Author: Larry Dale Zeagler
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 372
Book Description
Catalytic Dehydration of T-butyl Alcohol on Alumina Using a Continuous Stirred Tank Catalytic Reactor
Author: Larry Dale Zeagler
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 372
Book Description
Publisher:
ISBN:
Category : Catalysis
Languages : en
Pages : 372
Book Description
Vapor Phase Catalytic Dehydration of T-butyl Alcohol on Dowex 50w-x8 Using a Continuous Stirred Tank Catalytic Reactor
Author: Edward Charles Hauswald
Publisher:
ISBN:
Category : Butanol
Languages : en
Pages : 194
Book Description
Publisher:
ISBN:
Category : Butanol
Languages : en
Pages : 194
Book Description
Kinetic Studies in a Recycle Reactor II-catalytic Dehydration of T-butyl Alcohol
Author: John Henry Becher
Publisher:
ISBN:
Category : Butanol
Languages : en
Pages : 192
Book Description
Publisher:
ISBN:
Category : Butanol
Languages : en
Pages : 192
Book Description
Catalytic Dehydration of Tertiary Butyl Alcohol in a Fluidized Bed Reactor
Author: Robert Lee Mills
Publisher:
ISBN:
Category : Butanol
Languages : en
Pages : 348
Book Description
Publisher:
ISBN:
Category : Butanol
Languages : en
Pages : 348
Book Description
Catalytic Dehydration of Tertiary Butyl Alcohol in a Fluidized Bed Reactor
Author: Seong Ho Rhee
Publisher:
ISBN:
Category : Fluidized reactors
Languages : en
Pages : 248
Book Description
Publisher:
ISBN:
Category : Fluidized reactors
Languages : en
Pages : 248
Book Description
Catalytic Dehydration of Ethyl Alcohol on Alumina
Author: Herman J. Solomon
Publisher:
ISBN:
Category :
Languages : en
Pages : 264
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 264
Book Description
Ethanol Dehydration Over Alumina Catalysts with Phosphorus and Noble Metal Modification
Author: Mutjalin Limlamthong
Publisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 332
Book Description
The mixture of 1:1 volume ratio of gamma and chi crystalline phase alumina support was prepared via the solvothermal technique using the mixed solution between toluene and 1-butanol. The support was brought to modify with phosphoric acid and noble metal agents. These catalysts were investigated on the effect of both phosphorus loading and types of noble metal on catalytic characteristic and catalytic activity. The catalytic performance was identified through ethanol dehydration reaction in gas phase process at 1 atm and temperature of 200oC to 400oC. The results were found that the phosphorus modification had an effect on catalytic acidity by decreasing the amount of medium to strong acid sites and raised quantity of weak acid sites. The higher amount of weak acid brought the catalysts to demonstrate the higher catalytic activity through the ethanol dehydration to diethyl ether. The mixed phase of alumina supports modified with 5 wt% of phosphorus exhibited the highest catalytic activity among other P-modified alumina catalysts giving the diethyl ether yield of 34.41%. In addition, the different types of noble metal modification were found to have a significant effect on catalytic performance. The 5P/Al2O3 catalyst deposited by palladium showed the highest catalytic activity through all of the studied catalysts reached 57.68% of diethyl ether yield. The highest average yield of diethyl ether of 42.50% was obtained from using Pd5P/Al2O3 catalyst in time on stream system for 10 h. Despite of high diethyl ether yield obtained, both 5P/Al2O3 and Pd5P/Al2O3 catalysts had the lower coke formation when compared to non-modified alumina supports.
Publisher:
ISBN:
Category : Catalysts
Languages : en
Pages : 332
Book Description
The mixture of 1:1 volume ratio of gamma and chi crystalline phase alumina support was prepared via the solvothermal technique using the mixed solution between toluene and 1-butanol. The support was brought to modify with phosphoric acid and noble metal agents. These catalysts were investigated on the effect of both phosphorus loading and types of noble metal on catalytic characteristic and catalytic activity. The catalytic performance was identified through ethanol dehydration reaction in gas phase process at 1 atm and temperature of 200oC to 400oC. The results were found that the phosphorus modification had an effect on catalytic acidity by decreasing the amount of medium to strong acid sites and raised quantity of weak acid sites. The higher amount of weak acid brought the catalysts to demonstrate the higher catalytic activity through the ethanol dehydration to diethyl ether. The mixed phase of alumina supports modified with 5 wt% of phosphorus exhibited the highest catalytic activity among other P-modified alumina catalysts giving the diethyl ether yield of 34.41%. In addition, the different types of noble metal modification were found to have a significant effect on catalytic performance. The 5P/Al2O3 catalyst deposited by palladium showed the highest catalytic activity through all of the studied catalysts reached 57.68% of diethyl ether yield. The highest average yield of diethyl ether of 42.50% was obtained from using Pd5P/Al2O3 catalyst in time on stream system for 10 h. Despite of high diethyl ether yield obtained, both 5P/Al2O3 and Pd5P/Al2O3 catalysts had the lower coke formation when compared to non-modified alumina supports.
Applied Science & Technology Index
Author:
Publisher:
ISBN:
Category : Electronic journals
Languages : en
Pages : 1744
Book Description
Publisher:
ISBN:
Category : Electronic journals
Languages : en
Pages : 1744
Book Description
Dissertation Abstracts International
Author:
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1090
Book Description
Publisher:
ISBN:
Category : Dissertations, Academic
Languages : en
Pages : 1090
Book Description
Catalyst Separation, Recovery and Recycling
Author: David J. Cole-Hamilton
Publisher: Springer Science & Business Media
ISBN: 9781402040863
Category : Science
Languages : en
Pages : 270
Book Description
This book looks at new ways of tackling the problem of separating reaction products from homogeneous catalytic solutions. The new processes involve low leaching supported catalysts, soluble supports such as polymers and dendrimers and unusual solvents such as water, fluorinated organics, ionic liquids and supercritical fluids. The advantages of the different possibilities are discussed alongside suggestions for further research that will be required for commercialisation. Unlike other books, in addition to the chemistry involved, the book looks at the process design that would be required to bring the new approaches to fruition. Comparisons are given with existing processes that have already been successfully applied and examples are given where these approaches are not suitable. The book includes: - New processes for the separation of products from solutions containing homogeneous catalysts - Catalysts on insoluble or soluble supports – fixed bed catalysts - continuous flow or ultrafiltration - Biphasic systems: water - organic, fluorous - organic, ionic liquid – organic, supercritical fluids (monophasic or biphasic with water, organic or ionic liquid) - Comparisons with current processes involving atmospheric or low temperature distillation - Consideration of Chemistry and Process Design - Advantages and disadvantages of each process exposed - Consideration of what else is need for commercialisation
Publisher: Springer Science & Business Media
ISBN: 9781402040863
Category : Science
Languages : en
Pages : 270
Book Description
This book looks at new ways of tackling the problem of separating reaction products from homogeneous catalytic solutions. The new processes involve low leaching supported catalysts, soluble supports such as polymers and dendrimers and unusual solvents such as water, fluorinated organics, ionic liquids and supercritical fluids. The advantages of the different possibilities are discussed alongside suggestions for further research that will be required for commercialisation. Unlike other books, in addition to the chemistry involved, the book looks at the process design that would be required to bring the new approaches to fruition. Comparisons are given with existing processes that have already been successfully applied and examples are given where these approaches are not suitable. The book includes: - New processes for the separation of products from solutions containing homogeneous catalysts - Catalysts on insoluble or soluble supports – fixed bed catalysts - continuous flow or ultrafiltration - Biphasic systems: water - organic, fluorous - organic, ionic liquid – organic, supercritical fluids (monophasic or biphasic with water, organic or ionic liquid) - Comparisons with current processes involving atmospheric or low temperature distillation - Consideration of Chemistry and Process Design - Advantages and disadvantages of each process exposed - Consideration of what else is need for commercialisation