Contribution à l'étude de l'électrode de sodium dans les hydroxydes alcalins fondus PDF Download
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Author: Louis Lacourcelle
Publisher:
ISBN:
Category :
Languages : fr
Pages : 192
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Author: Louis Lacourcelle
Publisher:
ISBN:
Category :
Languages : fr
Pages : 192
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Author: Philippe Thomas
Publisher:
ISBN:
Category :
Languages : fr
Pages : 272
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Ce travail se situe dans le cadre général de l'étude de l'insertion électrochimique de métaux alcalins dans des matériaux carbonés susceptibles d'applications comme anodes de générateurs secondaires. Une attention toute particulière est portée sur l'influence de la nature de l'électrolyte et du matériau carboné sur les performances électrochimiques (capacités réversible et irréversible, évolution en cyclage). L'insertion des ions sodium dans des électrolytes à base de solvants carbonates est décrite pour le graphite UF4 et les fibres P75. L'utilisation du carbonate d'éthylène (EC) entraîne la formation d'une couche de passivation sur l'électrode carbonée, imperméable aux molécules de solvant mais permettant la diffusion des ions sodium. Ce film passivant a été caractérisé par microscopie électronique à transmission (imagerie, diffraction électronique et spectrométrie par pertes d'énergie des électrons transmis). Alors que l'emploi du carbonate de propylène (PC) conduit à l'exfoliation des domaines graphités, les électrodes peuvent être cyclées soit en utilisant des mélanges EC-PC ou ChloroEC-PC soit après formation d'un film de passivation dans EC préalablement au cyclage dans PC. L'étude de l'insertion du sodium dans des fibres de carbone issues de précurseurs différents (brai mésophase ou polyacrylonitrile (PAN)) a permis de mettre en évidence deux mécanismes de fixation de l'alcalin. L'intercalation entre les feuillets de graphène est le mécanisme majoritaire pour les fibres ex-brai alors que l'insertion dans la porosité devient significative pour les fibres ex-PAN. Des produits contenant une quantité notable de sodium et cyclant réversiblement peuvent alors être synthétisés. Enfin, une étude préliminaire concerne l'insertion du sodium dans des graphites modifiés par broyage, soit chimiquement par suroxydation électrochimique. Le graphite naturel UF4, dans lequel l'insertion du sodium ne conduit qu'à des produits très pauvres, peut ainsi, après broyage, intercaler des quantités importantes de sodium (NaC11). Les moyens d'optimiser les performances électrochimiques des matériaux anodiques sont alors discutés.
Author: Alain Eluard
Publisher:
ISBN:
Category :
Languages : fr
Pages : 147
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Author: Arthur Amos Noyes
Publisher:
ISBN:
Category : Electrolytes
Languages : en
Pages : 374
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Author: James A. Lane
Publisher:
ISBN:
Category : Fluid fuel reactors
Languages : en
Pages : 1016
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Author: Fatih Şen
Publisher: Elsevier
ISBN: 0128194774
Category : Technology & Engineering
Languages : en
Pages : 286
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Nanomaterials for Hydrogen Storage Applications introduces nanomaterials and nanocomposites manufacturing and design for hydrogen storage applications. The book covers the manufacturing, design, characterization techniques and hydrogen storage applications of a range of nanomaterials. It outlines fundamental characterization techniques for nanocomposites to establish their suitability for hydrogen storage applications. Offering a sound knowledge of hydrogen storage application of nanocomposites, this book is an important resource for both materials scientists and engineers who are seeking to understand how nanomaterials can be used to create more efficient energy storage solutions. - Assesses the characterization, design, manufacture and application of different types of nanomaterials for hydrogen storage - Outlines the major challenges of using nanomaterials in hydrogen storage - Discusses how the use of nanotechnology is helping engineers create more effective hydrogen storage systems
Author: Karl Kordesch
Publisher: Wiley-VCH
ISBN: 9783527285792
Category : Technology & Engineering
Languages : en
Pages : 375
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Book Description
This unique book concerning fuel cells and their applications fills the gap which currently exists between the theoretical aspects and the detailed practical data available. It describes a technology that dates from the early classical discoveries of the 1850s which predicted that direct energy conversion of chemical energy into electricity with fuel cells would be far more efficient at lower temperatures than with combustion processes. The importance of fuel cells for energy saving purposes is emphasised. Their applications are wide-ranging with use found in local stations and power plants, in industry for the highly efficient conversion of waste and biomass materials and in carbon dioxide reduction in all fossil-fuel-burning processes. Unique features highlighted include their importance in spacecrafts and their development for affordable implementation in electric cars. The most recent scientific publications and manufacturer's brochures have been screened in order to bring together the state- of-the-art technology of fuel cells. Readers at all levels including chemists, physicists, chemical engineers ry technologists and students will appreciate this comprehensive overvie ind the clarity of numerous graphs and tables highly valuable.
Author: Nabisab Mujawar Mubarak
Publisher: Springer Nature
ISBN: 9811660220
Category : Technology & Engineering
Languages : en
Pages : 270
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Book Description
This book provides an overview of the electronic applications of nanotechnology. It presents latest research in the areas of nanotechnology applied to the fields of electronics and energy. Various topics covered in this book include nanotechnology in electronic field, electronic chips and circuits, batteries, wireless devices, energy storage, semiconductors, fuel cells, defense and military equipment, and aerospace industry, This book will be useful for engineers, researchers and industry professionals primarily in the fields of electrical engineering engineering, materials science and nanotechnology.
Author: Alejandro A. Franco
Publisher: CRC Press
ISBN: 9814310824
Category : Science
Languages : en
Pages : 618
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Book Description
This book focuses on the recent research progress on the fundamental understanding of the materials degradation phenomena in PEFC, for automotive applications. On a multidisciplinary basis, through contributions of internationally recognized researchers in the field, this book provides a complete critical review on crucial scientific topics related to PEFC materials degradation, and ensures a strong balance between experimental and theoretical analysis and preparation techniques with several practical applications for both the research and the industrial communities.
Author: Joseph Robert Dietrich
Publisher:
ISBN: 9781258727338
Category :
Languages : en
Pages : 860
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Book Description
Contributing Authors Include D. F. Babcock, W. R. Baldwin, D. W. Bareis, And Others.
