Fouling Characteristics of a Desalted Crude Oil

Fouling Characteristics of a Desalted Crude Oil PDF Author: Dah-cheng Lin
Publisher:
ISBN:
Category : Heat exchangers
Languages : en
Pages : 264

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Book Description
The fouling characteristics of a desalted crude oil were investigated in a systematic investigation. There are two main parts in this study, the dry bulk tests (dehydrated crude oil) and the wet bulk tests (to which desalter brine was added). Three barrels of desalted crude oil provided by Amoco Oil Company were studied. For the dry bulk tests, no brine was added to the crude oil. The effects of fluid velocity and surface temperature on fouling were investigated. The higher the surface temperature the greater the fouling was observed. Fouling decreased with an increase of fluid velocity. Fluid velocity had a stronger effect on fouling at low surface temperatures than at high surface temperatures. It was also observed that the fouling behavior of crude oil depended on small difference in composition. The threshold surface temperatures for the initiation of fouling were 400-450 °F (3.0 ft/sec), 525-550 °F (5.5 ft/sec), 550-600 °F (8.0 ft/sec) and about 600 °F (10.0 ft/sec) for Barrel No. 2 and Barrel No. 3. For Barrel No. 1 however, the threshold surface temperatures were about 550 °F (3.0 ft/sec) and 600 °F (5.5 ft/sec). For the wet bulk tests, a certain amount desalter brine (weight percentage = 0.8%) was added to the crude oil for each run. The effects of fluid velocity, surface temperature and the presence of brine on fouling were investigated. Higher surface temperature enhanced fouling considerably. Fouling was reduced as fluid velocity was increased. It was shown that brine had a strong effect on fouling. No fouling occurred for velocities of 5.5 and 8.0 ft/sec at a surface temperature of 350 °F which was a condition for which an aqueous phase was present and the salt remained in solution. Significant fouling occurred for velocities of 5.5 and 8.0 ft/sec at a surface temperature operated at a low 400 °F (Tb = 300 °F) which was a condition for which the aqueous phase at the heat transfer surface was dissolved or boiled to extinction and the salt was deposited on the heat transfer surface.

Fouling Characteristics of a Desalted Crude Oil

Fouling Characteristics of a Desalted Crude Oil PDF Author: Dah-cheng Lin
Publisher:
ISBN:
Category : Heat exchangers
Languages : en
Pages : 264

Get Book Here

Book Description
The fouling characteristics of a desalted crude oil were investigated in a systematic investigation. There are two main parts in this study, the dry bulk tests (dehydrated crude oil) and the wet bulk tests (to which desalter brine was added). Three barrels of desalted crude oil provided by Amoco Oil Company were studied. For the dry bulk tests, no brine was added to the crude oil. The effects of fluid velocity and surface temperature on fouling were investigated. The higher the surface temperature the greater the fouling was observed. Fouling decreased with an increase of fluid velocity. Fluid velocity had a stronger effect on fouling at low surface temperatures than at high surface temperatures. It was also observed that the fouling behavior of crude oil depended on small difference in composition. The threshold surface temperatures for the initiation of fouling were 400-450 °F (3.0 ft/sec), 525-550 °F (5.5 ft/sec), 550-600 °F (8.0 ft/sec) and about 600 °F (10.0 ft/sec) for Barrel No. 2 and Barrel No. 3. For Barrel No. 1 however, the threshold surface temperatures were about 550 °F (3.0 ft/sec) and 600 °F (5.5 ft/sec). For the wet bulk tests, a certain amount desalter brine (weight percentage = 0.8%) was added to the crude oil for each run. The effects of fluid velocity, surface temperature and the presence of brine on fouling were investigated. Higher surface temperature enhanced fouling considerably. Fouling was reduced as fluid velocity was increased. It was shown that brine had a strong effect on fouling. No fouling occurred for velocities of 5.5 and 8.0 ft/sec at a surface temperature of 350 °F which was a condition for which an aqueous phase was present and the salt remained in solution. Significant fouling occurred for velocities of 5.5 and 8.0 ft/sec at a surface temperature operated at a low 400 °F (Tb = 300 °F) which was a condition for which the aqueous phase at the heat transfer surface was dissolved or boiled to extinction and the salt was deposited on the heat transfer surface.

Fouling in Refineries

Fouling in Refineries PDF Author: James G. Speight
Publisher: Gulf Professional Publishing
ISBN: 0128011459
Category : Technology & Engineering
Languages : en
Pages : 539

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Book Description
Fouling in Refineries is an important and ongoing problem that directly affects energy efficiency resulting in increased costs, production losses, and even unit shutdown, requiring costly expenditures to clean up equipment and return capacity to positive levels. This text addresses this common challenge for the hydrocarbon processing community within each unit of the refinery. As refineries today face a greater challenge of accepting harder to process heavier crudes and the ongoing flow of the lighter shale oil feedstocks, resulting in bigger challenges to balance product stability within their process equipment, this text seeks to inform all relative refinery personnel on how to monitor fouling, characterize the deposits, and follow all available treatments. With basic modeling and chemistry of fouling and each unit covered, users will learn how to operate at maximum production rates and elongate the efficiency of their refinery’s capacity. Presents an understanding of the breakdown of fouling per refinery unit, including distillation and coking units Provides all the factors, crude types, and refining blends that cause fouling, especially the unconventional feedstocks and high acid crudes used today Helps users develop an analysis-based treatment and control strategy that empowers them to operate refinery equipment at a level that prevents fouling from occurring

Crude Oil Fouling

Crude Oil Fouling PDF Author: Francesco Coletti
Publisher: Gulf Professional Publishing
ISBN: 0128013591
Category : Technology & Engineering
Languages : en
Pages : 385

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Book Description
With production from unconventional rigs continuing to escalate and refineries grappling with the challenges of shale and heavier oil feedstocks, petroleum engineers and refinery managers must ensure that equipment used with today’s crude oil is protected from fouling deposits Crude Oil Fouling addresses this overarching challenge for the petroleum community with clear explanations on what causes fouling, current models and new approaches to evaluate and study the formation of deposits, and how today’s models could be applied from lab experiment to onsite field usability for not just the refinery, but for the rig, platform, or pipeline. Crude Oil Fouling is a must-have reference for every petroleum engineer’s library that gives the basic framework needed to analyze, model, and integrate the best fouling strategies and operations for crude oil systems. Defines the most critical variables and events that cause fouling Explains the consequences of fouling and its impact on operations, safety, and economics Provides the technical models available to better predict and eliminate the potential for fouling in any crude system

Desalting Crude Petroleum

Desalting Crude Petroleum PDF Author: Lloyd F. Christianson
Publisher:
ISBN:
Category : Petroleum
Languages : en
Pages : 34

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Book Description


Modeling and Optimization of Crude Oil Desalting

Modeling and Optimization of Crude Oil Desalting PDF Author: Shahrokh Ilkhaani
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Book Description
When first received by a refinery, the crude oil usually contains some water, mineral salts, and sediments. The salt appears in different forms, most often times it is dissolved in the formation water that comes with the crude i.e. in brine form, but it could also be present as solid crystals, water-insoluble particles of corrosion products or scale and metal-organic compounds such as prophyrins and naphthenates. The amount of salt in the crude can vary typically between 5 to 200 PTB depending on the crude source, API, viscosity and other properties of the crude. For the following reasons, it is of utmost importance to reduce the amount of salt in the crude before processing the crude in the Crude Distillation Unit and consequently downstream processing units of a refinery. 1. Salt causes corrosion in the equipment. 2. Salt fouls inside the equipment. The fouling problem not only negatively impacts the heat transfer rates in the exchangers and furnace tubes but also affects the hydraulics of the system by increasing the pressure drops and hence requiring more pumping power to the system. Salt also plugs the fractionator trays and causes reduced mass transfer i.e. reduced separation efficiency and therefore need for increased re-boiler/condenser duties. 3. The salt in the crude usually has a source of metallic compounds, which could cause poisoning of catalyst in hydrotreating and other refinery units. Until a few years ago, salt concentrations as high as 10 PTB (1 PTB = 1 lb salt per 1000 bbl crude) was acceptable for desalted crude; However, most of the refineries have adopted more stringent measures for salt content and recent specs only allow 1 PTB in the desalted crude. This would require many existing refineries to improve their desalting units to achieve the tighter salt spec. This study will focus on optimizing the salt removal efficiency of a desalting unit which currently has an existing single-stage desalter. By adding a second stage desalter, the required salt spec in the desalted crude will be met. Also, focus will be on improving the heat integration of the desalting process, and optimization of the desalting temperature to achieve the best operating conditions in the plant after revamp.

Refinery Feedstocks

Refinery Feedstocks PDF Author: James G. Speight
Publisher: CRC Press
ISBN: 0429675658
Category : Art
Languages : en
Pages : 371

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Book Description
Over the last several decades, the petroleum industry has experienced significant changes in resource availability, petro-politics, and technological advancements dictated by the changing quality of refinery feedstocks. However, the dependence on fossil fuels as the primary energy source has remained unchanged. Refinery Feedstocks addresses the problems of changing feedstock availability and properties; the refining process; and solids deposition during refining. This book will take the reader through the various steps that are necessary for crude oil evaluation and refining including the potential for the use of coal liquids, shale oil, and non-fossil fuel materials (biomass) as refinery feedstocks. Other features: Describes the various types of crude oil and includes a discussion of extra heavy oil and tar sand bitumen Includes basic properties and specifications of crude oil and the significance in refinery operations This book is a handy reference for engineers, scientists, and students who want an update on crude oil refining and on the direction the industry must take to assure the refinability of various feedstocks and the efficiency of the refining processes in the next fifty years. Non-technical readers, with help from the extensive glossary, will also benefit from reading this book.

Dewatering, Desalting, and Distillation in Petroleum Refining

Dewatering, Desalting, and Distillation in Petroleum Refining PDF Author: James G. Speight
Publisher: CRC Press
ISBN: 1000802639
Category : Technology & Engineering
Languages : en
Pages : 271

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Book Description
This book presents a detailed and practical description of various processes – dewatering, desalting, and distillation – that prepare refinery feedstocks for different conversion processes they will go through. Relevant process data are provided, and process operations are fully described. This accessible guide is written for managers, professionals, and technicians as well as graduate students transitioning into the refining industry. Key Features: • Describes feedstock evaluation and the effects of elemental, chemical, and fractional composition. • Details the equipment and components and possible impacts due to composition. • Explores the process options and parameters involved in dewatering, desalting, and distillation. • Considers next-generation processes and developments.

Processing of Heavy Crude Oils

Processing of Heavy Crude Oils PDF Author: Ramasamy Marappa Gounder
Publisher:
ISBN: 1839684097
Category :
Languages : en
Pages : 274

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Book Description


Root-cause Analysis of Crude Oil Fouling

Root-cause Analysis of Crude Oil Fouling PDF Author: C. B. Panchal
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages :

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Book Description


Surfactants

Surfactants PDF Author: Laurier Lincoln Schramm
Publisher: Cambridge University Press
ISBN: 0521640679
Category : Science
Languages : en
Pages : 633

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Book Description
This 2000 book provides an introduction to the nature, occurrence, physical properties, propagation, and uses of surfactants in the petroleum industry.