Compound-specific Stable Isotope Analysis

Compound-specific Stable Isotope Analysis PDF Author: Maik A Jochmann
Publisher: Royal Society of Chemistry
ISBN: 1782626107
Category : Science
Languages : en
Pages :

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Book Description
The use of Compound-specific Stable Isotope Analysis (CSIA) is increasing in many areas of science and technology for source allocation, authentication, and characterization of transformation reactions. Until now, there have been no textbooks available for students with an analytical chemical background or basic introductory books emphasising the instrumentation and theory. This book is the first to focus solely on stable isotope analysis of individual compounds in sometimes complex mixtures. It acts as both a lecture companion for students and a consultant for advanced scientists in fields including forensic and environmental science. The book starts with a brief history of the field before going on to explain stable isotopes from scratch. The different ways to express isotope abundances are introduced together with isotope effects and isotopic fractionation. A detailed account of the required technical equipment and general procedures for CSIA is provided. This includes sections on derivatization and the use of microextraction techniques in GC-IRMS. The very important topic of referencing and calibration in CSIA is clearly described. This differs from approaches used in quantitative analysis and is often difficult for the newcomer to comprehend. Examples of successful applications of CSIA in food authenticity, forensics, archaeology, doping control, environmental science, and extraterrestrial materials are included. Applications in isotope data treatment and presentation are also discussed and emphasis is placed on the general conclusions that can be drawn from the uses of CSIA. Further instrumental developments in the field are highlighted and selected experiments are introduced that may act as a basis for a short practical course at graduate level.

Compound-specific Stable Isotope Analysis

Compound-specific Stable Isotope Analysis PDF Author: Maik A Jochmann
Publisher: Royal Society of Chemistry
ISBN: 1782626107
Category : Science
Languages : en
Pages :

Get Book

Book Description
The use of Compound-specific Stable Isotope Analysis (CSIA) is increasing in many areas of science and technology for source allocation, authentication, and characterization of transformation reactions. Until now, there have been no textbooks available for students with an analytical chemical background or basic introductory books emphasising the instrumentation and theory. This book is the first to focus solely on stable isotope analysis of individual compounds in sometimes complex mixtures. It acts as both a lecture companion for students and a consultant for advanced scientists in fields including forensic and environmental science. The book starts with a brief history of the field before going on to explain stable isotopes from scratch. The different ways to express isotope abundances are introduced together with isotope effects and isotopic fractionation. A detailed account of the required technical equipment and general procedures for CSIA is provided. This includes sections on derivatization and the use of microextraction techniques in GC-IRMS. The very important topic of referencing and calibration in CSIA is clearly described. This differs from approaches used in quantitative analysis and is often difficult for the newcomer to comprehend. Examples of successful applications of CSIA in food authenticity, forensics, archaeology, doping control, environmental science, and extraterrestrial materials are included. Applications in isotope data treatment and presentation are also discussed and emphasis is placed on the general conclusions that can be drawn from the uses of CSIA. Further instrumental developments in the field are highlighted and selected experiments are introduced that may act as a basis for a short practical course at graduate level.

Encyclopedia of Geochemistry

Encyclopedia of Geochemistry PDF Author: William M. White
Publisher: Springer
ISBN: 9783319393117
Category : Science
Languages : en
Pages : 1680

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Book Description
The Encyclopedia is a complete and authoritative reference work for this rapidly evolving field. Over 200 international scientists, each experts in their specialties, have written over 330 separate topics on different aspects of geochemistry including geochemical thermodynamics and kinetics, isotope and organic geochemistry, meteorites and cosmochemistry, the carbon cycle and climate, trace elements, geochemistry of high and low temperature processes, and ore deposition, to name just a few. The geochemical behavior of the elements is described as is the state of the art in analytical geochemistry. Each topic incorporates cross-referencing to related articles, and also has its own reference list to lead the reader to the essential articles within the published literature. The entries are arranged alphabetically, for easy access, and the subject and citation indices are comprehensive and extensive. Geochemistry applies chemical techniques and approaches to understanding the Earth and how it works. It touches upon almost every aspect of earth science, ranging from applied topics such as the search for energy and mineral resources, environmental pollution, and climate change to more basic questions such as the Earth’s origin and composition, the origin and evolution of life, rock weathering and metamorphism, and the pattern of ocean and mantle circulation. Geochemistry allows us to assign absolute ages to events in Earth’s history, to trace the flow of ocean water both now and in the past, trace sediments into subduction zones and arc volcanoes, and trace petroleum to its source rock and ultimately the environment in which it formed. The earliest of evidence of life is chemical and isotopic traces, not fossils, preserved in rocks. Geochemistry has allowed us to unravel the history of the ice ages and thereby deduce their cause. Geochemistry allows us to determine the swings in Earth’s surface temperatures during the ice ages, determine the temperatures and pressures at which rocks have been metamorphosed, and the rates at which ancient magma chambers cooled and crystallized. The field has grown rapidly more sophisticated, in both analytical techniques that can determine elemental concentrations or isotope ratios with exquisite precision and in computational modeling on scales ranging from atomic to planetary.

Anaerobic Utilization of Hydrocarbons, Oils, and Lipids

Anaerobic Utilization of Hydrocarbons, Oils, and Lipids PDF Author: Matthias Boll
Publisher: Springer
ISBN: 9783319503905
Category : Science
Languages : en
Pages : 0

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Book Description
The book uniquely covers all aspects of anaerobic biodegradation of the environmentally important hydrocarbons. The contributions by international experts cover the molecular characterization of unique biocatalysts for oxygen-independent C-H-bond functionalization, the identification of unifying concepts, and the presentation of state-of-the-art methodologies. The current knowledge of the global importance of anaerobic hydrocarbon degradation is highlighted.

Stable Isotopes in Ecology and Environmental Science

Stable Isotopes in Ecology and Environmental Science PDF Author: Robert Michener
Publisher: John Wiley & Sons
ISBN: 0470691174
Category : Science
Languages : en
Pages : 592

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Book Description
This book highlights new and emerging uses of stable isotope analysis in a variety of ecological disciplines. While the use of natural abundance isotopes in ecological research is now relatively standard, new techniques and ways of interpreting patterns are developing rapidly. The second edition of this book provides a thorough, up-to-date examination of these methods of research. As part of the Ecological Methods and Concepts series which provides the latest information on experimental techniques in ecology, this book looks at a wide range of techniques that use natural abundance isotopes to: follow whole ecosystem element cycling understand processes of soil organic matter formation follow the movement of water in whole watersheds understand the effects of pollution in both terrestrial and aquatic environments study extreme systems such as hydrothermal vents follow migrating organisms In each case, the book explains the background to the methodology, looks at the underlying principles and assumptions, and outlines the potential limitations and pitfalls. Stable Isotopes in Ecology and Environmental Science is an ideal resource for both ecologists who are new to isotopic analysis, and more experienced isotope ecologists interested in innovative techniques and pioneering new uses.

Tracking Animal Migration with Stable Isotopes

Tracking Animal Migration with Stable Isotopes PDF Author: Keith A. Hobson
Publisher: Academic Press
ISBN: 0128147245
Category : Nature
Languages : en
Pages : 268

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Book Description
Tracking Animal Migration with Stable Isotopes, Second Edition, provides a complete introduction to new and powerful isotopic tools and applications that track animal migration, reviewing where isotope tracers fit in the modern toolbox of tracking methods. The book provides background information on a broad range of migration scenarios in terrestrial and aquatic systems and summarizes the most cutting-edge developments in the field that are revolutionizing the way migrant individuals and populations are assigned to their true origins. It allows undergraduates, graduate students and non-specialist scientists to adopt and apply isotopes to migration research, and also serves as a useful reference for scientists. The new edition thoroughly updates the information available to the reader on current applications of this technique and provides new tools for the isotopic assignment of individuals to origins, including geostatistical multi-isotope approaches and the ways in which researchers can combine isotopes with routine data in a Bayesian framework to provide best estimates of animal origins. Four new chapters include contributions on applications to the movements of terrestrial mammals, with particular emphasis on how aspects of animal physiology can influence stable isotope values. Includes an animal physiology component that is an in-depth overview of the cautions and caveats related to this technique Covers marine and aquatic isoscapes and methods to track marine organisms for researchers trying to apply isotopic tracking to animals in these environments Features state-of-the-art statistical treatments for assignment and combining diverse datasets

Earth, Life, and Isotopes

Earth, Life, and Isotopes PDF Author: Ohkouchi Naohiko
Publisher: Trans Pacific Press
ISBN: 9784876989607
Category : Literary Collections
Languages : en
Pages : 0

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Book Description
Section 3. Method development: 21. Ultra-sensitive elemental analyzer/isotope ratio mass spectrometer for stable nitrogen and carbon isotope analyses / Ogawa, N.O. ... [et al.] -- 22. An improved method for precise determination of carbon isotopic composition of amino acids / Chikaraishi, Y. and Ohkouchi, N. -- 23. Instrumental optimization of compound-specific nitrogen isotope analysis of amino acids by gas chromatography/combustion/isotope ratio mass spectrometry / Chikaraishi, Y. ... [et al.] -- 24. Enantiomer-specific isotope analysis of D-and L-alanine / Takano, Y., Chikaraishi, Y. and Ohkouchi, N. -- Appendix. Summary of methods for measuring isotopic compositions presented in this book / Ohkouchi, N., Tayasu, I., and Koba, K.

Handbook of Stable Isotope Analytical Techniques

Handbook of Stable Isotope Analytical Techniques PDF Author: Pier A. de Groot
Publisher: Elsevier
ISBN: 9780080533278
Category : Science
Languages : en
Pages : 1258

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Book Description
(Parent with price) Volume I contains subjective reviews, specialized and novel technique descriptions by guest authors. Part 1 includes contributions on purely analytical techniques and Part 2 includes matters such as development of mass spectrometers, stability of ion sources, standards and calibration, correction procedures and experimental methods to obtain isotopic fractionation factors. Volume II will be available in 2005.

Stable Isotopes as Indicators of Ecological Change

Stable Isotopes as Indicators of Ecological Change PDF Author:
Publisher: Academic Press
ISBN: 0080551009
Category : Science
Languages : en
Pages : 436

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Book Description
The 20th century has experienced environmental changes that appear to be unprecedented in their rate and magnitude during the Earth’s history. For the first time, Stable Isotopes as Indicators of Ecological Change brings together a wide range of perspectives and data that speak directly to the issues of ecological change using stable isotope tracers. The information presented originates from a range of biological and geochemical sources and from research fields within biological, climatological and physical disciplines covering time-scales from days to centuries. Unlike any other reference, editors discuss where isotope data can detect, record, trace and help to interpret environmental change. Provides researchers with groundbreaking data on how to predict the terrestrial ecosystems response to the ongoing rapid alterations Reveals how ecosystems have responded to environmental and biotic fluctuations in the past Includes examples from research by a wide range of biological and physical scientists who are using isotopic records to both detect and interpret environmental change

Stable Isotope Ecology

Stable Isotope Ecology PDF Author: Brian Fry
Publisher: Springer Science & Business Media
ISBN: 0387337458
Category : Science
Languages : en
Pages : 308

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Book Description
A solid introduction to stable isotopes that can also be used as an instructive review for more experienced researchers and professionals. The book approaches the use of isotopes from the perspective of ecological and biological research, but its concepts can be applied within other disciplines. A novel, step-by-step spreadsheet modeling approach is also presented for circulating tracers in any ecological system, including any favorite system an ecologist might dream up while sitting at a computer. The author’s humorous and lighthearted style painlessly imparts the principles of isotope ecology. The online material contains color illustrations, spreadsheet models, technical appendices, and problems and answers.

Encyclopedia of Paleoclimatology and Ancient Environments

Encyclopedia of Paleoclimatology and Ancient Environments PDF Author: Vivien Gornitz
Publisher: Springer Science & Business Media
ISBN: 1402045514
Category : Science
Languages : en
Pages : 1062

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Book Description
One of Springer’s Major Reference Works, this book gives the reader a truly global perspective. It is the first major reference work in its field. Paleoclimate topics covered in the encyclopedia give the reader the capability to place the observations of recent global warming in the context of longer-term natural climate fluctuations. Significant elements of the encyclopedia include recent developments in paleoclimate modeling, paleo-ocean circulation, as well as the influence of geological processes and biological feedbacks on global climate change. The encyclopedia gives the reader an entry point into the literature on these and many other groundbreaking topics.