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Languages : en
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X-ray photoelectron spectroscopy (XPS) is a quantitative, chemically specific technique with a probing depth of a few angstroms to a few nanometers. It is therefore ideally suited to investigate the chemical nature of the surfaces of catalysts. Because of the scattering of electrons by gas molecules, XPS is generally performed under vacuum conditions. However, for thermodynamic and/or kinetic reasons, the catalyst's chemical state observed under vacuum reaction conditions is not necessarily the same as that of a catalyst under realistic operating pressures. Therefore, investigations of catalysts should ideally be performed under reaction conditions, i.e., in the presence of a gas or gas mixtures. Using differentially pumped chambers separated by small apertures, XPS can operate at pressures of up to 1 Torr, and with a recently developed differentially pumped lens system, the pressure limit has been raised to about 10 Torr. Here, we describe the technical aspects of high-pressure XPS and discuss recent applications of this technique to oxidation and heterogeneous catalytic reactions on metal surfaces.
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Languages : en
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Book Description
X-ray photoelectron spectroscopy (XPS) is a quantitative, chemically specific technique with a probing depth of a few angstroms to a few nanometers. It is therefore ideally suited to investigate the chemical nature of the surfaces of catalysts. Because of the scattering of electrons by gas molecules, XPS is generally performed under vacuum conditions. However, for thermodynamic and/or kinetic reasons, the catalyst's chemical state observed under vacuum reaction conditions is not necessarily the same as that of a catalyst under realistic operating pressures. Therefore, investigations of catalysts should ideally be performed under reaction conditions, i.e., in the presence of a gas or gas mixtures. Using differentially pumped chambers separated by small apertures, XPS can operate at pressures of up to 1 Torr, and with a recently developed differentially pumped lens system, the pressure limit has been raised to about 10 Torr. Here, we describe the technical aspects of high-pressure XPS and discuss recent applications of this technique to oxidation and heterogeneous catalytic reactions on metal surfaces.
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Languages : en
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X-ray photoelectron spectroscopy (XPS) is a powerful tool for surface and interface analysis, providing the elemental composition of surfaces and the local chemical environment of adsorbed species. Conventional XPS experiments have been limited to ultrahigh vacuum (UHV) conditions due to a short mean free path of electrons in a gas phase. The recent advances in instrumentation coupled with third-generation synchrotron radiation sources enables in-situ XPS measurements at pressures above 5 Torr. In this review, we describe the basic design of the ambient pressure XPS setup that combines differential pumping with an electrostatic focusing. We present examples of the application of in-situ XPS to studies of water adsorption on the surface of metals and oxides including Cu(110), Cu(111), TiO2(110) under environmental conditions of water vapor pressure. On all these surfaces we observe a general trend where hydroxyl groups form first, followed by molecular water adsorption. The importance of surface OH groups and their hydrogen bonding to water molecules in water adsorption on surfaces is discussed in detail.
Author: D. Briggs
Publisher: Wiley
ISBN: 9780471953401
Category : Science
Languages : en
Pages : 674
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Book Description
This is an updated manual covering the theory and practice of X-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) techniques for surface analysis. Topics covered include historical development; all relevant theory for data interpretation and a description of instrumentation; the major fields of applications, such as metallurgy, polymers, semiconductors, and corrosion science; catalysis; and many appendices of essential data for day-to-day use. This new edition also takes into account improvements in equipment, experimental procedures and data interpretation over the last seven years.
Author: J. H. D. Eland
Publisher: Elsevier
ISBN: 1483103218
Category : Science
Languages : en
Pages : 286
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Book Description
Photoelectron Spectroscopy: An Introduction to Ultraviolet Photoelectronspectroscopy in the Gas Phase, Second Edition Photoelectron Spectroscopy: An Introduction to Ultraviolet PhotoelectronSpectroscopy in the Gas Phase, Second Edition aims to give practical approach on the subject of photoelectron spectroscopy, as well as provide knowledge on the interpretation of the photoelectron spectrum. The book covers topics such as the principles and literature of photoelectron microscopy; the main features and analysis of photoelectron spectra; ionization techniques; and energies from the photoelectron spectra. Also covered in the book are topics suc as photoelectron band structure and the applications of photoelectron spectroscopy in chemistry. The text is recommended for students and practitioners of chemistry who would like to be familiarized with the concepts of photoelectron spectroscopy and its importance in the field.
Author: Mg Salya
Publisher:
ISBN: 9783096275958
Category : Science
Languages : en
Pages : 0
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Author: Spyridon Zafeiratos
Publisher: World Scientific
ISBN: 180061330X
Category : Science
Languages : en
Pages : 548
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Book Description
X-ray photoelectron spectroscopy (XPS) has become a standard practice technique, and automated XPS facilities can be found in industry and in universities all over the world. This transformed XPS from an advanced characterization method for dedicated research, to a rather standard analysis technique of surface analysis. The catalyst's surface state is probably the most prominent factor that influences the catalytic performance. It is therefore no surprise that XPS has become an indispensable tool in studies of solid catalysts. It has been directly used to investigate issues such as the surface composition of the active catalyst and reaction and deactivation mechanisms.The objective of this book is to provide a comprehensive overview of the current status and future perspectives of X-ray photoelectron spectroscopy dedicated to catalytic applications, including thermal catalysis, electrocatalysis, and photo(electro)catalysis. The book contains 13 chapters, starting with the necessary introduction of the technique background, including basic phenomena and instrumentation aspects. The second part of the book focuses on the presentation of long-established applications of the technique, such as XPS studies of model catalysts. Finally, the book describes relatively recent developments of this method for cutting-edge surface characterization mainly using synchrotron X-ray radiation.
Author: Joseph Woicik
Publisher: Springer
ISBN: 3319240439
Category : Science
Languages : en
Pages : 576
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Book Description
This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.
Author: Zhuoluo Albert Feng
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
At solid-gas electrochemical interfaces, gas molecules interact dynamically with surface ions and electrons. A fundamental understanding of the technologically important interfaces can lead to better fuel cells and electrolyzers. In the bulk of typical oxygen-ion-conducting solids, oxygen vacancies and mobile electrons migrate under the influence of concentration and electrostatic potential gradients. Similarly, at gas-solid interfaces, these charge carriers migrate across an electrochemical double layer. The two-way traffic of ions and electrons contrasts sharply with conventional metal-based electrocatalysis, in which only electrons are transferred. This type of ion insertion reaction is ubiquitous in energy conversion and storage devices, such as lithium ion batteries, water-splitting membranes and solid oxide fuel cells. CeO2-[delta] (ceria) is a model oxygen-ion-conducting electrode, which is commonly employed to catalyze H2 oxidation and H2O dissociation reactions, as well as CO oxidation and CO2 dissociation reactions. In my thesis studies, I developed synchrotron-based ambient pressure X-ray photoelectron spectroscopy to characterize the electrochemical double layer under reaction conditions. Concentrations and binding energy of oxygen ions, localized electrons, and surface reaction intermediates were quantified using core level and valence band X-ray photoelectron spectroscopy as a function of electrochemical overpotentials. These measurements reveal that localized electrons and oxygen vacancies segregate persistently from the bulk to the surface, resulting in concentrations up to four orders of magnitude greater on the surface than in the bulk. Under water splitting conditions, H2O molecules incorporate rapidly into surface oxygen vacancies. Spectroscopy and electrochemistry results suggest that the electron transfer between Ce 4f states and OH adsorbates is rate determining. Under CO oxidation and CO2 dissociation conditions, on the other hand, carbonate is the stable adsorbate. The larger footprint of carbonate relative to hydroxyl adsorbate gives rise to adsorbate-adsorbate interactions, resulting in a coverage-dependent reaction pathway. Lastly, measurement of surface dipole potential energy in both cases reveals intrinsic dipole moments of adsorbates as the origin of electrostatic potential gradient near the surface. Combined, these in-situ investigations unravel the electrochemical reaction pathway, particularly the role of point defects at ceria/gas interfaces, and establish a rational path towards enhancing the efficacy of oxide electrocatalysts.
Author: Darren Haggerston
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Nicolo' Comini
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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