Formation of Secondary Organic Aerosols in Atmospheric Liquid Water PDF Download
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Author: Marwa M. H. El-Sayed
Publisher:
ISBN:
Category :
Languages : en
Pages : 748
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Book Description
The formation of secondary organic aerosols through aqueous processes (aqSOA) has been identified as an important route in forming organic aerosols; however, many aspects of this formation are still uncertain. One main uncertainty is the nature by which these aqueous compounds are formed, whether the formation is reversible, irreversible, or a mixture of both. To date, there are no ambient measurements to quantify or constrain the relative contributions of reversible/irreversible aqSOA. Hence, we have developed an online method to simultaneously measure water-soluble organic carbon in the gas (WSOCg) and particle (WSOCp) phases to characterize the reversible and irreversible uptake of water-soluble organic gases to aerosol liquid water (ALW) across the different seasons in Maryland located in the eastern United States.
Author: Marwa M. H. El-Sayed
Publisher:
ISBN:
Category :
Languages : en
Pages : 748
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Book Description
The formation of secondary organic aerosols through aqueous processes (aqSOA) has been identified as an important route in forming organic aerosols; however, many aspects of this formation are still uncertain. One main uncertainty is the nature by which these aqueous compounds are formed, whether the formation is reversible, irreversible, or a mixture of both. To date, there are no ambient measurements to quantify or constrain the relative contributions of reversible/irreversible aqSOA. Hence, we have developed an online method to simultaneously measure water-soluble organic carbon in the gas (WSOCg) and particle (WSOCp) phases to characterize the reversible and irreversible uptake of water-soluble organic gases to aerosol liquid water (ALW) across the different seasons in Maryland located in the eastern United States.
Author: Chen Wang
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
A sound parameterization of the gas-particle partitioning process is essential for understanding and quantifying secondary organic aerosol (SOA) formation. This thesis aimed to improve the understanding and description of phase partitioning during SOA formation through a combination of both laboratory and modeling studies. Partitioning of organic compounds between gas and particle phase is influenced by the presence of a large quantity of inorganic salts in aerosol, which is known as the salt effect. The salt effects of atmospherically relevant inorganic salts for a large number of organic compounds with various functional groups were measured in this study. The results revealed the importance of both salt species and organic compound identities on the salt effect, with the former as the dominant determinant. Models in predicting salt effect were calibrated and evaluated using the experimental data. Salt effect in mixtures was also investigated, which assists the understanding of salt effect in mixture salt solutions, including aerosols. A new approach for predicting gas-particle partitioning during SOA formation based on quantum chemical calculations was presented, which considers the partitioning species explicitly and captures the dynamic aspects of the aerosol formation processes. The role of different atmospheric parameters and chemical properties (organic loading, liquid water content, salinity, chemical ageing, etc.) was investigated and compared. Performance of the model was found to be comparable to the best currently used group contribution methods. SOA formation from constant emission and oxidation of precursor compounds was simulated to resemble the realistic scenario in the ambient atmosphere. The differential yield that describes the amount of SOA formed from a certain amount of added oxidation products was introduced, which is more relevant for SOA formation in the ambient atmosphere. The necessity of considering kinetic processes in addition to the thermodynamic equilibrium process was also discussed.
Author: Hajime Akimoto
Publisher: John Wiley & Sons
ISBN: 111942240X
Category : Science
Languages : en
Pages : 765
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Book Description
An important guide that highlights the multiphase chemical processes for students and professionals who want to learn more about aerosol chemistry Atmospheric Multiphase Reaction Chemistry provides the information and knowledge of multiphase chemical processes and offers a review of the fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols. The authors—noted experts on the topic—also describe new particle formation, and cloud condensation nuclei activity. In addition, the text includes descriptions of field observations on secondary aerosols and PM2.5. Atmospheric aerosols play a critical role in air quality and climate change. There is growing evidence that the multiphase reactions involving heterogeneous reactions on the air-particle interface and the reactions in the bulk liquid phase of wet aerosol and cloud/fog droplets are important processes forming secondary aerosols in addition to gas-phase oxidation reactions to form low-volatile compounds. Comprehensive in scope, the book offers an understanding of the topic by providing a historical overview of secondary aerosols, the fundamentals of multiphase reactions, gas-phase reactions of volatile organic compounds, aqueous phase and air-particle interface reactions of organic compound. This important text: Provides knowledge on multiphase chemical processes for graduate students and research scientists Includes fundamentals on gas-liquid equilibrium, gas phase reactions, bulk aqueous phase reactions, and gas-particle interface reactions related to formation of secondary aerosols Covers in detail reaction chemistry of secondary organic aerosols Written for students and research scientists in atmospheric chemistry and aerosol science of environmental engineering, Atmospheric Multiphase Reaction Chemistry offers an essential guide to the fundamentals of multiphase chemical processes.
Author: Sherri W. Hunt
Publisher: ACS Symposium
ISBN: 9780841233638
Category : Science
Languages : en
Pages : 0
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Book Description
This book highlights new cross-disciplinary advances in aerosol chemistry that involve more than one phase, for example, unique chemical processes occurring on gas-solid and liquid-solid interfaces.
Author: Ian Colbeck
Publisher: John Wiley & Sons
ISBN: 1405139196
Category : Science
Languages : en
Pages : 276
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Book Description
Aerosol particles are ubiquitous in the Earth’s atmosphere and are central to many environmental issues such as climate change, stratospheric ozone depletion and air quality. In urban environments, aerosol particles can affect human health through their inhalation. Atmospheric aerosols originate from naturally occurring processes, such as volcanic emissions, sea spray and mineral dust emissions, or from anthropogenic activity such as industry and combustion processes. Aerosols present pathways for reactions, transport, and deposition that would not occur in the gas phase alone. Understanding the ways in which aerosols behave, evolve, and exert these effects requires knowledge of their formation and removal mechanism, transport processes, as well as their physical and chemical characteristics. Motivated by climate change and adverse health effects of traffic-related air pollution, aerosol research has intensified over the past couple of decades, and recent scientific advances offer an improved understanding of the mechanisms and factors controlling the chemistry of atmospheric aerosols. Environmental Chemistry of Aerosols brings together the current state of knowledge of aerosol chemistry, with chapters written by international leaders in the field. It will serve as an authoritative and practical reference for scientists studying the Earth’s atmosphere and as an educational and training resource for both postgraduate students and professional atmospheric scientists.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 34
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Book Description
Organic aerosol is an important fraction of the fine particulate matter present in the atmosphere. This organic aerosol comes from a variety of sources; primary organic aerosol emitted directly from combustion process, and secondary aerosol formed in the atmosphere from condensable vapors. This secondary organic aerosol (SOA) can result from both anthropogenic and biogenic sources. In rural areas of the United States, organic aerosols can be a significant part of the aerosol load in the atmosphere. However, the extent to which gas-phase biogenic emissions contribute to this organic load is poorly understood. Such an understanding is crucial to properly apportion the effect of anthropogenic emissions in these rural areas that are sometimes dominated by biogenic sources. To help gain insight on the effect of biogenic emissions on particle concentrations in rural areas, we have been conducting a field measurement program at the University of California Blodgett Forest Research Facility. The field location includes has been used to acquire an extensive suite of measurements resulting in a rich data set, containing a combination of aerosol, organic, and nitrogenous species concentration and meteorological data with a long time record. The field location was established in 1997 by Allen Goldstein, a professor in the Department of Environmental Science, Policy and Management at the University of California at Berkeley to study interactions between the biosphere and the atmosphere. The Goldstein group focuses on measurements of concentrations and whole ecosystem biosphere-atmosphere fluxes for volatile organic compounds (VOC's), oxygenated volatile organic compounds (OVOC's), ozone, carbon dioxide, water vapor, and energy. Another important collaborator at the Blodgett field location is Ronald Cohen, a professor in the Chemistry Department at the University of California at Berkeley. At the Blodgett field location, his group his group performs measurements of the concentrations of important gas phase nitrogen compounds. Experiments have been ongoing at the Blodgett field site since the fall of 2000, and have included portions of the summer and fall of 2001, 2002, and 2003. Analysis of both the gas and particle phase data from the year 2000 show that the particle loading at the site correlates with both biogenic precursors emitted in the forest and anthropogenic precursors advected to the site from Sacramento and the Central Valley of California. Thus the particles at the site are affected by biogenic processing of anthropogenic emissions. Size distribution measurements show that the aerosol at the site has a geometric median diameter of approximately 100 nm. On many days, in the early afternoon, growth of nuclei mode particles (
Author: Claudio Tomasi
Publisher: John Wiley & Sons
ISBN: 3527336451
Category : Science
Languages : en
Pages : 706
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Book Description
Ein Blick auf die morphologischen, physikalischen und chemischen Eigenschaften von Aerosolen aus den unterschiedlichsten natürlichen und anthropogenen Quellen trägt zum besseren Verständnis der Rolle bei, die Aerosolpartikel bei der Streuung und Absorption kurz- und langwelliger Strahlung spielen. Dieses Fachbuch bietet Informationen, die sonst schwer zu finden sind, und vermittelt ausführlich die Kenntnisse, die erforderlich sind, um die mikrophysikalischen, chemischen und Strahlungsparameter zu charakterisieren, die bei der Wechselwirkung von Sonnen- und Erdstrahlen so überaus wichtig sind. Besonderes Augenmerk liegt auf den indirekten Auswirkungen von Aerosolen auf das Klima im Rahmen des komplexen Systems aus Aerosolen, Wolken und der Atmosphäre. Auch geht es vorrangig um die Wirkungen natürlicher und anthropogener Aerosole auf die Luftqualität und die Umwelt, auf die menschliche Gesundheit und unser kulturelles Erbe. Mit einem durchgängig lösungsorientierten Ansatz werden nicht nur die Probleme und Gefahren dieser Aerosole behandelt, sondern auch praktikable Lösungswege aufgezeigt.
Author: Daniel J. Jacob
Publisher: Princeton University Press
ISBN: 0691001855
Category : Nature
Languages : en
Pages : 280
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Book Description
Atmospheric chemistry is one of the fastest growing fields in the earth sciences. Until now, however, there has been no book designed to help students capture the essence of the subject in a brief course of study. Daniel Jacob, a leading researcher and teacher in the field, addresses that problem by presenting the first textbook on atmospheric chemistry for a one-semester course. Based on the approach he developed in his class at Harvard, Jacob introduces students in clear and concise chapters to the fundamentals as well as the latest ideas and findings in the field. Jacob's aim is to show students how to use basic principles of physics and chemistry to describe a complex system such as the atmosphere. He also seeks to give students an overview of the current state of research and the work that led to this point. Jacob begins with atmospheric structure, design of simple models, atmospheric transport, and the continuity equation, and continues with geochemical cycles, the greenhouse effect, aerosols, stratospheric ozone, the oxidizing power of the atmosphere, smog, and acid rain. Each chapter concludes with a problem set based on recent scientific literature. This is a novel approach to problem-set writing, and one that successfully introduces students to the prevailing issues. This is a major contribution to a growing area of study and will be welcomed enthusiastically by students and teachers alike.
Author: Bethany A. Warren
Publisher:
ISBN:
Category : Aerosols
Languages : en
Pages : 414
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Book Description
Author: Kenneth Stephen Docherty
Publisher:
ISBN:
Category : Aerosols
Languages : en
Pages : 626
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Book Description
