Chemical-looping Combustion with Solid Fuels

Chemical-looping Combustion with Solid Fuels PDF Author: T. A. Brown
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Modeling Aspects of Chemical-looping Combustion for Solid Fuels

Modeling Aspects of Chemical-looping Combustion for Solid Fuels PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 42

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Fluidization Engineering

Fluidization Engineering PDF Author: D. Kunii
Publisher: Elsevier
ISBN: 008050664X
Category : Science
Languages : en
Pages : 520

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Book Description
Fluidization Engineering, Second Edition, expands on its original scope to encompass these new areas and introduces reactor models specifically for these contacting regimes. Completely revised and updated, it is essentially a new book. Its aim is to distill from the thousands of studies those particular developments that are pertinent for the engineer concerned with predictive methods, for the designer, and for the user and potential user of fluidized beds. - Covers the recent advances in the field of fluidization. - Presents the studies of developments necessary to the engineers, designers, and users of fluidized beds.

Chemical Looping Systems for Fossil Energy Conversions

Chemical Looping Systems for Fossil Energy Conversions PDF Author: Liang-Shih Fan
Publisher: John Wiley & Sons
ISBN: 1118063139
Category : Technology & Engineering
Languages : en
Pages : 353

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This book presents the current carbonaceous fuel conversion technologies based on chemical looping concepts in the context of traditional or conventional technologies. The key features of the chemical looping processes, their ability to generate a sequestration-ready CO2 stream, are thoroughly discussed. Chapter 2 is devoted entirely to the performance of particles in chemical looping technology and covers the subjects of solid particle design, synthesis, properties, and reactive characteristics. The looping processes can be applied for combustion and/or gasification of carbon-based material such as coal, natural gas, petroleum coke, and biomass directly or indirectly for steam, syngas, hydrogen, chemicals, electricity, and liquid fuels production. Details of the energy conversion efficiency and the economics of these looping processes for combustion and gasification applications in contrast to those of the conventional processes are given in Chapters 3, 4, and 5.Finally, Chapter 6 presents additional chemical looping applications that are potentially beneficial, including those for H2 storage and onboard H2 production, CO2 capture in combustion flue gas, power generation using fuel cell, steam-methane reforming, tar sand digestion, and chemicals and liquid fuel production. A CD is appended to this book that contains the chemical looping simulation files and the simulation results based on the ASPEN Plus software for such reactors as gasifier, reducer, oxidizer and combustor, and for such processes as conventional gasification processes, Syngas Chemical Looping Process, Calcium Looping Process, and Carbonation-Calcination Reaction (CCR) Process. Note: CD-ROM/DVD and other supplementary materials are not included as part of eBook file.

Finial Scientific

Finial Scientific PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

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Chemical Looping Combustion is a novel combustion technology for the inherent separation of the greenhouse gas, CO2. In 1983, Richter and Knoche proposed reversible combustion, which utilized both the oxidation and reduction of metal. Metal associated with its oxidized form as an oxygen carrier was circulated between two reactors--oxidizer and reducer. In the reducer, the solid oxygen carrier reacts with the fuel to produce CO2, H2O and elemental metal only. Pure CO2 will be obtained in the exit gas stream from the reducer after H2O is condensed. The pure CO2 is ready for subsequent sequestration. In the oxidizer, the elemental metal reacts with air to form metal oxide and separate oxygen from nitrogen. Only nitrogen and some unused oxygen are emitted from the oxidizer. The advantage of CLC compared to normal combustion is that CO2 is not diluted with nitrogen but obtained in a relatively pure form without any energy needed for separation. In addition to the energy-free purification of CO2, the CLC process also provides two other benefits. First, NO(subscript x) formation can be largely eliminated. Secondly, the thermal efficiency of a CLC system is very high. Presently, the CLC process has only been used with natural gas. An oxygen carrier based on an energy balance analysis and thermodynamics analysis was selected. Copper (Cu) seems to be the best choice for the CLC system for solid fuels. From this project, the mechanisms of CuO reduction by solid fuels may be as follows: (1) If pyrolysis products of solid fuels are available, reduction of CuO could start at about 400 C or less. (2) If pyrolysis products of solid fuels are unavailable and the reduction temperature is lower, reduction of CuO could occur at an onset temperature of about 500 C, char gasification reactivity in CO2 was lower at lower temperatures. (3) If pyrolysis products of solid fuels are unavailable and the reduction temperature is higher than 750 C, all reaction reactivities were improved, especially the CO2 gasification reactivity of char. Thus, the reduction of CuO by the gasification product CO could proceed quickly. Based on the results obtained, the following coal characteristics would be desirable for the Chemical Looping Combustion process: high volatile matter with a high reactivity of the char produced. PRB coal meets these criteria while being comparatively less expensive and also very abundant. The high moisture content present in PRB coal might also increase the reactivity for char gasification through the development of pore structure and specific surface area in the char during pyrolysis. Biomass materials are also suitable, considering the reaction mechanism of CLC system of solid fuels. The feasibility of the chemical looping combustion process of solid fuels was verified by focusing on PRB coal and biomass. Based on PRB coal as the preferred solid fuel in the development of the CLC system, the mass, energy and system in a dual reactor recirculation system has been determined. In the Cu oxidation tests, it was confirmed that the heating rate is the most important effect on the Cu oxidation process. Lower heating rates and lower operational temperatures would result in incomplete conversion of Cu to CuO. Cu2O may be the intermediate product. The operating temperature did not affect the reaction rate of the oxidation process. Under any operating conditions, the exothermic properties are clearly shown.

Handbook of Chemical Looping Technology

Handbook of Chemical Looping Technology PDF Author: Ronald W. Breault
Publisher: John Wiley & Sons
ISBN: 3527342028
Category : Business & Economics
Languages : en
Pages : 488

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Book Description
This comprehensive and up-to-date handbook on this highly topical field, covering everything from new process concepts to commercial applications. Describing novel developments as well as established methods, the authors start with the evaluation of different oxygen carriers and subsequently illuminate various technological concepts for the energy conversion process. They then go on to discuss the potential for commercial applications in gaseous, coal, and fuel combustion processes in industry. The result is an invaluable source for every scientist in the field, from inorganic chemists in academia to chemical engineers in industry.

Chemical-looping Combustion with Solid Fuels

Chemical-looping Combustion with Solid Fuels PDF Author: Henrik Leion
Publisher:
ISBN:
Category :
Languages : en
Pages : 42

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Experimental Investigation of Chemical-looping Combustion Utilizing Gaseous and Solid Fuels

Experimental Investigation of Chemical-looping Combustion Utilizing Gaseous and Solid Fuels PDF Author: Georg Ludwig Schwebel
Publisher:
ISBN: 9783844021806
Category :
Languages : en
Pages : 217

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Gas-Solid Reactions

Gas-Solid Reactions PDF Author: Julian Szekely
Publisher: Elsevier
ISBN: 0323151396
Category : Science
Languages : en
Pages : 415

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Book Description
Gas-Solid Reactions describes gas-solid reaction systems, focusing on the four phenomena—external mass transfer, pore diffusion, adsorption/desorption, and chemical reaction. This book consists of eight chapters. After the introduction provided in Chapter 1, the basic components of gas-solid reactions are reviewed in Chapter 2. Chapter 3 describes the reactions of individual nonporous solid particles, while Chapter 4 elaborates the reaction of single porous particles. Solid-solid reactions proceeding through gaseous intermediates are considered in Chapter 5. Chapter 6 deals with the experimental approaches to the study of gas-solid reaction systems. How information on single-particle behavior may be used for the design of multiparticle, large-scale assemblies, and packed- and fluidized-bed reaction systems is deliberated in Chapter 7. The last chapter covers the specific gas-solid reaction systems, including some statistical indices indicating the economic importance of the systems and processes it's based on. This publication is recommended for practicing engineers engaged in process research, development, and design in the many fields where gas-solid reactions are important.

Chemical Looping Combustion of Solid Fuels Using Manganese-based Oxygen Carriers

Chemical Looping Combustion of Solid Fuels Using Manganese-based Oxygen Carriers PDF Author: Matthias Schmitz
Publisher:
ISBN: 9789175976952
Category :
Languages : en
Pages :

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