Group 8 and 9 Half Sandwich Complexes of N-heterocyclic Phosphines PDF Download
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Author: Daniel Abraham Lev
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 706
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Book Description
Investigations of ligands capable of donating/accepting hydrogen bonds in important catalytic applications were undertaken. It has been found that heterocyclic phosphine ligands, namely 2-pyridyl and 2-imidazolyl phosphines, greatly influence the reactivity of CpRu catalysts. This has led to highly efficient anti-Markovnikov hydration of a variety of terminal alkynes, including aryl alkynes and trimethylsilyl alkynes. Enzyme-like rate enhancements of>109 have facilitated experimental and computational mechanistic studies, supporting multipoint cooperativity involving the metal and the heterocyclic phosphine ligands.
Author: Daniel Abraham Lev
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 706
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Book Description
Investigations of ligands capable of donating/accepting hydrogen bonds in important catalytic applications were undertaken. It has been found that heterocyclic phosphine ligands, namely 2-pyridyl and 2-imidazolyl phosphines, greatly influence the reactivity of CpRu catalysts. This has led to highly efficient anti-Markovnikov hydration of a variety of terminal alkynes, including aryl alkynes and trimethylsilyl alkynes. Enzyme-like rate enhancements of>109 have facilitated experimental and computational mechanistic studies, supporting multipoint cooperativity involving the metal and the heterocyclic phosphine ligands.
Author: Aziza Ahmida
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
Author: Nikolaos Tsoureas
Publisher:
ISBN:
Category :
Languages : en
Pages : 258
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Book Description
Author: Robert H. Crabtree
Publisher: John Wiley & Sons
ISBN: 0471718750
Category : Science
Languages : en
Pages : 600
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Book Description
Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 860
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Book Description
Author: Armando J. L. Pombeiro
Publisher: John Wiley & Sons
ISBN: 1118742893
Category : Science
Languages : en
Pages : 848
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Book Description
A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.
Author: Eric V. Anslyn
Publisher: University Science Books
ISBN: 9781891389313
Category : Science
Languages : en
Pages : 1148
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Book Description
In additionto covering thoroughly the core areas of physical organic chemistry -structure and mechanism - this book will escortthe practitioner of organic chemistry into a field that has been thoroughlyupdated.
Author: Françoise Colobert
Publisher: John Wiley & Sons
ISBN: 3527343407
Category : Science
Languages : en
Pages : 294
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Book Description
Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.
Author:
Publisher:
ISBN:
Category : Chemistry
Languages : en
Pages : 2800
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Book Description
Author: Belakatte Parameshwarappa Nandeshwarappa
Publisher: BoD – Books on Demand
ISBN: 1789859433
Category : Science
Languages : en
Pages : 250
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Book Description
The book ‘Organic Synthesis - A Nascent Relook’ is a compendium of the recent progress in all aspects of organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic, green chemistry and medicinal chemistry, polymer chemistry, as well as analytical methods in organic chemistry. The book presents the latest developments in these fields. The chapters are written by chosen experts who are internationally known for their eminent research contributions. Organic synthesis is the complete chemical synthesis of a target molecule. In this book, special emphasis is given to the synthesis of various bioactive heterocycles. Careful selection of various topics in this book will serve the rightful purpose for the chemistry community and the industrial houses at all levels.
