Author: Susan Deborah Toto
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
I. Synthesis, Characterization and Reactivity of Platinum(II) Metal Complexes of Phosphorus-containing Mesocycles. II. Bifunctional Phosphines as Reagents in Carbon Tetrachloride-promoted Chlorination Reactions
Author: Susan Deborah Toto
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 504
Book Description
Dissertation Abstracts International
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 770
Book Description
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 770
Book Description
Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities
Author: American Chemical Society. Committee on Professional Training
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages : 1646
Book Description
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages : 1646
Book Description
Chiral Transition Metal Complexes Containing Phosphines
Author: Darlene Grace D'Alliessi
Publisher:
ISBN:
Category :
Languages : en
Pages : 314
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 314
Book Description
Development of Bifunctional Phosphines, Metal Complexes and Catalysts for Various Organic Transformations
Author:
Publisher:
ISBN: 9781124696287
Category :
Languages : en
Pages : 424
Book Description
A series of phosphines with different heterocycles (pyridine and imidazole) possessing different substituents (alkyl and aryl) were synthesized. The phosphine ligands were reacted with different metal precursors to from organometallic complexes which were applied to catalysis. This dissertation describes, part of the discovery process of a uniquely active and selective catalyst for alkene isomerization and the importance of heterocyclic ring in the ligand, enhancing the acceleration of the reaction to almost 11,000 times faster than a non-heterocyclic analog. Further investigation of the isomerization catalyst, as a catalyst for cycloisomerization of alkynols led to discovery of the fact that a related alkyne hydration catalyst, reported by Dan Lev in 2004, was broadly useful in cycloisomerization reactions leading to synthesis of both indoles and benzofurans. A series of allylpalladium(II) chloride bifunctional phosphine complexes were also synthesized and characterized and eventually applied as catalysts for aryl amination reactions. Finally, two mechanistically distinct approaches to anti-Markovnikov alkene hydration using bifunctional ligands are described, which show promise for further development.
Publisher:
ISBN: 9781124696287
Category :
Languages : en
Pages : 424
Book Description
A series of phosphines with different heterocycles (pyridine and imidazole) possessing different substituents (alkyl and aryl) were synthesized. The phosphine ligands were reacted with different metal precursors to from organometallic complexes which were applied to catalysis. This dissertation describes, part of the discovery process of a uniquely active and selective catalyst for alkene isomerization and the importance of heterocyclic ring in the ligand, enhancing the acceleration of the reaction to almost 11,000 times faster than a non-heterocyclic analog. Further investigation of the isomerization catalyst, as a catalyst for cycloisomerization of alkynols led to discovery of the fact that a related alkyne hydration catalyst, reported by Dan Lev in 2004, was broadly useful in cycloisomerization reactions leading to synthesis of both indoles and benzofurans. A series of allylpalladium(II) chloride bifunctional phosphine complexes were also synthesized and characterized and eventually applied as catalysts for aryl amination reactions. Finally, two mechanistically distinct approaches to anti-Markovnikov alkene hydration using bifunctional ligands are described, which show promise for further development.
Transition-metal Complexes Containing Phosphorus Ligands
Author: Naseer Ahmad
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 6
Book Description
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 6
Book Description
Synthesis, Characterization and Reactivity of Platinum(0)-tetraphosphion Complexes and Group VIII Metal Phosphine Complexes Coordinated to Alkoxide and Hydroxide Ligands
Author: Lisa Marie Green
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 502
Book Description
Publisher:
ISBN:
Category : Ligands
Languages : en
Pages : 502
Book Description
Cage Metal Complexes
Author: Yan Voloshin
Publisher: Springer
ISBN: 331956420X
Category : Science
Languages : en
Pages : 475
Book Description
This fundamental book presents the most comprehensive summary of the current state in chemistry of cage metal complexes. After their previous book “The Encapsulation Phenomenon” (www.springer.com/978-3-319-27737-0) the authors in this book focus on the encapsulation of metal ions by different types of three-dimensional mono- and polynucleating caging ligands. Within these cage metal complexes, (metal) ions can be isolated from external factors. The book provides both a classification of the cage compounds and summaries of synthetic approaches. On that basis the authors then describe the unique chemical and physical properties and the resulting reactivity of the cage compounds, as well as practical and potential applications as potent topological drugs and prodrugs, antifibrillogenic agents, radiodiagnostic and radiotherapeutic compounds, paramagnetic probes, single-molecule magnets, electrocatalysts for hydrogen production, (photo)electronic devices, and many more. Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented in over 300 color schemes and figures.
Publisher: Springer
ISBN: 331956420X
Category : Science
Languages : en
Pages : 475
Book Description
This fundamental book presents the most comprehensive summary of the current state in chemistry of cage metal complexes. After their previous book “The Encapsulation Phenomenon” (www.springer.com/978-3-319-27737-0) the authors in this book focus on the encapsulation of metal ions by different types of three-dimensional mono- and polynucleating caging ligands. Within these cage metal complexes, (metal) ions can be isolated from external factors. The book provides both a classification of the cage compounds and summaries of synthetic approaches. On that basis the authors then describe the unique chemical and physical properties and the resulting reactivity of the cage compounds, as well as practical and potential applications as potent topological drugs and prodrugs, antifibrillogenic agents, radiodiagnostic and radiotherapeutic compounds, paramagnetic probes, single-molecule magnets, electrocatalysts for hydrogen production, (photo)electronic devices, and many more. Readers will find a well-structured and concise overview, with particular emphasis on a review of synthesis and reactivity of various cage metal complexes, summarizing over 400 literature references, clearly presented in over 300 color schemes and figures.
Gold Chemistry
Author: Fabian Mohr
Publisher: John Wiley & Sons
ISBN: 3527320865
Category : Science
Languages : en
Pages : 425
Book Description
Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.
Publisher: John Wiley & Sons
ISBN: 3527320865
Category : Science
Languages : en
Pages : 425
Book Description
Written by world-class authors, this most recent major book on the topic highlights new and current trends as well as future directions. It is comprehensive in its scope, covering all aspects of gold chemistry -- from homogeneous to heterogeneous catalysis, from supramolecular assemblies to sensors and medicinal applications. The result is an invaluable work for both organic and inorganic chemists working in universities and industry, as well as material scientists.
Heterocycles Via Cross Dehydrogenative Coupling
Author: Ananya Srivastava
Publisher:
ISBN: 9789811391453
Category : Heterocyclic chemistry
Languages : en
Pages : 498
Book Description
This book discusses the developments in the synthesis and functionalization of different heterocycles based on the formation of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds using cross-dehydrogenative coupling (CDC). Consisting of 13 chapters, the book systematically describes the advances in the synthesis and functionalization of nitrogen, oxygen, and sulfur-containing heterocycles. It also discusses the various mechanistic pathways to help readers gain an in-depth understanding of the CDC reactions of heterocycles. Lastly, in order to promote green chemistry, it addresses a range of metal-free CDC reactions of heterocycles - an area that has attracted significant attention in both academic and industrial research.
Publisher:
ISBN: 9789811391453
Category : Heterocyclic chemistry
Languages : en
Pages : 498
Book Description
This book discusses the developments in the synthesis and functionalization of different heterocycles based on the formation of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds using cross-dehydrogenative coupling (CDC). Consisting of 13 chapters, the book systematically describes the advances in the synthesis and functionalization of nitrogen, oxygen, and sulfur-containing heterocycles. It also discusses the various mechanistic pathways to help readers gain an in-depth understanding of the CDC reactions of heterocycles. Lastly, in order to promote green chemistry, it addresses a range of metal-free CDC reactions of heterocycles - an area that has attracted significant attention in both academic and industrial research.