current areas of research activity. It is quite clear from the diversity of topics covered in the various papers that electrochemistry and electrochemical techniques and principles have much to contribute to our under standing of many important biochemical phenomena. For example, electrochemical studies are providing important insights into the redox properties of biomolecules ranging from relatively small organic molecules such as indoleamine neurotransmitters to very large organic/organometallic molecules which include various redox enzymes or model enzyme systems. Many of the most powerful analytical techniques are now being coupled to electrodes to monitor potential-controlled behaviors of bio logical molecules at charged interfaces. Electrochemical techniques are now being developed which permit extraordinarily small electrodes to be inserted into single cells to monitor electroactive biomolecules. Other microelectrodes are being employed to control cell growth and to manipulate single cells.