The Activation of Dioxygen and Homogeneous Catalytic Oxidation PDF Download
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Author: D.H.R. Barton
Publisher: Springer Science & Business Media
ISBN: 1461530008
Category : Science
Languages : en
Pages : 503
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Book Description
This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract form are invited to communicate directly with the authors of the abstracts. This is the fifth international symposium that has been held on this subject. The first was hosted by the CNRS, May 21-29, 1979, in Bendor, France (on the Island of Bandol). The second meeting was organized as a NATO workshop in Padova, Italy, June 24-27, 1984. This was followed by a meeting in Tsukuba, Japan, July 12-16, 1987. The fourth symposium was held at Balatonfured, Hungary, September 10-14, 1990. The sixth meeting is scheduled to take place in Delft, The Netherlands (late Spring, 1996); the organizer and host will be Professor R. A. Sheldon.
Author: D.H.R. Barton
Publisher: Springer Science & Business Media
ISBN: 1461530008
Category : Science
Languages : en
Pages : 503
Get Book Here
Book Description
This monograph consists of the proceedings of the Fifth International Symposium on the Activation of Dioxygen and Homogeneous Catalytic Oxidation, held in College Station, Texas, March 14-19, 1993. It contains an introductory chapter authored by Professors D. H. R. Barton and D. T. Sawyer, and twenty-nine chapters describing presentations by the plenary lecturers and invited speakers. One of the invited speakers, who could not submit a manuscript for reasons beyond his control, is represented by an abstract of his lecture. Also included are abstracts of forty-seven posters contributed by participants in the symposium. Readers who may wish to know more about the subjects presented in abstract form are invited to communicate directly with the authors of the abstracts. This is the fifth international symposium that has been held on this subject. The first was hosted by the CNRS, May 21-29, 1979, in Bendor, France (on the Island of Bandol). The second meeting was organized as a NATO workshop in Padova, Italy, June 24-27, 1984. This was followed by a meeting in Tsukuba, Japan, July 12-16, 1987. The fourth symposium was held at Balatonfured, Hungary, September 10-14, 1990. The sixth meeting is scheduled to take place in Delft, The Netherlands (late Spring, 1996); the organizer and host will be Professor R. A. Sheldon.
Author: L. I. Simándi
Publisher: Elsevier Publishing Company
ISBN:
Category : Science
Languages : en
Pages : 748
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Book Description
Dioxygen activation is a rapidly developing field in which research is directed at (1) modelling of biological oxidations, (2) design and utilization of new catalysts for oxidative transformations of organic substrates, (3) application of O 2 (and H 2 O 2 ) as a cheap oxidant in the manufacture of fine and bulk chemicals. Provided here is a collection of both review and original papers covering all aspects of dioxygen activation. All papers provide background information of previous work. Reactions mechanisms are extensively treated and a keyword index facilitates quick orientation. The book should prove invaluable to organic, bioinorganic and coordination chemists as well as biochemists interested in homogeneous catalysis.
Author: László I. Simándi
Publisher: Springer Science & Business Media
ISBN: 9780792318965
Category : Science
Languages : en
Pages : 420
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Book Description
The activation of dioxygen by metal ions has both synthetic potential and biological relevance. Dioxygen is the cleanest oxidant for use in emission-free technologies to minimize pollution of the environment. The book gives a survey of those catalyst systems based on metal complexes which have been discovered and studied in the last decade. They activate molecular oxygen and effect the oxidation of various organic compounds under mild conditions. Much of the recent progress is due to a search for biomimetic catalysts that would duplicate the action of metalloenzymes. Mechanistic aspects are emphasized throughout the book. An introductonary chapter reviews the chemistry of transition metal dioxygen complexes, which are usually the active intermediates in the catalytic reactions discussed. Separate chapters are devoted to oxidation of saturated, unsaturated and aromatic hydrocarbons, phenols, catechols, oxo-compounds, phosphorus, sulfur and nitrogen compounds.
Author: László I. Simándi
Publisher: Springer Science & Business Media
ISBN: 0306478161
Category : Science
Languages : en
Pages : 349
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Book Description
The subject of dioxygen activation and homogeneous catalytic oxidation by metal complexes has been in the focus of attention over the last 20 years. The widespread interest is illustrated by its recurring presence among the sessions and subject areas of important international conferences on various aspects of bioinorganic and coordination chemistry as well as catalysis. The most prominent examples are ICCC, ICBIC, EUROBIC, ISHC, and of course the ADHOC series of meetings focusing on the subject itself. Similarly, the number of original and review papers devoted to various aspects of dioxygen activation are on the rise. This trend is due obviously to the relevance of catalytic oxidation to biological processes such as dioxygen transport, and the action of oxygenase and oxidase enzymes related to metabolism. The structural and functional modeling of metalloenzymes, particularly of those containing iron and copper, by means of low-molecular complexes of iron, copper, ruthenium, cobalt, manganese, etc., have provided a wealth of indirect information helping to understand how the active centers of metalloenzymes may operate. The knowledge gained from the study of metalloenzyme models is also applicable in the design of transition metal complexes as catalytsts for specific reactions. This approach has come to be known as biomimetic or bioinspired catalysis and continues to be a fruitful and expanding area of research.
Author: Christopher S. Foote
Publisher: Springer Science & Business Media
ISBN: 9400708742
Category : Science
Languages : en
Pages : 355
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Book Description
Taking an interdisciplinary approach, this book and its counterpart, Active Oxygen in Biochemistry, explore the active research area of the chemistry and biochemistry of oxygen. Complementary but independent, the two volumes integrate subject areas including medicine, biology, chemistry, engineering, and environmental studies.
Author: Philippe Arpentinier
Publisher: Editions TECHNIP
ISBN: 9782710807773
Category : Science
Languages : en
Pages : 490
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Book Description
Volume 1 covers the most important technological aspects of the use of molecular oxygen for catalytic oxidation reactions.Volume 2 addresses the safety issues associated with the use of oxygen in catalytic oxidation reactions.Contents Vol. 1: 1. Introduction. 2. Chemical-physical properties of molecular oxygen. 3. Oxygen production technologies. 4. Chemical fundamentals of oxidation reactions. 5. Reactor technologies for multiphase systems. 6. Liquid phase oxidations. 7. Gas phase selective oxidations. 8. Selective oxidation of paraffins. References. Index. Vol. 2: 9. Introduction to safety problems in the chemical industry. 10. Chemical aspects of combustion in the gaseous phase. 11. Homogeneous chemical explosions: autoignition or spontaneous ignition. 12. Deflagration or propagation of flame. 13. Conditions governing flame propagation capability. 14. Detonation in the gaseous phase. 15. Prevention of and protection against explosions. References. Index.
Author: Mario G. Clerici
Publisher: John Wiley & Sons
ISBN: 1118356756
Category : Science
Languages : en
Pages : 438
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Book Description
Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.
Author: Shannon S. Stahl
Publisher: John Wiley & Sons
ISBN: 3527337814
Category : Technology & Engineering
Languages : en
Pages : 454
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Book Description
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
Author: B. Delmon
Publisher: Elsevier
ISBN: 008053435X
Category : Technology & Engineering
Languages : en
Pages : 594
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Book Description
The symposium on Hydrotreatment and Hydrocracking of Oil Fractions aims to provide a global perspective and an inspection of the state-of-the-art of these processes. New American, European and Japanese environmental regulations call for advanced hydrotreatment processes for HDS and HDN for the removal of S- and Ni-components from oil fractions. These will alter the product slate of the oil refineries and the hydrocarbon composition of these products. Hydrocracking will play an important part in this shift.Adapting the operating conditions will not suffice to reach the desired product specifications and yields. Adequate catalysts will have to be developed. Powerful tools are now available for this, e.g. surface science techniques, molecular modeling and new types of reactors operated in a nonsteady mode.Another instrument in the improvement of hydrotreatment and hydrocracking units is the availability of more realistic kinetic models. These are based on a judicious insight into the reaction mechanism, also provided by the above-mentioned tools. Progress in the analytical techniques has allowed the reduction of the lumping of components in these kinetic models and first order kinetic equations are gradually replaced by equations accounting for the adsorption of the various components.More detailed and more realistic reactor models are now based on rigorous hydrodynamic models and their application has become possible through the rapidly increasing possibilities of computers.
Author: Sang-Eon Park
Publisher: Elsevier
ISBN: 0080472176
Category : Technology & Engineering
Languages : en
Pages : 626
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Book Description
Addressing global environmental problems, such as global warming is essential to global sustainability. Continued research leads to advancement in standard methods and produces new data. Carbon Dioxide Utilization for Global Sustainability: Proceedings of the 7th ICCDU (International Conference on Carbon Dioxide Utilization) reflects the most recent research results, as well as stimulating scientific discussions with new challenges in advancing the development of carbon dioxide utilization. Drawing on a wealth of information, this well structured book will benefit students, researchers and consultants looking to catch up on current developments in environmental and chemical engineering.* Provides comprehensive data on CO2 utilisation* Contains up-to-date information, including recent research trends* Is written for students, researchers and consultants in environmental and chemical engineering
