Effect of Variable Fuel Composition on Emissions and Lean Blowoff Stability Performance

Effect of Variable Fuel Composition on Emissions and Lean Blowoff Stability Performance PDF Author: Andrés Colorado
Publisher:
ISBN:
Category : Fuel switching
Languages : en
Pages : 42

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Effect of Variable Fuel Composition on Emissions and Lean Blowoff Stability Performance

Effect of Variable Fuel Composition on Emissions and Lean Blowoff Stability Performance PDF Author: Andrés Colorado
Publisher:
ISBN:
Category : Fuel switching
Languages : en
Pages : 42

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Effect of Variable Fuel Composition on Emissions and Lean Blowoff Stability Performance

Effect of Variable Fuel Composition on Emissions and Lean Blowoff Stability Performance PDF Author: Andrés Colorado
Publisher:
ISBN:
Category : Fuel switching
Languages : en
Pages : 54

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Evaluation of the Performance of a Variable Geometry Low-swirl Burner Operated on Simulated Renewable Fuels in a Boiler Environment

Evaluation of the Performance of a Variable Geometry Low-swirl Burner Operated on Simulated Renewable Fuels in a Boiler Environment PDF Author: Nathan James Kirksey
Publisher:
ISBN: 9781321441352
Category :
Languages : en
Pages : 152

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This thesis evaluates a variable blockage low-swirl injector operated on digester gas in a simulated boiler environment to understand how such a device can impact combustion performance as fuel composition varies. California, like many other states, is requiring a reduction in emissions from primary sources of electricity generation. As emission regulations become stricter, novel strategies for achieving the reductions required are required. The current energy policy in California specifically promotes the use of renewable and carbon neutral fuels such as digester gas. The future generations of burners must be fuel flexible in order to meet these emission laws while providing continual operation. To address this, a variable geometry low-swirl injector was developed and its emissions and stability performance assessed using a variety of diagnostics. It was found that a fiber optic probe, integrated into the injector head, was able to provide a reliable measure of emissions and stability. One key result from the optical probe is that the recorded radiation emitted by the reaction corresponding to the lean blow off limits of any composition of digester gas remains constant, implying it could serve as a robust stability sensor with minimal signal processing. Evaluating the role of the variable geometry found that (1) variable center blockage in a low-swirl injector has no effect on the lean blow off limits, (2) as the center blockage becomes less restrictive the NOx emissions will increase, and (3) incorporation of a quarl expansion rather than a sudden expansion increased the lean blow off limits and gave a 50% reduction in NOx emissions. Utilizing a low-swirl injector with high blockage in the central flow, high swirl number, can reduce the NOx emissions across the range of lean operating conditions.

Effects of Fuel Composition on Combustion Stability and NO Emissions for Traditional and Alternative Jet Fuels

Effects of Fuel Composition on Combustion Stability and NO Emissions for Traditional and Alternative Jet Fuels PDF Author: Shazib Z. Vijlee
Publisher:
ISBN:
Category : Flame stability
Languages : en
Pages : 206

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Book Description
Synthetic jet fuels are studied to help understand their viability as alternatives to traditionally derived jet fuel. Two combustion parameters - flame stability and NOX emissions - are used to compare these fuels through experiments and models. At its core, this is a fuels study comparing how chemical makeup and behavior relate. Six 'real', complex fuels are studied in this work - four are synthetic from alternative sources and two are traditional from petroleum sources. Two of the synthetic fuels are derived from natural gas and coal via the Fischer Tropsch catalytic process. The other two are derived from Camelina oil and tallow via hydroprocessing. The traditional military jet fuel, JP8, is used as a baseline as it is derived from petroleum. The sixth fuel is derived from petroleum and is used to study the effects of aromatic content on the synthetic fuels. The synthetic fuels lack aromatic compounds, which are an important class of hydrocarbons necessary for fuel handling systems to function properly. Several single-component fuels are studied (through models and/or experiments) to facilitate interpretation and understanding. Methane is used for detailed modeling as it has a relatively small and well-understood chemical kinetic mechanism. Toluene, iso-octane, n-octane, propylcyclohexane, and 1,3,5-trimethylbenzene are included as they are all potential surrogates for jet fuel components. The flame stability study first compares all the `real', complex fuels for blowout. A toroidal stirred reactor is used to try and isolate temperature and chemical effects. The reactor has a volume of 250 mL and a residence time of approximately 8.0 ms. The air flow rate is held constant such that the inlet jets are sonic and turbulent mixing is present throughout the reactor. The fuel flow rate (hence equivalence ratio) is slowly lowered until the flame cannot sustain itself and it extinguishes. The results show that there is very little variation in blowout temperature and equivalence ratio for the synthetic fuels when compared to JP8 with low levels (0, 10, and 20%) of the aromatic additive. However, the 100% aromatic fuel behaved significantly differently and showed a lower resistance to blowout (i.e., it blew out at a higher temperature and equivalence ratio). The modeling study of blowout in the toroidal reactor is the key to understanding any fuel-based differences in blowout behavior. A detailed, reacting CFD model of methane is used to understand how the reactor stabilizes the flame and how that changes as the reactor approaches blowout. A 22 species reduced form of GRI 3.0 is used to model methane chemistry. The model shows that the reactor is quite homogenous at high temperatures, far away from blowout, and the transport of chain-initiating and chain-branching radical species is responsible for stabilizing the flame. Particularly, OH radical is recirculated around the reactor with enough concentration and at a high enough rate such that the radicals interact with the incoming fuel/air and initiate fuel decomposition. However, as equivalence ratio decreases, the reactor begins to behave in a more zonal nature and the radical concentration/location is no longer sufficient to initiate or sustain combustion. The knowledge of the radical species role is utilized to investigate the differences between a highly aliphatic fuel (surrogated by iso-octane) and a highly aromatic fuel (surrogated by toluene). A perfectly stirred reactor model is used to study the chemical kinetic pathways for these fuels near blowout. The differences in flame stabilization can be attributed to the rate at which these fuels are attacked and destroyed by radical species. The slow disintegration of the aromatic rings reduces the radical pool available for chain-initiating and chain-branching, which ultimately leads to an earlier blowout. The NOX study compares JP8, the aromatic additive, the synthetic fuels with and without an aromatic additive, and an aromatic surrogate (1,3,5-trimethylbenzene). A jet stirred reactor is used to try and isolate temperature and chemical effects. The reactor has a volume of 15.8 mL and a residence time of approximately 2.5 ms. The fuel flow rate (hence equivalence ratio) is adjusted to achieve nominally consistent temperatures of 1800, 1850, and 1900K. Small oscillations in fuel flow rate cause the data to appear in bands, which facilitated Arrhenius-type NOX-temperature correlations for direct comparison between fuels. The fuel comparisons are somewhat inconsistent, especially when the aromatic fuel is blended into the synthetic fuels. In general, the aromatic surrogate (1,3,5-trimethylbenzene) produces the most NOX, followed by JP8. The synthetic fuels (without aromatic additive) are always in the same ranking order for NOX production (HP Camelina > FT Coal > FT Natural Gas > HP Tallow). The aromatic additive ranks differently based on the temperature, which appears to indicate that some of the differences in NOX formation are due to the Zeldovich NOX formation pathway. The aromatic additive increases NOX for the HP Tallow and decreases NOX for the FT Coal. The aromatic additive causes increased NOX at low temperatures but decreases NOX at high temperatures for the HP Camelina and FT Natural Gas. A single perfectly stirred reactor model is used with several chemical kinetic mechanisms to study the effects of fuel (and fuel class) on NOX formation. The 27 unique NOX formation reactions from GRI 3.0 are added to published mechanisms for jet fuel surrogates. The investigation first looked at iso-octane and toluene and found that toluene produces more NOX because of a larger pool of O radical. The O radical concentration was lower for iso-octane because of an increased concentration of methyl (CH3) radical that consumes O radical readily. Several surrogate fuels (iso-octane, toluene, propylcyclohexane, n-octane, and 1,3,5-trimethylbenzene) are modeled to look for differences in NOX production. The trend (increased CH3→ decreased O → decreased NOX) is consistently true for all surrogate fuels with multiple kinetic mechanisms. It appears that the manner in which the fuel disintegrates and creates methyl radical is an extremely important aspect of how much NOX a fuel will produce.

Combustion Behavior Associated with Alternative Fuels in Lean Premixed, High-swirl Stabilized Distributed Reactions

Combustion Behavior Associated with Alternative Fuels in Lean Premixed, High-swirl Stabilized Distributed Reactions PDF Author: Amin Akbari
Publisher:
ISBN: 9781303167799
Category :
Languages : en
Pages : 195

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Lean blowoff, flashback and pollutant emission associated with lean premixed combustion of alternative fuels stabilized by high swirl are evaluated in this work. Alternative fuel compositions include blends of natural gas and hydrogen. Lean blowoff refers to events where the fuel-to-air ratio is not sufficient to sustain the reaction. Blowoff is often a dynamic process consisting of several stages. Correlations based on constant Damköhler (Da) number are able to estimate the impact of fuel composition on lean blowoff for the conditions studied. The accuracy of estimating initiation of blowoff is superior compared to estimation of subsequent stages of blowoff. Flashback refers to propagation of the reaction upstream into the premixing zone. In high swirl combustion applications, the concept of a quench criterion has been proposed for predicting flashback. For the present work, this concept only holds for some measured cases, which indicates multiple flashback modes even in high swirl combustion applications. The other major combustion challenge is pollutant emission. In this study NOx, CO, and N2O levels are experimentally measured. In addition, a chemical reaction network (CRN) was developed to study the details of emission formation. To develop a CRN, details of the reacting flow were needed. Hence, computational fluid dynamics (CFD) simulations were conducted. To validate CFD simulations, particle image velocimetry (PIV) and OH* chemiluminescence flame front imaging were applied. OH* chemiluminescence was also employed to visualize the flame structure and shape for different fuel compositions. The CRN simulations indicate that the NNH NOx formation pathway dominates the other formation pathways. Thus, conditions that enhance NNH NOx, such as an increase of hydrogen in fuel composition, and decrease of residence time, will result in more total NOx. The CRN also illustrates how the relative contribution of each NOx formation pathway to total NOx changes with adiabatic flame temperature (AFT). The NNH NOx formation pathway is dominant for AFT below 1900K; the Zeldovich mechanism is dominant for AFT above 1900K. In terms of N2O emissions measured and simulated results suggest the levels are negligible even for very low combustion temperatures.

Effects of Ambient Conditions and Fuel Composition on Combustion Stability

Effects of Ambient Conditions and Fuel Composition on Combustion Stability PDF Author: Michael C. Janus
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Presented at the International Gas Turbine & Aeroengine Congress & Exhibition, Orlando, FL, Jun 2 - Jun 5, 1997.

Effect of Fuel Composition on Exhaust Emissions from a Spark-ignition Engine

Effect of Fuel Composition on Exhaust Emissions from a Spark-ignition Engine PDF Author: Ralph David Fleming
Publisher:
ISBN:
Category : Automobiles
Languages : en
Pages : 76

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The Effects of Natural Gas Composition on Engine Combustion, Performance, and Emissions

The Effects of Natural Gas Composition on Engine Combustion, Performance, and Emissions PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 15

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Effect of Fuel Composition on the Operation of a Lean Burn Natural Gas Engine

Effect of Fuel Composition on the Operation of a Lean Burn Natural Gas Engine PDF Author: Nigel N. Clark
Publisher:
ISBN:
Category : Automobiles
Languages : en
Pages :

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Scientific and Technical Aerospace Reports

Scientific and Technical Aerospace Reports PDF Author:
Publisher:
ISBN:
Category : Aeronautics
Languages : en
Pages : 688

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Book Description
Lists citations with abstracts for aerospace related reports obtained from world wide sources and announces documents that have recently been entered into the NASA Scientific and Technical Information Database.