Ignition Studies of Oxy-syngas/CO2 Mixtures Using Shock Tube for Cleaner Combustion Engines

Ignition Studies of Oxy-syngas/CO2 Mixtures Using Shock Tube for Cleaner Combustion Engines PDF Author: Samuel Evan Barak
Publisher:
ISBN:
Category :
Languages : en
Pages : 28

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Book Description
In this study, syngas combustion was investigated behind reflected shock waves in order to gain insight into the behavior of ignition delay times and effects of the CO2 dilution. Pressure and light emissions time-histories measurements were taken at a 2 cm axial location away from the end wall. High-speed visualization of the experiments from the end wall was also conducted. Oxy-syngas mixtures that were tested in the shock tube were diluted with CO2 fractions ranging from 60% - 85% by volume. A 10% fuel concentration was consistently used throughout the experiments. This study looked at the effects of changing the equivalence ratios ([phi]), between 0.33, 0.5, and 1.0 as well as changing the fuel ratio ([theta]), hydrogen to carbon monoxide, from 0.25, 1.0 and 4.0. The study was performed at 1.61-1.77 atm and a temperature range of 1006-1162K. The high-speed imaging was performed through a quartz end wall with a Phantom V710 camera operated at 67,065 frames per second. From the experiments, when increasing the equivalence ratio, it resulted in a longer ignition delay time. In addition, when increasing the fuel ratio, a lower ignition delay time was observed. These trends are generally expected with this combustion reaction system. The high-speed imaging showed non-homogeneous combustion in the system, however, most of the light emissions were outside the visible light range where the camera is designed for. The results were compared to predictions of two combustion chemical kinetic mechanisms: GRI v3.0 and AramcoMech v2.0 mechanisms. In general, both mechanisms did not accurately predict the experimental data. The results showed that current models are inaccurate in predicting CO2 diluted environments for syngas combustion.

Ignition Studies of Oxy-syngas/CO2 Mixtures Using Shock Tube for Cleaner Combustion Engines

Ignition Studies of Oxy-syngas/CO2 Mixtures Using Shock Tube for Cleaner Combustion Engines PDF Author: Samuel Evan Barak
Publisher:
ISBN:
Category :
Languages : en
Pages : 28

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Book Description
In this study, syngas combustion was investigated behind reflected shock waves in order to gain insight into the behavior of ignition delay times and effects of the CO2 dilution. Pressure and light emissions time-histories measurements were taken at a 2 cm axial location away from the end wall. High-speed visualization of the experiments from the end wall was also conducted. Oxy-syngas mixtures that were tested in the shock tube were diluted with CO2 fractions ranging from 60% - 85% by volume. A 10% fuel concentration was consistently used throughout the experiments. This study looked at the effects of changing the equivalence ratios ([phi]), between 0.33, 0.5, and 1.0 as well as changing the fuel ratio ([theta]), hydrogen to carbon monoxide, from 0.25, 1.0 and 4.0. The study was performed at 1.61-1.77 atm and a temperature range of 1006-1162K. The high-speed imaging was performed through a quartz end wall with a Phantom V710 camera operated at 67,065 frames per second. From the experiments, when increasing the equivalence ratio, it resulted in a longer ignition delay time. In addition, when increasing the fuel ratio, a lower ignition delay time was observed. These trends are generally expected with this combustion reaction system. The high-speed imaging showed non-homogeneous combustion in the system, however, most of the light emissions were outside the visible light range where the camera is designed for. The results were compared to predictions of two combustion chemical kinetic mechanisms: GRI v3.0 and AramcoMech v2.0 mechanisms. In general, both mechanisms did not accurately predict the experimental data. The results showed that current models are inaccurate in predicting CO2 diluted environments for syngas combustion.

High Temperature Shock Tube Ignition Studies of CO2́2 Diluted Mixtures

High Temperature Shock Tube Ignition Studies of CO2́2 Diluted Mixtures PDF Author: Owen Marcus Pryor
Publisher:
ISBN:
Category :
Languages : en
Pages : 66

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Book Description
Experimental data for ignition delay times and species time-histories (CH4) were obtained in mixtures diluted with CO2. Experiments were performed behind reflected shockwaves from temperatures of 1200 to 2000 K for pressures ranging from 1 to 11 atm. Ignition times were obtained from emission and laser absorption measurements. Current experimental data were compared with the predictions of detailed chemical kinetic models (available from literature) that will allow for accurate design and modeling of combustion systems.

Shock Tube Studies of the Combustion of Methane/hydrogen/oxygen Mixtures

Shock Tube Studies of the Combustion of Methane/hydrogen/oxygen Mixtures PDF Author: K. P. Rickson
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Shock Tube Investigations of Novel Combustion Environments Towards a Carbon-neutral Future

Shock Tube Investigations of Novel Combustion Environments Towards a Carbon-neutral Future PDF Author: Samuel Evan Barak
Publisher:
ISBN:
Category :
Languages : en
Pages : 157

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Book Description
Supercritical carbon dioxide (sCO2) cycles are being investigated for the future of power generation. These cycles will contribute to a carbon-neutral future to combat the effects of climate change. These direct-fired closed cycles will produce power without adding significant pollutants to the atmosphere. For these cycles to be efficient, they will need to operate at significantly higher pressures (e.g., 300 atm for Allam Cycle) than existing systems (typically less than 40 atm). There is limited knowledge on combustion at these pressures or at the high dilution of carbon dioxide. Nominal fuel choices for gas turbines include natural gas and syngas (mixture of CO and H2). Shock tubes study these problems in order to understand the fundamentals and solve various challenges. Shock tube experiments have been studied by the author in the sCO2 regime for various fuels including natural gas, methane and syngas. Using the shock tube to take measurements, pressure and light emissions time-histories measurements were taken at a 2-cm axial location away from the end wall. Experiments for syngas at lower pressure utilized high-speed imaging through the end wall to investigate the effects of bifurcation. It was found that carbon dioxide created unique interactions with the shock tube compared to tradition bath gasses such as argon. The experimental results were compared to predictions from leading chemical kinetic mechanisms. In general, mechanisms can predict the experimental data for methane and other hydrocarbon fuels; however, the models overpredict for syngas mixtures. Reaction pathway analysis was evaluated to determine where the models need improvements. A new shock tube has been designed and built to operate up to 1000 atm pressures for future high-pressure experiments. Details of this new facility are included in this work. The experiments in this work are necessary for mechanism development to design an efficient combustor operate these cycles.

Oxy-Fuel Combustion for Power Generation and Carbon Dioxide (CO2) Capture

Oxy-Fuel Combustion for Power Generation and Carbon Dioxide (CO2) Capture PDF Author: L Zheng
Publisher: Elsevier
ISBN: 0857090984
Category : Technology & Engineering
Languages : en
Pages : 397

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Book Description
Oxy-fuel combustion is currently considered to be one of the major technologies for carbon dioxide (CO2) capture in power plants. The advantages of using oxygen (O2) instead of air for combustion include a CO2-enriched flue gas that is ready for sequestration following purification and low NOx emissions. This simple and elegant technology has attracted considerable attention since the late 1990s, rapidly developing from pilot-scale testing to industrial demonstration. Challenges remain, as O2 supply and CO2 capture create significant energy penalties that must be reduced through overall system optimisation and the development of new processes.Oxy-fuel combustion for power generation and carbon dioxide (CO2) capture comprehensively reviews the fundamental principles and development of oxy-fuel combustion in fossil-fuel fired utility boilers. Following a foreword by Professor János M. Beér, the book opens with an overview of oxy-fuel combustion technology and its role in a carbon-constrained environment. Part one introduces oxy-fuel combustion further, with a chapter comparing the economics of oxy-fuel vs. post-/pre-combustion CO2 capture, followed by chapters on plant operation, industrial scale demonstrations, and circulating fluidized bed combustion. Part two critically reviews oxy-fuel combustion fundamentals, such as ignition and flame stability, burner design, emissions and heat transfer characteristics, concluding with chapters on O2 production and CO2 compression and purification technologies. Finally, part three explores advanced concepts and developments, such as near-zero flue gas recycle and high-pressure systems, as well as chemical looping combustion and utilisation of gaseous fuel.With its distinguished editor and internationally renowned contributors, Oxy-fuel combustion for power generation and carbon dioxide (CO2) capture provides a rich resource for power plant designers, operators, and engineers, as well as academics and researchers in the field. Comprehensively reviews the fundamental principles and development of oxy-fuel combustion in fossil-fuel fired utility boilers Provides an overview of oxy-fuel combustion technology and its role in a carbon-constrained environment Introduces oxy-fuel combustion comparing the economics of oxy-fuel vs. post-/pre-combustion CO2 capture

A Shock Tube for the Study of Ignition in Fuel-air-mixtures

A Shock Tube for the Study of Ignition in Fuel-air-mixtures PDF Author: Philip Cheng-Kang Wu
Publisher:
ISBN:
Category :
Languages : en
Pages : 260

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A Shock Tube Study of the Ignition Delay of Hydrogen-air Mixtures Mear the Second Explosion Limit

A Shock Tube Study of the Ignition Delay of Hydrogen-air Mixtures Mear the Second Explosion Limit PDF Author: Roger Ronald Craig
Publisher:
ISBN:
Category : Shock tubes
Languages : en
Pages : 62

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Shock Tube Investigation of Ignition in Propane-Oxygen-Argon Mixtures

Shock Tube Investigation of Ignition in Propane-Oxygen-Argon Mixtures PDF Author: Karl Scheller
Publisher:
ISBN:
Category :
Languages : en
Pages : 31

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Book Description
The ignition of propane-oxygen mixtures highly diluted with argon has been examined in the region behind a reflected shock wave in a single pulse shock tube. The measurements covered a temperature range of 1250-1600K at pressures varying from 2 to 10 atmospheres for mixture equivalence ratios of 0.125 to 2.0. For these conditions, observed induction times ranged from 12 to 600 microseconds. In one series of tests on a stoichiometric mixture, analyses were made of the shocked gas just prior to and immediately after ignition. These revealed that extensive pyrolysis of the propane preceded ignition. Mixture compositions and test conditions in this investigation were selected in such a manner that the influence of significant parameters on the ignition delay times could be clearly delineated. It was found that the experimental results of more than 150 tests were well correlated. (Author).

MILD Combustion: Modelling Challenges, Experimental Configurations and Diagnostic Tools

MILD Combustion: Modelling Challenges, Experimental Configurations and Diagnostic Tools PDF Author: Alessandro Parente
Publisher: Frontiers Media SA
ISBN: 2889717003
Category : Technology & Engineering
Languages : en
Pages : 160

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Shock Tube Studies of the Ignition Kinetics of Methane and Carbon Monoxide

Shock Tube Studies of the Ignition Kinetics of Methane and Carbon Monoxide PDF Author: Peter A. Soriano
Publisher:
ISBN:
Category : Chemical equilibrium
Languages : en
Pages : 208

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