Conducting Polymer Electrodes for Thermogalvanic Cells PDF Download
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Author: Kosala Wijeratne
Publisher: Linköping University Electronic Press
ISBN: 9176851567
Category :
Languages : en
Pages : 114
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Book Description
Fossil fuels are still the dominant (ca. 80%) energy source in our society. A significant fraction is used to generate electricity with a heat engine possessing an efficiency of approximately 35%. Therefore, about 65% of fossil fuel energy is wasted in heat. Other primary heat sources include solar and geothermal energies that can heat up solid and fluids up to 150°C. The growing demand and severe environmental impact of energy systems provide an impetus for effective management and harvesting solutions dealing with waste heat. A promising way to use waste heat is to directly convert thermal energy into electrical energy by thermoelectric generators (TEGs). Solid state TEGs are electronic devices that generate electrical power due to the thermo-diffusion of electronic charge carriers in the semiconductor upon application of the thermal field. However, there is another type of thermoelectric device that has been much less investigated; this is the thermogalvanic cell (TGCs). The TGC is an electrochemical device that consists of the electrolyte solution including a reversible redox couple sandwiched between two electrodes. In our study, we focus on iron-based organometallic molecules in aqueous electrolyte. A temperature difference (???) between the electrodes promotes a difference in the electrode potentials [???(??)]. Since the electrolyte contains a redox couple acting like electronic shuttle between the two electrodes, power can be generated when the two electrodes are submitted to a temperature difference. The focus of this thesis is (i) to investigate the possibility to use conducting polymer electrodes for thermogalvanic cells as an alternative to platinum and carbon-based electrodes, (ii) to investigate the role of viscosity of the electrolyte in order to consider polymer electrolytes, (iii) to understand the mechanisms limiting the electrical power output in TGCs; and (iv) to understand the fundamentals of the electron transfer taking place at the interface between the polymer electrode and the redox molecule in the electrolyte. These findings provide an essential toolbox for further improvement in conducting polymer thermogalvanic cells and various other emerging electrochemical technologies such as fuel cells, redox flow battery, dye-sensitized solar cells and industrial electrochemical synthesis.
Author: Kosala Wijeratne
Publisher: Linköping University Electronic Press
ISBN: 9176851567
Category :
Languages : en
Pages : 114
Get Book Here
Book Description
Fossil fuels are still the dominant (ca. 80%) energy source in our society. A significant fraction is used to generate electricity with a heat engine possessing an efficiency of approximately 35%. Therefore, about 65% of fossil fuel energy is wasted in heat. Other primary heat sources include solar and geothermal energies that can heat up solid and fluids up to 150°C. The growing demand and severe environmental impact of energy systems provide an impetus for effective management and harvesting solutions dealing with waste heat. A promising way to use waste heat is to directly convert thermal energy into electrical energy by thermoelectric generators (TEGs). Solid state TEGs are electronic devices that generate electrical power due to the thermo-diffusion of electronic charge carriers in the semiconductor upon application of the thermal field. However, there is another type of thermoelectric device that has been much less investigated; this is the thermogalvanic cell (TGCs). The TGC is an electrochemical device that consists of the electrolyte solution including a reversible redox couple sandwiched between two electrodes. In our study, we focus on iron-based organometallic molecules in aqueous electrolyte. A temperature difference (???) between the electrodes promotes a difference in the electrode potentials [???(??)]. Since the electrolyte contains a redox couple acting like electronic shuttle between the two electrodes, power can be generated when the two electrodes are submitted to a temperature difference. The focus of this thesis is (i) to investigate the possibility to use conducting polymer electrodes for thermogalvanic cells as an alternative to platinum and carbon-based electrodes, (ii) to investigate the role of viscosity of the electrolyte in order to consider polymer electrolytes, (iii) to understand the mechanisms limiting the electrical power output in TGCs; and (iv) to understand the fundamentals of the electron transfer taking place at the interface between the polymer electrode and the redox molecule in the electrolyte. These findings provide an essential toolbox for further improvement in conducting polymer thermogalvanic cells and various other emerging electrochemical technologies such as fuel cells, redox flow battery, dye-sensitized solar cells and industrial electrochemical synthesis.
Author: Shiren Wang
Publisher: Woodhead Publishing
ISBN: 0128236914
Category : Technology & Engineering
Languages : en
Pages : 266
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Book Description
Low-Grade Thermal Energy Harvesting: Advances in Thermoelectrics, Materials, and Emerging Applications provides readers with fundamental and key concepts surrounding low-grade thermal energy conversion while also reviewing the latest research directions. The book covers the most promising and emerging technologies for low-grade heat recovery, harvesting and conversion, including wearable thermoelectrics and organic thermoelectrics. Each chapter includes key materials, principles, design and fabrication strategies for low-grade heat recovery. Special attention on emerging materials such as organic composites, 2D materials and nanomaterials are also included. The book emphasizes materials and device structures that enable the powering of wearable electronics and consumer electronics. The book is suitable for materials scientists and engineers in academia and R&D in manufacturing, industry, energy and electronics. - Introduces key concepts and fundamental principles of low-grade thermal energy harvesting, storage and conversion - Provides an overview on key materials, design principles and fabrication strategies for devices for low energy harvesting applications - Focuses on materials and device designs that enable wearable thermoelectrics and flexible electronics applications
Author: Vidya Nand Singh
Publisher: CRC Press
ISBN: 1003860141
Category : Technology & Engineering
Languages : en
Pages : 283
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Book Description
Nowadays, most of the research focuses on nanomaterials in which one of the dimensions falls in the 1-100 nm range. These nanomaterials can be thin films, quantum dots, nanowires, nanopyramids, and nanoclusters. Thus, nanomaterials are impacting almost all aspects of materials for various applications in emerging energy and sensor devices. The book comprises ten chapters and discusses nanomaterial applications in energy, solar cells, water splitting, sensors, etc. The book caters to budding researchers’ needs in synthesizing nanomaterials and post-graduate students.
Author: Deepalekshmi Ponnamma
Publisher: Springer
ISBN: 331950424X
Category : Technology & Engineering
Languages : en
Pages : 404
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Book Description
This book covers smart polymer nanocomposites with perspectives for application in energy harvesting, as self-healing materials, or shape memory materials. The book is application-oriented and describes different types of polymer nanocomposites, such as elastomeric composites, thermoplastic composites, or conductive polymer composites. It outlines their potential for applications, which would meet some of the most important challenges nowadays: for harvesting energy, as materials with the capacity to self-heal, or as materials memorizing a given shape.The book brings together these different applications for the first time in one single platform. Chapters are ordered both by the type of composites and by the target applications. Readers will thus find a good overview, facilitating a comparison of the different smart materials and their applications. The book will appeal to scientists in the fields of chemistry, material science and engineering, but also to technologists and physicists, from graduate student level to researcher and professional.
Author: Daoben Zhu
Publisher: John Wiley & Sons
ISBN: 3527835504
Category : Technology & Engineering
Languages : en
Pages : 404
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Book Description
Organic Thermoelectrics Enables readers to understand the development and applications of organic thermoelectric conversion, including fundamentals and experimental breakthroughs Organic Thermoelectrics: From Materials to Devices introduces organic thermoelectric materials to devices in a systematic manner, covering the development of organic thermoelectric materials, followed by a discussion on the fundamental mechanism of thermoelectric conversion, design strategy, and advances in different materials, device fabrication, and characterizations of thermoelectric parameters. In Organic Thermoelectrics: From Materials to Devices, readers can expect to find detailed information on: Fundamentals of thermoelectric (TE) conversion, development of organic thermoelectric (OTE) fields and mechanisms, and basic physical processes in carrier transport and thermal transport for TE conversion Recent development and key strategies to develop p-type, n-type, and composite/hybrid OTE materials Basic mechanisms, fundamental requirements, and recent advances of doping for OTE applications, plus geometries and construction methods of OTE devices Theoretical and experimental advances in single molecular TE devices, together with the recent development in related detection methods Powered by worldwide innovative research results in the past ten years and strongly supported by many collaborators, Organic Thermoelectrics is a comprehensive reference on the subject and is invaluable for scientists and students in chemistry, materials, and engineering.
Author: Pradip Kar
Publisher: John Wiley & Sons
ISBN: 1118573803
Category : Technology & Engineering
Languages : en
Pages : 176
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Book Description
An A-to-Z of doping including its definition, its importance, methods of measurement, advantages and disadvantages, properties and characteristics—and role in conjugated polymers The versatility of polymer materials is expanding because of the introduction of electro-active behavior into the characteristics of some of them. The most exciting development in this area is related to the discovery of intrinsically conductive polymers or conjugated polymers, which include such examples as polyacetylene, polyaniline, polypyrrole, and polythiophene as well as their derivatives. "Synmet" or "synthetic metal" conjugated polymers, with their metallic characteristics, including conductivity, are of special interest to researchers. An area of limitless potential and application, conjugated polymers have sparked enormous interest, beginning in 2000 when the Nobel Prize for the discovery and development of electrically conducting conjugated polymers was awarded to three scientists: Alan J. Heeger, Alan G. MacDiarmid, and Hideki Shirakawa. Conjugated polymers have a combination of properties—both metallic (conductivity) and polymeric; doping gives the conjugated polymer's semiconducting a wide range of conductivity, from insulating to low conducting. The doping process is a tested effective method for producing conducting polymers as semiconducting material, providing a substitute for inorganic semiconductors. Doping in Conjugated Polymers is the first book dedicated to the subject and offers a comprehensive A-to-Z overview. It details doping interaction, dopant types, doping techniques, and the influence of the dopant on applications. It explains how the performance of doped conjugated polymers is greatly influenced by the nature of the dopants and their level of distribution within the polymer, and shows how the electrochemical, mechanical, and optical properties of the doped conjugated polymers can be tailored by controlling the size and mobility of the dopants counter ions. The book also examines doping at the nanoscale, in particular, with carbon nanotubes. Readership The book will interest a broad range of researchers including chemists, electrochemists, biochemists, experimental and theoretical physicists, electronic and electrical engineers, polymer and materials scientists. It can also be used in both graduate and upper-level undergraduate courses on conjugated polymers and polymer technology.
Author: Kuniharu Takei
Publisher: John Wiley & Sons
ISBN: 3527804846
Category : Technology & Engineering
Languages : en
Pages : 438
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Book Description
The book introduces flexible and stretchable wearable electronic systems and covers in detail the technologies and materials required for healthcare and medical applications. A team of excellent authors gives an overview of currently available flexible devices and thoroughly describes their physical mechanisms that enable sensing human conditions. In dedicated chapters, crucial components needed to realize flexible and wearable devices are discussed which include transistors and sensors and deal with memory, data handling and display. Additionally, suitable power sources based on photovoltaics, thermoelectric energy and supercapacitors are reviewed. A special chapter treats implantable flexible sensors for neural recording. The book editor concludes with a perspective on this rapidly developing field which is expected to have a great impact on healthcare in the 21st century.
Author: Angel E. Kaifer
Publisher: John Wiley & Sons
ISBN: 3527613617
Category : Science
Languages : de
Pages : 255
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Book Description
This book describes the electrochemical behavior of supramolecular systems. Special emphasis will be given to the electrochemistry of host-guest complexes, monolayer and multilayer assemblies, dendrimers, and other supramolecular assemblies. A fundamental theme throughout the book is to explore the effects that supramolecular structure exerts on the thermodynamics and kinetics of electrochemical reactions. Conversely, attention will be placed to the various ways in which electrochemical or redox conversions can be utilized to control or affect the structure or properties of supramolecular systems. This first book on this topic will be of value for graduate students and advanced researchers in both electrochemistry and supramolecular chemistry.
Author: Margarita Sanchez-Dominguez
Publisher: Elsevier
ISBN: 0128017589
Category : Technology & Engineering
Languages : en
Pages : 538
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Book Description
Nanocolloids: A Meeting Point for Scientists and Technologists presents an easy-to-read approach to current trends in nanoscale colloid chemistry, which offers relatively simple and economically feasible ways to produce nanomaterials. Nanocolloids have been the subjects of major development in modern technology, with many current and future applications. The book helps scientists and technologists to understand the different aspects of modern nanocolloid science. It outlines the underlying fundamental principles of nanocolloid science and covers applications ranging from emulsions to dispersions and suspensions. You will find details on experimental techniques and methods for the synthesis and characterization of nanocolloids, including the latest developments in nanoemulsions and nanoparticles. - Edited by leading academics with over 10 years' experience in the field of colloid and surfactant science - Each chapter is authored by recognized experts in the field - Outlines the underlying fundamental science behind nanocolloids - Provides comprehensive coverage of current topics and potential applications in nanocolloid science - Presents a multidisciplinary approach to help chemical engineers, chemists, physicists, materials scientists and pharmacologists, form an in-depth understanding of nanocolloid science
Author: Andreas Elschner
Publisher: CRC Press
ISBN: 1420069128
Category : Technology & Engineering
Languages : en
Pages : 380
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Book Description
While there is information available in handbooks on polythiophene chemistry and physics, until now, few if any books have focused exclusively on the most forwardly developed electrically conductive polymer, Poly (3,4-ethylenedioxythiophene)-otherwise known as PEDOT. This resource provides full chemical, physical, and technical information about this important conducting polymer, discussing basic knowledge and exploring its technical applications. Presented information is based on information generated at universities and through academic research, as well as by industrial scientists, providing a complete picture of the experimental and the practical aspects of this important polymer.
