Determination of Nitrated/oxygenated Polycyclic Aromatic Hydrocarbons and Personal Care Products in River Water, Sediment, Fish Muscle and Liver with Ultra-performance Liquid Chromatography/tandem Mass Spectrometry PDF Download
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Author: 唐子杰
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: 唐子杰
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Author: Yanhui Yu
Publisher:
ISBN:
Category : Polycyclic aromatic hydrocarbons
Languages : en
Pages : 428
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Author: British Standards Institute Staff
Publisher:
ISBN: 9780580403576
Category : High performance liquid chromatography
Languages : en
Pages : 32
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Book Description
Water, Quality, Water testing, Chemical analysis and testing, Determination of content, Aromatic hydrocarbons, Polynuclear aromatic hydrocarbons, Liquid chromatography, Extraction methods of analysis, Fluorescence, Potable water, Ground water
Author: Wang Huiyong
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 232
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Book Description
Polycyclic aromatic hydrocarbons (PAH) are important environmental pollutants originating from a wide variety of natural and anthropogenic sources. Because many of them are highly suspect as etiological agents in human cancer, chemical analysis of PAH is of great environmental and toxicological importance. Current methodology for PAH follows the classical pattern of sample preparation and chromatographic analysis. Sample preparation pre-concentrates PAH, simplifies matrix composition, and facilitates analytical resolution in the chromatographic column. Among the several approaches that exist to pre-concentrate PAH from water samples, the Environmental Protection Agency (EPA) recommends the use of solid-phase extraction (SPE). High-performance liquid chromatography (HPLC) and gas chromatography-mass spectrometry (GC-MS) are the basis for standard PAH identification and determination. Ultraviolet (UV) absorption and room temperature fluorescence detection are both widely used in HPLC, but the specificity of these detectors is modest. Since PAH identification is solely based on retention times, unambiguous PAH identification requires complete chromatographic resolution of sample components. When HPLC is applied to "unfamiliar" samples, the EPA recommends that a supporting analytical technique such as GC-MS be applied to verify compound identification and to check peak-purity HPLC fractions. Independent of the volume of extracted water, the approximate time required to separate and determine the sixteen "priority pollutants" (EPA-PAH) via HPLC is approximately 60min. If additional GC-MS analysis is required for unambiguous PAH determination, the total analysis time will reach 2-3 hours per sample. If the concentrations of target species are found to lie outside the detector's response range, the sample must be diluted and the process repeated. These are important considerations when routine analysis of numerous samples is contemplated. Parent PAH are relatively inert and need metabolic activation to express their carcinogenicity. By virtue of the rich heterogeneous distribution of metabolic products they produce, PAH provide a full spectrum of the complexity associated with understanding the initial phase of carcinogenesis. PAH metabolites include a variety of products such as expoxides, hydroxyl aromatics, quinines, dihydrodiols, dioepoxides, tetrols and water soluble conjugates. During the past decades tremendous efforts have been made to develop bio-analytical techniques that possess the selectivity and sensitivity for the problem at hand. Depending on the complexity of the sample and the relative concentrations of the targeted metabolites, a combination of sample preparation techniques is often necessary to reach the limits of detection of the instrumental method of analysis. The numerous preparation steps open ample opportunity to metabolite loss and collection of inaccurate data. Separation of metabolites has been accomplished via HPLC, capillary electrophoresis (CE) and GC-MS. Unfortunately, the existence of chemically related metabolic products with virtually identical fragmentation patterns often challenges the specificity of these techniques. This dissertation presents significant improvements in various fronts. Its first original component--which we have named solid-phase nano-extraction (SPNE)--deals with the use of gold nanoparticles (Au NPs) as extracting material for PAH. The advantages of SPNE are demonstrated for the analysis of PAH in water samples via both HPLC and Laser-Excited Time-Resolved Shpol'skii Spectroscopy (LETRSS). The same concept is then extended to the analysis of monohydroxy-PAH in urine samples via SPE- HPLC and In-Capillary SPNE-CE. The second original component of this dissertation describes the application of Shpol'skii Spectroscopy to the analysis of polar PAH metabolites. The outstanding selectivity and sensitivity for the direct analysis of PAH at trace concentration levels has made Shpol'skii spectroscopy a leading technique in environmental analysis. Unfortunately, the requirement of a specific guest-host combination--typically a non-polar PAH dissolved in an n-alkane-- has hindered its widespread application to the field of analytical chemistry. This dissertation takes the first steps in removing this limitation demonstrating its feasibility for the analysis of polar benzopyrene metabolites in alcohol matrixes.
Author: Madison Richards Schwaab
Publisher:
ISBN:
Category : Fishes
Languages : en
Pages : 61
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Book Description
Fisheries populations and their ecosystems are negatively impacted by both chronic and acute inputs of pollutants, including oil spills such as the Deepwater Horizon platform blowout in 2010 in the Gulf of Mexico (GoM). After Deepwater Horizon, toxicological studies of demersal fishes of the northern GoM were undertaken to characterize impacts and to establish baseline contaminant levels in the aftermath of the spill. In this study, I quantify polycyclic aromatic hydrocarbon (PAH) concentrations in eight pelagic fish species to demonstrate oil exposure differences between species, region and time. Analysis of biliary PAH metabolite equivalents using high performance liquid chromatography was used to estimate short-term and acute exposure in pelagic fishes (n = 102). Hepatic PAH concentrations of 19 parental PAHs and their alkylated homologs in pelagic liver samples (n = 142) were quantified using QuEChERS extractions and GC/MS/MS to quantify long-term and chronic exposure. The hepatic ∑46PAH (sum of 46 parental and homolog PAH compounds) concentration ranges quantified for all species and regions (21.2 to 468 ng g-1 wet weight) are within the range found previously in the GoM region for demersal and reef fishes. Biliary PAH equivalent ∑3FAC concentrations (fluorescent aromatic compounds of three PAH indicators) ranged from 4,400 to 1,400,000 ng FAC g-1 bile, which were also within the same range as demersal and reef species in this region. However, mean biliary PAH concentrations measured in Yellowfin Tuna (855 μg FAC g-1) from the north central GoM were more than three times higher than Golden Tilefish (263 μg FAC g-1) and 20 times higher than Yellowedge Grouper (Hyporthodus flavolimbatus, 41 μg FAC g-1) collected in the same region. Significant negative relationships between PAH concentrations, biometrics (e.g. fish length), and putative indices of fish health including Fulton’s condition factor and the hepatosomatic index were identified for multiple species. Intraspecies and regional differences were also identified for Greater Amberjack, Seriola dumerili, and Yellowfin Tuna, Thunnus albacares, suggesting variation in PAH sources across region. Produced waters from oil and gas platform discharges among other sources including riverine input, atmospheric deposition, burning of fossil fuels, resuspension of contaminated sediments, and chronically leaking wells are likely contributing to regional differences within species. Furthermore, the high levels of PAH exposure in pelagic species compared to demersal and reef species, indicated by biliary fluorescent aromatic compounds (FACs), warrants further investigation to identify the prominent source of surface water PAHs and the specific physiological species differences that govern the observed high rates of exposure and metabolic clearance for species such as the Yellowfin Tuna.
Author: Muharrem Ince
Publisher: BoD – Books on Demand
ISBN: 1789844207
Category : Technology & Engineering
Languages : en
Pages : 100
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Book Description
This book covers hydrocarbon pollution, measurement techniques for hydrocarbons, risk assessment, and environmental impact. This comprehensive book takes a broad view of the subject and integrates a wide variety of approaches. This book attempts to address the needs of graduate and postgraduate students and other professionals or readers interested in food, soil, water, and air pollution. The aim of this book is to explain and clarify important studies, and compare and develop the new and groundbreaking measurement techniques. Written by leading experts in their respective areas, the book is highly recommended to professionals interested in environmental and human health because it provides specific and comprehensive examples.
Author: Janusz Pawliszyn
Publisher: Elsevier
ISBN: 0123914493
Category : Science
Languages : en
Pages : 497
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The relatively new technique of solid phase microextraction (SPME) is an important tool to prepare samples both in the lab and on-site. SPME is a "green" technology because it eliminates organic solvents from analytical laboratory and can be used in environmental, food and fragrance, and forensic and drug analysis. This handbook offers a thorough background of the theory and practical implementation of SPME. SPME protocols are presented outlining each stage of the method and providing useful tips and potential pitfalls. In addition, devices and fiber coatings, automated SPME systems, SPME method development, and In Vivo applications are discussed. This handbook is essential for its discussion of the latest SPME developments as well as its in depth information on the history, theory, and practical application of the method. - Practical application of Solid Phase Microextraction methods including detailed steps - Provides history of extraction methods to better understand the process - Suitable for all levels, from beginning student to experienced practitioner
Author: Albert Lebedev
Publisher: ILM Publications
ISBN: 1906799121
Category : Science
Languages : en
Pages : 544
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Book Description
"In full colour throughout, this book describes the power of mass spectrometry in resolving environmental issues, demonstrating how real-world complex problems can be solved in a simple and elegant way."--Worldcat.
Author:
Publisher:
ISBN:
Category : Butadiene
Languages : en
Pages : 142
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Author:
Publisher:
ISBN:
Category : Acrolein
Languages : en
Pages : 232
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