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Author: Eberhard Steckhan
Publisher: Springer
ISBN: 9783540182269
Category : Science
Languages : en
Pages : 208
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Book Description
Contents/Information: C.E. Lunte, W.R. Heineman, Cincinnati, OH, USA: ""Electrochemical Techniques in Bioanalysis""
Author: Eberhard Steckhan
Publisher: Springer
ISBN: 9783540182269
Category : Science
Languages : en
Pages : 208
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Book Description
Contents/Information: C.E. Lunte, W.R. Heineman, Cincinnati, OH, USA: ""Electrochemical Techniques in Bioanalysis""
Author: Mandeep Dalal
Publisher: Dalal Institute
ISBN: 8193872010
Category : Science
Languages : en
Pages : 432
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Book Description
An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Author: John O'M. Bockris
Publisher: Springer Science & Business Media
ISBN: 9780306250026
Category : Science
Languages : en
Pages : 876
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Book Description
7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El.
Author: Carl H. Hamann
Publisher: Wiley-VCH
ISBN: 9783527310692
Category : Science
Languages : en
Pages : 550
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Book Description
This second, completely updated edition of a classic textbook provides a concise introduction to the fundamental principles of modern electrochemistry, with an emphasis on applications in energy technology. The renowned and experienced scientist authors present the material in a didactically skilful and lucid manner. They cover the physical-chemical fundamentals as well as such modern methods of investigation as spectroelectrochemistry and mass spectrometry, electrochemical analysis and production methods, as well as fuel cells and micro- and nanotechnology. The result is a must-have for advanced chemistry students as well as those studying chemical engineering, materials science and physics.
Author: Allen J. Bard
Publisher: Wiley Global Education
ISBN: 1118312805
Category : Science
Languages : de
Pages : 862
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Book Description
Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.
Author: Indiana University
Publisher:
ISBN:
Category :
Languages : en
Pages : 572
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Book Description
Author: University of Wisconsin
Publisher:
ISBN:
Category :
Languages : en
Pages : 750
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Book Description
Some nos. include Announcement of courses.
Author: Noam Eliaz
Publisher: John Wiley & Sons
ISBN: 3527341390
Category : Science
Languages : en
Pages : 480
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Book Description
This bestselling textbook on physical electrochemistry caters to the needs of advanced undergraduate and postgraduate students of chemistry, materials engineering, mechanical engineering, and chemical engineering. It is unique in covering both the more fundamental, physical aspects as well as the application-oriented practical aspects in a balanced manner. In addition it serves as a self-study text for scientists in industry and research institutions working in related fields. The book can be divided into three parts: (i) the fundamentals of electrochemistry; (ii) the most important electrochemical measurement techniques; and (iii) applications of electrochemistry in materials science and engineering, nanoscience and nanotechnology, and industry. The second edition has been thoroughly revised, extended and updated to reflect the state-of-the-art in the field, for example, electrochemical printing, batteries, fuels cells, supercapacitors, and hydrogen storage.
Author: J. A. McCleverty
Publisher: Newnes
ISBN: 0080913164
Category : Science
Languages : en
Pages : 11845
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Book Description
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
Author:
Publisher: UM Libraries
ISBN:
Category : Education, Higher
Languages : en
Pages : 828
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Book Description
