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Author: Richard Heck
Publisher: Elsevier
ISBN: 0323154700
Category : Science
Languages : en
Pages : 351
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Book Description
Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal d- and p-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.
Author: A. McKillop
Publisher: Elsevier
ISBN: 9780080423180
Category : Science
Languages : en
Pages : 698
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Book Description
The individual chapters in this volume cover the scope and impact of main group organometallic compounds and reagents on organic synthesis during the last ten to fifteen years. In a number of chapters, topics are dealt with in detail that either were not covered at all in COMC (eg selenium, tellurium) or were given scant attention (eg oxymercuration, organoantimony compounds). Certain topics, like directed metallation and LiKOR bases have only achieved prominence in synthesis in the last ten years, and are now reviewed by leading experts.
Author: Richard Heck
Publisher: Elsevier
ISBN: 0323154700
Category : Science
Languages : en
Pages : 351
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Book Description
Organotransition Metal Chemistry: A Mechanistic Approach describes a mechanistic approach to the study of the chemistry of organotransition metals. Organotransition metals are discussed in relation to their reactions with specific functional groups or types of compounds rather than by metals. Topics covered include the formation of hydrogen and carbon bonds to transition metals; reactions of transition metal d- and p-bonded derivatives; and addition and elimination reactions of olefinic compounds. This book is comprised of 10 chapters and begins with a historical overview of organotransition metal chemistry, together with the unique chemistry of transition metals and mechanisms of ligand replacements. The following chapters discuss the methods of preparation of hydrido complexes and carbon-transition metal bonds; homogeneous hydrogenation reactions; isomerization, dimerization, oligomerization, and polymerization of olefins; and reactions of dienes, trienes, and tetraenes with transition metal compounds. Transition metal reactions with acetylenes and carbon monoxide as well as organic carbonyl compounds are also examined. This monograph should be of value to organic chemists as well as students and researchers of organic chemistry.
Author:
Publisher: Academic Press
ISBN: 0080580025
Category : Science
Languages : en
Pages : 347
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Book Description
Advances in Organometallic Chemistry
Author: Ionel Haiduc
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110695278
Category : Science
Languages : en
Pages : 443
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Book Description
This book provides the reader with a comprehensive introduction to the topic of organometallic chemistry. With an easy to follow structure covering both non-transition metals and transition metals as well as the applications of organometallic reagents in organic synthesis, this book is a must-have for the organometallic chemist. Thematic overview of organometallic compounds of transition and non-transition metals. Covers structures as well as applications.
Author: Robert C. West
Publisher: Elsevier
ISBN: 0080560911
Category : Science
Languages : en
Pages : 359
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Book Description
Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.Volume 56 comprises Part 1 of a themed collection of papers on "The Organotransition Metal Chemistry of Poly(pyrazolyl)borates". Provides an authoritative, definitive review addressing all aspects of organometallic chemistry Useful to researchers within this active field and is a must for every modern library of chemistry High-quality research book within this rapidly developing field
Author: E W Abel
Publisher: Royal Society of Chemistry
ISBN: 1847554113
Category : Science
Languages : en
Pages : 526
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Book Description
Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.
Author: Alexandr D. Garnovskii
Publisher: CRC Press
ISBN: 0824748417
Category : Science
Languages : en
Pages : 559
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Book Description
This reference offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system.
Author:
Publisher: Academic Press
ISBN: 0080580440
Category : Science
Languages : en
Pages : 439
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Book Description
This book is an essential reference work for the academic and industrial chemists and will provide up-to-date material at the cutting edge of chemistry research.This widely-acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry.In basic research, organometallics have contributed inter alia to: - Metal cluster chemistry - Surface chemistry - The stabilization of highly reactive species by metal coordination - Chiral synthesis - The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Author: Manfred Schlosser
Publisher: John Wiley & Sons
ISBN: 047012217X
Category : Science
Languages : en
Pages : 1028
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Book Description
WINNER of the 2013 PROSE Award in Chemistry & Physics This latest edition enables readers to master new classes of organometallic compounds and syntheses A popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so that readers can easily replicate the results in their own labs. Moreover, each chapter has been written by a world leader in the field of organometallics in organic synthesis. These authors offer hands-on guidance and practical examples illustrating the preparation of organometallics and its application in organic synthesis. This Third Manual of Organometallics in Synthesis features completely new content and topics, with an eye towards providing researchers with the most useful and practical reference on the synthesis of organometallics. Organized into chapters by type of organometallic compound, the book covers: Organoalkali chemistry Organomagnesium and organozinc chemistry Organosilicon and relating organotin chemistry Organoiron chemistry Organopalladium chemistry Within each chapter, readers will find background information to learn more about the class of organometallics as well as mechanistic considerations. The authors thoroughly discuss the various methods of preparing the organometallic compounds presented in the book and outline their uses in synthetic reactions. In addition to current applications, the authors explore future research opportunities for each organometallic class. References at the end of each chapter enable readers to explore all the topics in greater depth. More and more industrial processes rely on organometallic chemistry. As a result, readers will find this book's step-by-step instructions essential in such fields as natural product synthesis, pharmaceuticals, fine chemicals, biotechnology, polymers, and materials science.
Author: E.P. Kündig
Publisher: Springer Science & Business Media
ISBN: 9783540016045
Category : Science
Languages : en
Pages : 248
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Book Description
Metal-arene p-complexes show a rich and varied chemistry. The metal adds a third dimension to the planar aromatic compounds and coordination of a metal to an arene thus not only altering the reactivity of ring-carbons and substituents but also makes possible reactions that lead to chiral non-racemic products. This book, organized in nine chapters and written by leading scientists in the field provides the reader with an up-to-date treatise on the subject organized according to reaction type and use. It covers the wide spectrum of arene activation: from the electrophilic activation of h6-bound areneï by p-Lewis acid metal complex fragments, to reactions of nucleophilic h2-coordinated arene complexes. The preparation of complexes is detailed, as are the scope, limitations and challenges of reactions in contemporary p-arene metal chemistry with special attention given to asymmetric transformations. The emphasis of the book is on transformations of interest to organic synthesis and on the use of the complexes as catalysts or as chiral ligands. The book is written for academic and industrial researchers in organic, organometallic, and inorganic chemistry as well as for advanced chemistry students
