Characterization of Baria-alumina-silica Glasses and YBa2Cu3O7-x Superconducting Films Prepared by the Sol-gel Process PDF Download
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Author: P. Strehlow
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Languages : en
Pages :
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Author: P. Strehlow
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Languages : en
Pages :
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Author: Ian Strawbridge
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Languages : en
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Author: Douglas Michael Korwin
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Category :
Languages : en
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Author: Danielle Marie Tahan
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Category :
Languages : en
Pages : 352
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Author: Aihu Chen
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Category :
Languages : en
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Author: Renata Reisfeld
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ISBN: 9783662149768
Category :
Languages : en
Pages : 276
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Author: Sa Sa Wang
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Category :
Languages : en
Pages : 93
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Author: Brandon T. Stone
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Category :
Languages : en
Pages : 432
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Author: Masayuki Nogami
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Category :
Languages : en
Pages : 6
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The sol-gel process has been applied successfully to the preparation of small-particle-size ZnS, CdS or PbS-doped silica glasses with a significant quantum size effect. Gels prepared through the hydrolysis of complex solutions Of Si(OC2H5)4 and acetate of Zn, Cd or Pb were heated at 500 to 900oC, then reacted with H2S gas to form fine microcrystals doped glasses. From X-ray diffraction analyses and transmission electron micrographs, these crystals were cubic ZnS, hexagonal CdS and cubic PbS crystal, respectively, and their sizes were 2 to 8 nm in diameter. In the optical absorption spectra, the absorption edge exhibited a blue shift compared with those of the bulk sulfides crystals. Size dependence of energy shift was discussed in relation to size quantization of electron-hole in microcrystals. The nonlinearity was estimated to be 1. 5 x 1010 esu for 2% CdS doped glass.
Author: British Standards Institution
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Category :
Languages : en
Pages : 20
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