Fundamental Studies of Reactive Intermediates in Homogeneous Catalysis PDF Download
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Languages : en
Pages : 7
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Book Description
The studies involve dissociation of Fe(CO){sub n}−, Ni(CO){sub n}, and other carbonyl anions; decarboxylation of (CO)4FeCOOH− to form CO2 and (CO)4FeH− in the water gas shift reaction; gas-phase bimolecular reactions of carbonyl anions and O2; reaction of O2 with CpMn(CO)2−; gas-phase chemistry of fullerene anions; and gas-phase thermochemistry of bicarbonate ion, bisulfite ion, and their conjugate acids (sulfonate ion was produced).
Author:
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ISBN:
Category :
Languages : en
Pages : 7
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Book Description
The studies involve dissociation of Fe(CO){sub n}−, Ni(CO){sub n}, and other carbonyl anions; decarboxylation of (CO)4FeCOOH− to form CO2 and (CO)4FeH− in the water gas shift reaction; gas-phase bimolecular reactions of carbonyl anions and O2; reaction of O2 with CpMn(CO)2−; gas-phase chemistry of fullerene anions; and gas-phase thermochemistry of bicarbonate ion, bisulfite ion, and their conjugate acids (sulfonate ion was produced).
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Category :
Languages : en
Pages :
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Author: Y. Ishii
Publisher: Springer Science & Business Media
ISBN: 1461570417
Category : Science
Languages : en
Pages : 307
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Book Description
Author: M. Tsutsui
Publisher: Springer Science & Business Media
ISBN: 1461570387
Category : Science
Languages : en
Pages : 247
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Book Description
The objective of this workshop on homogeneous catalysis was to identi fy opportunities for the solution of energy problems and industrial produc tion problems by homogeneous catalysis. The first day of the workshop was devoted to plenary lectures on frontier areas in homogeneous catalysis which set the tone for the workshop. On succeeding days of the workshop, the participants were divided into five working groups for discussion of various aspects of homogeneous catalysis. Each of the five workshops engaged in extensive discussions and then formulated a rough draft of their report and recommendations. The reports of the working groups were presented at a plenary session and suggestions for changes and revisions were made. These minor revisions were incorporated into the working group report by the Co-Chairmen of the working groups. This workshop on homogeneous catalysis was sponsored by the Na tional Science Foundation (United States) and by the National Research Council (Italy). Additional financial support was provided by Montedison, E.N.I., and S.I.R. We wish to thank Mr. William M. Tsutsui for typing and assisting in the editorial work. The Robert A. Welch Foundation Grant A-420 partial ly supported the time spent by M. Tsutsui for the organization of the work shop and the editorial work of the proceedings. Organizing Committee, December, 1976 C. Casey G. P. Chiusoli J. Halpern M. Tsutsui, Co-Editor R. Ugo, Co-Editor v CONTENTS In troduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IX . . . . . . . . . . . .
Author: M. Tsutsui
Publisher: Springer Science & Business Media
ISBN: 1461329582
Category : Science
Languages : en
Pages : 1040
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Book Description
During the 70's it has become drastically apparent that our natural resources, including energy, are not in unlimited supply. This realization is strongly felt in the economic turmoil that is occurring, but its effects will penetrate into other areas, even causing moderate social changes. Chemists playa major role in coverting the world's natural resources into products. The public consumes these products and now depends upon them to keep the high standard of living to which they have become accustomed. This topic could easily be expounded into a whole article, but it is sufficent to say that almost everything-from the use of lightweight, strong polymers which are replacing the use of metals in today's automobiles, to the curing of diseases with asymetrically synthesized drugs-is related to the endeavors of chemistry. Catalysts have played a major role in transforming resources to useful products. Since a catalyst lowers the activation energy required for a particular reaction, and often for only one specific pathway where normally many exist, it is not surprising within the extant climate that researchers are now increasing their efforts and focusing their priorities on improving and discovering more efficient and selective catalysts.
Author: Sumit Bhaduri
Publisher: John Wiley & Sons
ISBN: 1118872517
Category : Science
Languages : en
Pages : 302
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Book Description
Over the last decade, the area of homogeneous catalysis with transition metal has grown in great scientific interest and technological promise, with research in this area earning three Nobel Prizes and filing thousands of patents relating to metallocene and non-metallocene single site catalysts, asymmetric catalysis, carbon-carbon bond forming metathesis and cross coupling reactions. This text explains these new developments in a unified, cogent, and comprehensible manner while also detailing earlier discoveries and the fundamentals of homogeneous catalysis. Serving as a self-study guide for students and all chemists seeking to gain entry into this field, it can also be used by experienced researchers from both academia and industry for referring to leading state of the art review articles and patents, and also as a quick self-study manual in an area that is outside their immediate expertise. The book features: • Topics including renewable feed stocks (biofuel, glycerol), carbon dioxide based processes (polycarbonates), fluorous solvents, ionic liquid, hydroformylation, polymerization, oxidation, asymmetric catalysis, and more • Basic principles of organometallic chemistry, homogeneous catalysis, and relevant technological issues • Problems and answers, industrial applications (case studies), and examples from proven industrial processes with clear discussions on environmental and techno-commercial issues • Extensive references to cutting edge research with application potential and leading patents • Tables and illustrations to help explain difficult concepts
Author: Amy Elizabeth Stevens
Publisher:
ISBN:
Category :
Languages : en
Pages : 262
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Book Description
Author: M. Tsutsui
Publisher: Springer
ISBN: 9780306401992
Category : Science
Languages : en
Pages : 1112
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Book Description
During the 70's it has become drastically apparent that our natural resources, including energy, are not in unlimited supply. This realization is strongly felt in the economic turmoil that is occurring, but its effects will penetrate into other areas, even causing moderate social changes. Chemists playa major role in coverting the world's natural resources into products. The public consumes these products and now depends upon them to keep the high standard of living to which they have become accustomed. This topic could easily be expounded into a whole article, but it is sufficent to say that almost everything-from the use of lightweight, strong polymers which are replacing the use of metals in today's automobiles, to the curing of diseases with asymetrically synthesized drugs-is related to the endeavors of chemistry. Catalysts have played a major role in transforming resources to useful products. Since a catalyst lowers the activation energy required for a particular reaction, and often for only one specific pathway where normally many exist, it is not surprising within the extant climate that researchers are now increasing their efforts and focusing their priorities on improving and discovering more efficient and selective catalysts.
Author:
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 88
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Book Description
Author: Jens K. Nørskov
Publisher: John Wiley & Sons
ISBN: 1118888952
Category : Technology & Engineering
Languages : en
Pages : 228
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Book Description
This book is based on a graduate course and suitable as a primer for any newcomer to the field, this book is a detailed introduction to the experimental and computational methods that are used to study how solid surfaces act as catalysts. Features include: First comprehensive description of modern theory of heterogeneous catalysis Basis for understanding and designing experiments in the field Allows reader to understand catalyst design principles Introduction to important elements of energy transformation technology Test driven at Stanford University over several semesters
