Flows and Chemical Reactions in Homogeneous Mixtures PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Flows and Chemical Reactions in Homogeneous Mixtures PDF full book. Access full book title Flows and Chemical Reactions in Homogeneous Mixtures by Roger Prud'homme. Download full books in PDF and EPUB format.
Author: Roger Prud'homme
Publisher: John Wiley & Sons
ISBN: 1118832663
Category : Science
Languages : en
Pages : 200
Get Book Here
Book Description
Flows with chemical reactions can occur in various fields such as combustion, process engineering, aeronautics, the atmospheric environment and aquatics. The examples of application chosen in this book mainly concern homogeneous reactive mixtures that can occur in propellers within the fields of process engineering and combustion: – propagation of sound and monodimensional flows in nozzles, which may include disequilibria of the internal modes of the energy of molecules; – ideal chemical reactors, stabilization of their steady operation points in the homogeneous case of a perfect mixture and classical instruments of experimental and theoretical analysis such as population balances, and the distribution of residence and passage times; – laminar and turbulent flames, separating those which are premixed from those which are not and which do not exhibit the same mechanisms, but which also occur in the case of triple flames. Flows and Chemical Reactions in Homogeneous Mixtures provides information on dimensional analysis, statistical thermodynamics with coupling between internal modes and chemical reactions, the apparition and damping of fluid turbulence as well as its statistical processing, bifurcations, flames in a confined medium and diffusion. Contents 1. Flows in Nozzles. 2. Chemical Reactors. 3. Laminar and Turbulent Flames. Appendix 1. Dimensionless Numbers, Similarity. Appendix 2. Thermodynamic Functions. Appendix 3. Concepts of Turbulence. Appendix 4. Thermodynamic functions for a mixture in disequilibrium. Appendix 5. Notion of bifurcation. Appendix 6. Confined flame. Appendix 7. Limits of Validity of the First-order Expansions for Diffusion Flames.
Author: Roger Prud'homme
Publisher: John Wiley & Sons
ISBN: 1118832663
Category : Science
Languages : en
Pages : 200
Get Book Here
Book Description
Flows with chemical reactions can occur in various fields such as combustion, process engineering, aeronautics, the atmospheric environment and aquatics. The examples of application chosen in this book mainly concern homogeneous reactive mixtures that can occur in propellers within the fields of process engineering and combustion: – propagation of sound and monodimensional flows in nozzles, which may include disequilibria of the internal modes of the energy of molecules; – ideal chemical reactors, stabilization of their steady operation points in the homogeneous case of a perfect mixture and classical instruments of experimental and theoretical analysis such as population balances, and the distribution of residence and passage times; – laminar and turbulent flames, separating those which are premixed from those which are not and which do not exhibit the same mechanisms, but which also occur in the case of triple flames. Flows and Chemical Reactions in Homogeneous Mixtures provides information on dimensional analysis, statistical thermodynamics with coupling between internal modes and chemical reactions, the apparition and damping of fluid turbulence as well as its statistical processing, bifurcations, flames in a confined medium and diffusion. Contents 1. Flows in Nozzles. 2. Chemical Reactors. 3. Laminar and Turbulent Flames. Appendix 1. Dimensionless Numbers, Similarity. Appendix 2. Thermodynamic Functions. Appendix 3. Concepts of Turbulence. Appendix 4. Thermodynamic functions for a mixture in disequilibrium. Appendix 5. Notion of bifurcation. Appendix 6. Confined flame. Appendix 7. Limits of Validity of the First-order Expansions for Diffusion Flames.
Author: Roger Prud'homme
Publisher: John Wiley & Sons
ISBN: 1119054311
Category : Science
Languages : en
Pages : 134
Get Book Here
Book Description
This book - a sequel of previous publications Flows and Chemical Reactions, Chemical Reactions Flows in Homogeneous Mixtures and Chemical Reactions and Flows in Heterogeneous Mixtures - is devoted to flows with chemical reactions in the electromagnetic field. The first part, entitled basic equations, consists of four chapters. The first chapter provides an overview of the equations of electromagnetism in Minkowski spacetime. This presentation is extended to balance equations, first in homogeneous media unpolarized in the second chapter and homogeneous fluid medium polarized in the third chapter. Chapter four is devoted to heterogeneous media in the presence of electromagnetic field. Balance equations at interfaces therein. The second part of this volume is entitled applications. It also includes four chapters. Chapter five provides a study of the action of fields on fire. Chapter six deals with a typical application for the Peltier effect, chapter seven is devoted to metal-plasma interaction, especially in the Langmuir probe and finally Chapter Eight deals with the propulsion Hall effect. Are given in appendix supplements the laws of balance with electromagnetic field and described the methodology for establishing one-dimensional equations for flow comprising active walls as is the case in some Hall effect thrusters.
Author: Roger Prud'homme
Publisher: John Wiley & Sons
ISBN: 1848217854
Category : Science
Languages : en
Pages : 204
Get Book Here
Book Description
This book - a sequel of previous publications 'Flows and Chemical Reactions' and 'Chemical Reactions in Flows and Homogeneous Mixtures' - is devoted to flows with chemical reactions in heterogeneous environments. Heterogeneous media in this volume include interfaces and lines. They may be the site of radiation. Each type of flow is the subject of a chapter in this volume. We consider first, in Chapter 1, the question of the generation of environments biphasic individuals: dusty gas, mist, bubble flow. Chapter 2 is devoted to the study at the mesoscopic scale: particle-fluid exchange of momentum and heat with determination of the respective exchange coefficients. In Chapter 3, we establish simplified equations of macroscopic balance for mass, for the momentum and energy, in the case of particles of one size (monodisperse suspension). Radiative phenomena are presented in Chapter 5.
Author: National Research Council
Publisher: National Academies Press
ISBN: 0309046483
Category : Technology & Engineering
Languages : en
Pages : 145
Get Book Here
Book Description
Computational mechanics is a scientific discipline that marries physics, computers, and mathematics to emulate natural physical phenomena. It is a technology that allows scientists to study and predict the performance of various productsâ€"important for research and development in the industrialized world. This book describes current trends and future research directions in computational mechanics in areas where gaps exist in current knowledge and where major advances are crucial to continued technological developments in the United States.
Author: Nord-Eddine Sad Chemloul
Publisher: John Wiley & Sons
ISBN: 1119788021
Category : Science
Languages : en
Pages : 233
Get Book Here
Book Description
Dimensional analysis is the basis for the determination of laws that allow the experimental results obtained on a model to be transposed to the fluid system at full scale (a prototype). The similarity in fluid mechanics then allows for better redefinition of the analysis by removing dimensionless elements. This book deals with these two tools, with a focus on the Rayleigh method and the Vaschy-Buckingham method. It deals with the homogeneity of the equations and the conversion between the systems of units SI and CGS, and presents the dimensional analysis approach, before addressing the similarity of flows. Dimensional Analysis and Similarity in Fluid Mechanics proposes a scale model and presents numerous exercises combining these two methods. It is accessible to students from their first year of a bachelors degree.
Author: Roger Norris Keeler
Publisher:
ISBN:
Category : Chemical reactions
Languages : en
Pages : 208
Get Book Here
Book Description
Author: Robert J. Kee
Publisher: John Wiley & Sons
ISBN: 047146130X
Category : Science
Languages : en
Pages : 884
Get Book Here
Book Description
Complex chemically reacting flow simulations are commonly employed to develop quantitative understanding and to optimize reaction conditions in systems such as combustion, catalysis, chemical vapor deposition, and other chemical processes. Although reaction conditions, geometries, and fluid flow can vary widely among the applications of chemically reacting flows, all applications share a need for accurate, detailed descriptions of the chemical kinetics occurring in the gas-phase or on reactive surfaces. Chemically Reacting Flow: Theory and Practice combines fundamental concepts in fluid mechanics and physical chemistry, assisting the student and practicing researcher in developing analytical and simulation skills that are useful and extendable for solving real-world engineering problems. The first several chapters introduce transport processes, primarily from a fluid-mechanics point of view, incorporating computational simulation from the outset. The middle section targets physical chemistry topics that are required to develop chemically reacting flow simulations, such as chemical thermodynamics, molecular transport, chemical rate theories, and reaction mechanisms. The final chapters deal with complex chemically reacting flow simulations, emphasizing combustion and materials processing. Among other features, Chemically Reacting Flow: Theory and Practice: -Advances a comprehensive approach to interweaving the fundamentals of chemical kinetics and fluid mechanics -Embraces computational simulation, equipping the reader with effective, practical tools for solving real-world problems -Emphasizes physical fundamentals, enabling the analyst to understand how reacting flow simulations achieve their results -Provides a valuable resource for scientists and engineers who use Chemkin or similar software Computer simulation of reactive systems is highly effective in the development, enhancement, and optimization of chemical processes. Chemically Reacting Flow helps prepare both students and professionals to take practical advantage of this powerful capability.
Author: Rustam Ya Deberdeev
Publisher: Smithers Rapra
ISBN: 1909030287
Category : Science
Languages : en
Pages : 334
Get Book Here
Book Description
This book describes the fundamentals of fast liquid-phase chemical reactions and the principles of their scientific foundation, technical implementation and industrial application of new technologies. In addition, the equipment required to perform these reactions, in a turbulent mode in the chemical, petrochemical and petroleum industries, is also discussed. The macrokinetic approach has been developed with consideration of the diffusion, hydrodynamics, and heat transfer processes. Due to the advancement of fundamental knowledge, equations of practical engineering importance have been obtained for the calculations of mass and heat transfer processes carried out in conditions of high turbulence, and developed for the implementation in fast chemical reactions involving the synthesis of low molecular weight products and polymers. New methods for controlling the molecular characteristics of polymers have been developed based on the tailored regulation of the hydrodynamics of the reactive mixture flow. Typical processes have been used as model examples to reveal the influence of turbulence on the behaviour of fast chemical reactions used for the synthesis of low molecular weight products, in single-phase and two-phase reactive systems. Brand new tubular devices have been developed with the following characteristics: compact size, high productivity, and a quasi-perfect mixing operation mode in turbulent flows. These devices are subdivided into cylindrical, shell-and-tube, 'zone', and diffuser-confusor designs. Original solutions are proposed for the instrumental implementation of fast liquid-phase processes and development of continuous energy- and resource-efficient technologies for the synthesis of some large-scale compounds.
Author: Roger Prudhomme
Publisher: John Wiley & Sons
ISBN: 1119902967
Category : Science
Languages : en
Pages : 258
Get Book Here
Book Description
Interfaces are present in most fluid mechanics problems. They not only denote phase separations and boundary conditions, but also thin flames and discontinuity waves. Fluid Mechanics at Interfaces 1 focuses on the science of interfaces, in particular, using various scientific methods of analysis relating to space, speed and time. Our investigation takes us from the microscopic or small scale (starting with molecular and nanoscopic scales) to the macroscopic (including meso and interstellar scales), and also explores the laws of interfaces (classical mechanics, quantum mechanics and relativistic mechanics). Chapter 1 examines the questions raised by modeling interfaces in the presence of one or more fluid phases. Chapter 2 discusses the action of turbulence in liquid–vapor flows that contain both small, dispersed bubbles as well as large bubbles, with heat exchanges at the interfaces. In addition, a new model is presented, using large eddy simulation (LES). Chapter 3 studies an original method for calculating the drag force and thermal transfers in flows around networks of spherical particles, while Chapter 4 focuses on the relationships between interfaces and critical fluids. Chapter 5 examines shearing, which causes anomalies in the Brownian motion of particles in strongly fluctuating near-critical mixtures, and Chapter 6 introduces basic concepts related to combustion interfaces, raising the question of the combustion of solids, before ending with a brief presentation of the Rankine–Hugoniot theory and a historical overview of the research carried out in the field of combustion.
Author: Roger Prudhomme
Publisher: John Wiley & Sons
ISBN: 1786308177
Category : Science
Languages : en
Pages : 178
Get Book Here
Book Description
Interfaces are present in most fluid mechanics problems. They not only denote phase separations and boundary conditions, but also thin flames and discontinuity waves. Fluid Mechanics at Interfaces 2 examines cases that involve one-dimensional or bi-dimensional manifolds, not only in gaseous and liquid physical states but also in subcritical fluids and in single- and multi-phase systems that may be pure or mixed. Chapter 1 addresses certain aspects of turbulence in discrete mechanics, briefly describing the physical model associated with discrete primal and dual geometric topologies before focusing on channel flow simulations at turbulence-inducing Reynolds numbers. Chapter 2 centers on atomization in an accelerating domain. In one case, an initial Kelvin–Helmholtz instability generates an acceleration field, in turn creating a Rayleigh–Taylor instability which ultimately determines the size of the droplets formed. Chapter 3 explores numerical studies of pipes with sudden contraction using OpenFOAM, and focuses on modeling that will be useful for engines and automobiles. Chapters 4 and 5 study the evaporation of droplets that are subject to high-frequency perturbations, a possible cause of instabilities in injection engines. The Heidmann model, which replaces the droplets in motion in a combustion chamber with a single continuously-fed droplet, is made more complex by considering the finite conduction heat transfer phenomenon. Finally, Chapter 6 is devoted to a study of the rotor blade surface of a Savonius wind turbine, considering both a non-stationary and a three-dimensional flow.
