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Author: Susan Mary Kauzlarich
Publisher: VCH Publishers
ISBN:
Category : Science
Languages : en
Pages : 344
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Book Description
Seven chapters report current research into the phases and ions of a class of compounds that are electronically positioned between the intermetallic compounds and insulating valence compounds. They cover structure and bonding at the Zintl border, structural patterns of homo- and hetero-nuclear anions and related intermetallic compounds and concepts for interpreting them, the early p-block elements, polyanions in liquid ionic alloys, molecular transition metal complexes, transition metal compounds, and synthesizing and characterizing intermetallic materials using Zintl phases as precursors. An introduction surveys the life and work of German chemist Eduard Zintl (1898-1941). Annotation copyright by Book News, Inc., Portland, OR
Author: Susan Mary Kauzlarich
Publisher: VCH Publishers
ISBN:
Category : Science
Languages : en
Pages : 344
Get Book Here
Book Description
Seven chapters report current research into the phases and ions of a class of compounds that are electronically positioned between the intermetallic compounds and insulating valence compounds. They cover structure and bonding at the Zintl border, structural patterns of homo- and hetero-nuclear anions and related intermetallic compounds and concepts for interpreting them, the early p-block elements, polyanions in liquid ionic alloys, molecular transition metal complexes, transition metal compounds, and synthesizing and characterizing intermetallic materials using Zintl phases as precursors. An introduction surveys the life and work of German chemist Eduard Zintl (1898-1941). Annotation copyright by Book News, Inc., Portland, OR
Author:
Publisher: Newnes
ISBN: 0080965296
Category : Science
Languages : en
Pages : 7694
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Book Description
Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973
Author: Emeritus Professor and Wei Lun Research Professor Thomas Cw Mak
Publisher: Oxford University Press
ISBN: 019887295X
Category : Chemistry, Inorganic
Languages : en
Pages : 593
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Book Description
This book is an expanded and updated version of Part III of the authors' previous work, Advanced Structural Inorganic Chemistry (OUP 2008). The original part deals with main-group elements, the rare-earth elements, transition-metal clusters, and supramolecular systems. In this new book, selected material from significant advances in the past decade has been added, with particular emphasis on compounds that exemplify new types of bonds such as sigma-hole, triel bond, tetrel bond, pnictogen bond, chalcogen bond, halogen bond, halogen-halogen interaction, aerogen bond, as well as quintuple and sextuple metal-metal bonds. Other new topics include actinide compounds, metallophilicity, heterometallic macrocycles and cages, com- and dis-proportionation reactions, hydrogen-bonded organic frameworks (HOFs), halogen-bonded organic frameworks, halogen-halogen interactions in supramolecular frameworks, covalent organic frameworks (COFs), and metal-organic frameworks (MOFs).
Author: Ulrich Müller
Publisher: John Wiley & Sons
ISBN: 0470057262
Category : Science
Languages : en
Pages : 280
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Book Description
The essential introduction to the understanding of the structure of inorganic solids and materials. This revised and updated 2nd Edition looks at new developments and research results within Structural Inorganic Chemistry in a number of ways, special attention is paid to crystalline solids, elucidation and description of the spatial order of atoms within a chemical compound. Structural principles of inorganic molecules and solids are described through traditional concepts, modern bond-theoretical theories, as well as taking symmetry as a leading principle.
Author: Gerd Meyer
Publisher: John Wiley & Sons
ISBN: 3527609091
Category : Science
Languages : en
Pages : 375
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Book Description
Metal clusters are on the brink between molecules and nanoparticles in size. With molecular, nano-scale, metallic as well as non-metallic aspects, metal clusters are a growing, interdisciplinary field with numerous potential applications in chemistry, catalysis, materials and nanotechnology. This third volume in the series of hot topics from inorganic chemistry covers all recent developments in the field of metal clusters, with some 20 contributions providing an in-depth view. The result is a unique perspective, illustrating all facets of this interdisciplinary area: * Inter-electron Repulsion and Irregularities in the Chemistry of Transition Series * Stereochemical Activity of Lone Pairs in Heavier Main Group Element Compounds * How Close to Close Packing? * Forty-Five Years of Praseodymium Diiodide * Centered Zirconium Clusters * Titanium Niobium Oxychlorides * Trinuclear Molybdenum and Tungsten Cluster Chalcogenides * Current State of (B,C,N)-Compounds of Calcium and Lanthanum * Ternary Phases of Lithium with Main-Group and Late-Transition Metals * Polar Intermetallics and Zintl Phases along the Zintl Border * Rare Earth Zintl Phases * Structure-Property Relationships in Intermetallics * Ternary and Quaternary Niobium Arsenide Zintl Phases * The Building Block Approach to Understanding Main-Group-Metal Complex Structures * Cation-Deficient Quaternary Thiospinels * A New Class of Hybrid Materials via Salt Inclusion Synthesis * Layered Perrhenate and Vanadate Hybrid Solids * Hydrogen Bonding in Metal Halides * Syntheses and Catalytic Properties of Titanium Nitride Nanoparticles * Solventless Thermolysis * New Potential Scintillation Materials in Borophosphate Systems. With its didactical emphasis, this volume addresses a wide readership, such that both students and specialists will profit from the expert contributions.
Author: Rainer Pöttgen
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110637006
Category : Science
Languages : en
Pages : 478
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Book Description
The expanded edition focuses still more on Synthesis discussing necessary requirements for sample preparation and presents the broad range from structural analysis to property investigations. Additional examples of chemical and physical properties are highlighted for metallic, binary and multinary intermetallic compounds. The work contains an up-dated literature overview in all sub-chapters and a detailed formulae index.
Author: Richard Dronskowski
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3111167216
Category : Science
Languages : en
Pages : 186
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Book Description
Modern DFT simulations of solids and molecules are typically based on the mighty plane-wave pseudopotential combination. Despite being numerically efficient, it does not allow for chemical conclusions unless the electronic structure is unitarily transformed into atomic orbitals. This primer for chemists and as well for physicists and engineers shows how to simply extract the chemistry and, hence, truly understand a plethora of real-world materials The goal of this humorous primer entertaining to read is to truly serve but not repel the reader. Recent in-person and also virtual summer schools in Europe and Asia have demonstrated the need for such a primer, also to be used for self-training
Author: Riccardo Ferro
Publisher: Elsevier
ISBN: 0080553354
Category : Technology & Engineering
Languages : en
Pages : 813
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Book Description
Intermetallic science is closely related to physics, chemistry, metallurgy, materials science & technology, and engineering. This book emphasizes the chemical aspects of this science, and therefore the mutual reactivity of metals and the characteristics of intermetallic compounds. Topics included are:• Phase diagrams of alloy systems. Many intermetallic systems form several compounds, generally not obeying common simple stoichiometric rules, which are often homogeneous in a certain range of compositions. The stability and extension of these phases are conveniently presented through phase diagrams.• Selected aspects of intermetallics structural chemistry, with emphasis on the solid state. The general structural characteristics of intermetallic phases are considered, with attention to nomenclature and to alternative and complementary methods of presenting crystal-chemical data. A brief account is given of derivative and degenerate structures, modular aspects of crystal structures, and of a few special groups of alloys such as quasicrystals and amorphous alloys. A number of selected structural prototypes with typical features, their possible grouping in structural "families and their distribution among different types of alloys are provided.• Intermetallic reactivity trends in the Periodic Table. Attention is given to a few selected elemental parameters such as electron configuration and valence electron number and to their changes along the Table, which act as reference factors of the intermetallic behaviour. As an example, the relationships are considered between crystal structure and the number of valence electrons per atom (or per formula) in various classes of compounds or solid solution phases.• Alloying behaviour systematics of intermetallic systems with a description of the intermetallic reactivity of each element, or group of elements, in the order of their position in the Periodic Table. For each pair of metallic elements, their capability to form intermediate phases is summarised by maps and schemes. • A description of small scale preparation methods of intermetallics. A number of interesting and significant peculiarities are, e.g., those related to their high melting points, insolubility in common solvents, etc.· Systematic treatment of alloying behaviour· Wide overview of intermetallic chemistry· Illustrated, with many examples
Author: Wai-Kee Li
Publisher: Oxford University Press
ISBN: 0199216940
Category : Science
Languages : en
Pages : 842
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Book Description
A revised and updated English edition of a textbook based on teaching at the final year undergraduate and graduate level. It presents structure and bonding, generalizations of structural trends, crystallographic data, as well as highlights from the recent literature.
Author: Richard Dronskowski
Publisher: John Wiley & Sons
ISBN: 3527325875
Category : Technology & Engineering
Languages : en
Pages : 3912
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Book Description
This most comprehensive and unrivaled compendium in the field provides an up-to-date account of the chemistry of solids, nanoparticles and hybrid materials. Following a valuable introductory chapter reviewing important synthesis techniques, the handbook presents a series of contributions by about 150 international leading experts -- the "Who's Who" of solid state science. Clearly structured, in six volumes it collates the knowledge available on solid state chemistry, starting from the synthesis, and modern methods of structure determination. Understanding and measuring the physical properties of bulk solids and the theoretical basis of modern computational treatments of solids are given ample space, as are such modern trends as nanoparticles, surface properties and heterogeneous catalysis. Emphasis is placed throughout not only on the design and structure of solids but also on practical applications of these novel materials in real chemical situations.
