Dissociative Recombination of Molecular Ions with Electrons

Dissociative Recombination of Molecular Ions with Electrons PDF Author: Steven L. Guberman
Publisher: Springer Science & Business Media
ISBN: 1461500834
Category : Science
Languages : en
Pages : 467

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Book Description
Dissociative Recombination of Molecular Ions with Electrons is a comprehensive collection of refereed papers describing the latest developments in dissociative recombination research. The papers are written by the leading researchers in the field. The topics covered include the use of microwave afterglows, merged beams and storage rings to measure rate coefficients and to identify the products and their yields. The molecules studied range in size from the smallest, H2+, to bovine insulin ions. The theoretical papers cover the important role of Rydberg states and the use of wave packets and quantum defect theory to deduce cross sections, rate constants and quantum yields. Several theoretical and experimental papers address the controversial topic of H3+ dissociative recombination and its importance in the interstellar medium. Dissociative recombination studies of other molecular ions in the interstellar medium and in cometary and planetary atmospheres are covered. Ionization is an important competitive process to dissociative recombination and its competition with predissociation and its role in the reverse process of the association of neutral species is presented. Dissociative attachment, in which an electron attaches to a neutral molecule, has many similarities to dissociative recombination. The topics covered include the accurate calculation of electron affinities, attachment to molecules, clusters, and to species absorbed on solid surfaces and electron scattering by a molecular anion.

Dissociative Recombination of Molecular Ions with Electrons

Dissociative Recombination of Molecular Ions with Electrons PDF Author: Steven L. Guberman
Publisher: Springer Science & Business Media
ISBN: 1461500834
Category : Science
Languages : en
Pages : 467

Get Book

Book Description
Dissociative Recombination of Molecular Ions with Electrons is a comprehensive collection of refereed papers describing the latest developments in dissociative recombination research. The papers are written by the leading researchers in the field. The topics covered include the use of microwave afterglows, merged beams and storage rings to measure rate coefficients and to identify the products and their yields. The molecules studied range in size from the smallest, H2+, to bovine insulin ions. The theoretical papers cover the important role of Rydberg states and the use of wave packets and quantum defect theory to deduce cross sections, rate constants and quantum yields. Several theoretical and experimental papers address the controversial topic of H3+ dissociative recombination and its importance in the interstellar medium. Dissociative recombination studies of other molecular ions in the interstellar medium and in cometary and planetary atmospheres are covered. Ionization is an important competitive process to dissociative recombination and its competition with predissociation and its role in the reverse process of the association of neutral species is presented. Dissociative attachment, in which an electron attaches to a neutral molecule, has many similarities to dissociative recombination. The topics covered include the accurate calculation of electron affinities, attachment to molecules, clusters, and to species absorbed on solid surfaces and electron scattering by a molecular anion.

Dissociative Recombination of Molecular Ions

Dissociative Recombination of Molecular Ions PDF Author: Mats Larsson
Publisher: Cambridge University Press
ISBN: 9781107407671
Category : Science
Languages : en
Pages : 394

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Book Description
Dissociative recombination (DR) of molecular ions with electrons is a complex, poorly understood molecular process. Its critical role as a neutralising agent in the Earth's upper atmosphere is now well established and its occurrence in many natural and laboratory-produced plasma has been a strong motivation for studying the event. In this book theoretical concepts, experimental methodology and applications are united, revealing the governing principles behind the gas-phase reaction. The book takes the reader through the intellectual challenges posed, describing in detail dissociation mechanisms, dynamics, diatomic and polyatomic ions and related processes, including dissociative excitation, ion pair formation and photodissociation. With the final chapter dedicated to applications in astrophysics, atmospheric science, plasma physics and fusion research, this is a focused, definitive guide to a fundamental molecular process. The book will appeal to academics within physics, physical chemistry and related sciences.

Dissociative Recombination

Dissociative Recombination PDF Author: Bertrand R. Rowe
Publisher: Springer Science & Business Media
ISBN: 146152976X
Category : Science
Languages : en
Pages : 277

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Book Description
Proceedings of a NATO ARW held in Saint Jacut de la Mer, Brittany, France, May 3-8, 1992

Dissociative Recombination: Theory, Experiments And Applications Iv

Dissociative Recombination: Theory, Experiments And Applications Iv PDF Author: Mats Larsson
Publisher: World Scientific
ISBN: 9814543357
Category : Science
Languages : en
Pages : 314

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Book Description
Dissociative recombination is a complex molecular process that occurs in any plasma cold enough to contain molecular constituents. It is the dominant recombination process in planetary ionospheres and interstellar clouds. In this book, recent developments in the fields of molecular ion physics, atomic and molecular theory, astrochemistry, aeronomy and plasma physics are discussed.

Dissociative Recombination, Theory, Experiment And Applications Iii

Dissociative Recombination, Theory, Experiment And Applications Iii PDF Author: Daniel Zajfman
Publisher: World Scientific
ISBN: 981454857X
Category :
Languages : en
Pages : 270

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Book Description
In this book, the latest developments in the study of the dissociative recombination of electrons and molecular ions are discussed. This process is of great importance in controlling the physical and chemical states of ionized gases. It has direct application to astrophysics, aeronomy, thermonuclear fusion research, plasma processing and combustion science.

Proceedings of the 1995 Workshop on Dissociative Recombination

Proceedings of the 1995 Workshop on Dissociative Recombination PDF Author: Daniel Zajfman
Publisher:
ISBN: 9789814532129
Category : SCIENCE
Languages : en
Pages :

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Book Description


Proceedings of the 1995 Workshop on Dissociative Recombination

Proceedings of the 1995 Workshop on Dissociative Recombination PDF Author: Daniel Zajfman
Publisher: World Scientific Publishing Company Incorporated
ISBN: 9789810224431
Category : Dissociation
Languages : en
Pages : 254

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Book Description


Products of Dissociative Recombination in the Ionosphere

Products of Dissociative Recombination in the Ionosphere PDF Author: National Aeronautics and Space Administration (NASA)
Publisher: Createspace Independent Publishing Platform
ISBN: 9781722701406
Category :
Languages : en
Pages : 56

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Book Description
SRI International undertook a novel experimental measurement of the product states formed by dissociative ro-combination (DR) of C2(+), NO(+), and N2(+) as a function of both electron energy and reactant ion vibrational level. For these measurements we used a recently developed experimental technique for measuring dissociation product distributions that allows both the branching ratios to be accurately determined and the electronic and ro-vibrational state composition of the reactant ions to be specified. DR is the dominant electron loss mechanism in all regions of the ionosphere. In this process, electron attachment to the molecular ion produces an unstable neutral molecule that rapidly dissociates. Cosby, Philip Unspecified Center...

Proceedings of the 1999 Conference on Dissociative Recombination

Proceedings of the 1999 Conference on Dissociative Recombination PDF Author: Mats Larsson
Publisher: World Scientific Publishing Company Incorporated
ISBN: 9789810240776
Category : Science
Languages : en
Pages : 298

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Book Description
Dissociative recombination is a complex molecular process that occurs in any plasma cold enough to contain molecular constituents. It is the dominant recombination process in planetary ionospheres and interstellar clouds. In this book, recent developments in the fields of molecular ion physics, atomic and molecular theory, astrochemistry, aeronomy and plasma physics are discussed.

Photoionization and Photodetachment

Photoionization and Photodetachment PDF Author: Cheuk-Yiu Ng
Publisher: World Scientific
ISBN: 9814494739
Category : Science
Languages : en
Pages : 1416

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Book Description
Owing to the advances of vacuum ultraviolet and ultrafast lasers and third generation synchrotron sources, the research on photoionization, photoelectrons, and photodetachment has gained much vitality in recent years. These new light sources, together with ingenious experimental techniques, such as the coincidence imaging, molecular beam, pulsed field ionization photoelectron, mass-analyzed threshold ion, and pulsed field ion pair schemes, have allowed spectroscopic, dynamic, and energetic studies of gaseous species to a new level of detail and accuracy. Profitable applications of these methods to liquids are emerging. This invaluable two-volume review consists of twenty-two chapters, focusing on recent developments in photoionization and photodetachment studies of atoms; molecules, transient species, clusters, and liquids. Contents:Part I:Velocity Mapping Studies of Molecular Photodissociation and Photoionization Dynamics (D H Parker)Coherent Control of Photodissociation and Photoionization (R J Gordon & L-C Zhu)Non-Adiabatic Dynamics Studied by Femtosecond Time-Resolved Photoelectron Spectroscopy (C C Hayden & A Stolow)Femtosecond Time-Resolved Photoelectron Spectroscopy of Molecules and Clusters by Photoion-Photoelectron Coincidence Detection (W Radloff) The Renner-Teller Effect and the Role of Electronically Degenerate States in Molecular Ions (P Rosmus & G Chambaud)Zero-Kinetic-Energy Photoelectron Spectroscopic Studies of Aromatic-Argon van der Waals Complexes (K Kimura)Mass-Analyzed Cation Spectroscopy Using Rydberg States: MATI and PIRI (P M Johnson)High Resolution Threshold Photoelectron and Photoelectron-Photoion Coincidence Spectroscopy Using Synchrotron Radiation (Y Morioka)Advances in Photoionization and Photoelectron Studies Using Third Generation Synchrotron Radiation and UV/VUV Lasers (C-Y Ng)Unimolecular Reactions of Molecular Ions and Cluster Ions — From Thermal Towards State-Selective Experiments (K-M Weitzel)Laser Two-Photon Ionization in Solution and on Surface in Ambient Air: Investigations Through Conductivity Measurement (T Ogawa)Photoelectron Spectroscopy at Liquid Surfaces (M Faubel)Part II:Dissociative Electron-Ion Recombination Studies Using Ion Synchrotrons (M Larsson)Dissociative Photodetachment Studies of Transient Molecules by Coincidence Techniques (R E Continetti)Mass Selected Anion-Zero Kinetic Energy Photoelectron Spectroscopy (U Boesl et al.)Photodetachment Photoelectron Spectroscopy of Transition Metal Oxide Species (L-S Wang)Detachment Processes for Molecular Anions (J Simons)Competition Between Autoionization and Predissociation in Molecular Rydberg States (S T Pratt)Electron Capture Processes by Free and Bound Molecules (E Illenberger)Visualization of Electron Correlations in Doubly and Triply Excited States of Atoms (C D Lin & T Morishita)High-Resolution Angle-Resolved Studies of Atoms and Molecules Using Advanced Electron Spectroscopy at the ALS (N Berrah)X-Ray Scattering and Fluorescence from Atoms and Molecules (S H Southworth et al.) Readership: Researchers in physical chemistry, and atomic and molecular physics. Keywords:Reviews: “These volumes will occupy a prominent place on the bookshelf of virtually every practitioner in this field, and the various sets of chapters will be the subject of many student presentations to their research groups.” Journal of the American Chemical Society