Author: J.A. Moulijn
Publisher: Elsevier
ISBN: 0080886981
Category : Technology & Engineering
Languages : en
Pages : 485
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Book Description
Catalysis is a multidisciplinary activity which is reflected in this book. The editors have chosen a novel combination of basic disciplines - homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis with metallic and non-metallic solids. The main theme of the book is the molecular approach to industrial catalysis. In the introductory section Chapter 1 presents a brief survey of the history of industrial heterogeneous and homogeneous catalysis. Subsequently, a selection of current industrial catalytic processes is described (Chapter 2). A broad spectrum of important catalytic applications is presented, including the basic chemistry, some engineering aspects, feedstock sources and product utilisation. In Chapter 3, kinetic principles are treated. The section on fundamental catalysis begins with a description of the bonding in complexes and to surfaces (Chapter 4). The elementary steps on complexes and surfaces are described. The chapter on heterogeneous catalysis (5) deals with the mechanistic aspects of three groups of important reactions: syn-gas conversion, hydrogenation, and oxidation. The main principles of metal and metal oxide catalysis are presented. Likewise, the chapter on homogeneous catalysis (6) concentrates on three reactions representing examples from three areas: carbonylation, polymerization, and asymmetric catalysis. Identification by in situ techniques has been included. Many constraints to the industrial use of a catalyst have a macroscopic origin. In applied catalysis it is shown how catalytic reaction engineering deals with such macroscopic considerations in heterogeneous as well as homogeneous catalysis (Chapter 7). The transport and kinetic phenomena in both model reactors and industrial reactors are outlined. The section on catalyst preparation (Chapters 8 and 9) is concerned with the preparation of catalyst supports, zeolites, and supported catalysts, with an emphasis on general principles and mechanistic aspects. For the supported catalysts the relation between the preparative method and the surface chemistry of the support is highlighted. The molecular approach is maintained throughout. The first chapter (10) in the section on catalyst characterization summarizes the most common spectroscopic techniques used for the characterisation of heterogeneous catalysts such as XPS, Auger, EXAFS, etc. Temperature programmed techniques, which have found widespread application in heterogeneous catalysis both in catalyst characterization and simulation of pretreatment procedures, are discussed in Chapter 11. A discussion of texture measurement, theory and application, concludes this section (12). The final chapter (13) gives an outline of current trends in catalysis. Two points of view are adopted: the first one focusses on developments in process engineering. Most often these have their origin in demands by society for better processes. The second point of view draws attention to the autonomous developments in catalysis, which is becoming one of the frontier sciences of physics and chemistry. In this book emphasis is on those reactions catalyzed by heterogeneous and homogeneous catalysts of industrial relevance. The integrative treatment of the subject matter involves many disciplines, consequently, the writing of the book has been a multi-author task. The editors have carefully planned and harmonized the contents of the chapters.
Author: R.A. van Santen
Publisher: Elsevier
ISBN: 9780444505934
Category : Technology & Engineering
Languages : en
Pages : 646
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Book Description
This book concentrates on industrially relevant reactions which are catalyzed by heterogeneous and homogeneous catalysts. Homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis using metallic and non-metallic solids. In both areas the high degree of sophistication of spectroscopic techniques and theoretical modelling has led to an enormous increase in our understanding at the molecular level. This holds for the kinetics of the reactions and the reactivities of the catalysts, as well as for the syntheses of the catalytic materials. The development of catalysis science since the first edition of this book has necessitated a thorough revision, including special chapters on biocatalysis, catalyst characterization and adsorption methods. The multidisciplinary nature of catalysis is reflected in the choice of a novel combination of basic disciplines which will be refreshing and inspiring to readers.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Author: Paul C J Kamer
Publisher: Royal Society of Chemistry
ISBN: 178801233X
Category : Science
Languages : en
Pages : 897
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Book Description
Encompassing an integrated approach to the various aspects of catalysis, covering heterogeneous, homogeneous, organo-, bio-, and computational catalysis, as well as reaction and reactor engineering on an advanced level, this textbook is ideal for graduate students with diverse backgrounds, including catalysis, engineering, and organic synthesis. The basic principles of the various fields of catalysis are introduced in a concise way, preparing the reader for the more advanced chapters. Organometallic chemistry, surface science, biochemistry, nanoscience, transport phenomena and kinetics, reactor and reaction engineering are presented, spanning from the underlying science to industrial applications. Several important case studies on industrial applications are given. It includes catalyst preparation and characterisation and explores recent developments in the understanding of catalytic mechanisms, exploring advanced techniques such as operando spectroscopy.
Author: Jacob A. Moulijn
Publisher:
ISBN:
Category :
Languages : en
Pages : 460
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Book Description
Author: James D Burrington
Publisher: World Scientific Publishing Company
ISBN: 1783269006
Category : Science
Languages : en
Pages : 296
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Book Description
Industrial Catalysis: Chemistry and Mechanism is an essential textbook for upper-level undergraduate and graduate students with an interest in the underlying concepts of catalysis, industrial organic chemistry and the mechanism of catalysis. For undergraduates it provides an introduction to the basic catalytic principles and industrial processes. Graduate students will find that the book gives an in-depth understanding of the mechanism of catalytic surface intermediates and the practice of modern catalysis research. For the post graduate and industrial chemist involved in catalysis research, it is a valuable reference text as a compendium of mechanisms by which major industrial catalytic processes operate.This unique book fills the gap between basic organic chemistry and fundamental chemical principles of catalysis, and is a must read for students and researchers in the field.
Author: Jens Hagen
Publisher: John Wiley & Sons
ISBN: 3527607064
Category : Science
Languages : en
Pages : 525
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Book Description
Despite the fact that more than 90% of production processes in industry are catalyzed, most chemists and engineers are restricted to trial and error when searching for the proper catalyst. This book is the first emphasizing industrial aspects of catalysis and also particularly well suited to studying on one's own. It is dedicated to both, homogeneous and heterogeneous catalysis and in this second, edition biocatalysis, electrocatalysis, photocatalysis and asymmetric catalysis are also included; topics like zeolites, metals and olefin catalysis are now discussed in more detail. The book aids practically oriented readers in becoming familiar with the processes of catalyst development and testing and therefore deals with aspects of test planning, optimization and reactor modeling and simulation with the easy-to-learn PC program POLYMATH. Well over 100 exercises help to test and consolidate the gained knowledge.
Author: Jacob A. Moulijn
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Book Description
Author: Ulf Hanefeld
Publisher: John Wiley & Sons
ISBN: 3527341595
Category : Technology & Engineering
Languages : en
Pages : 384
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Book Description
Written by an excellent, highly experienced and motivated team of lecturers, this textbook is based on one of the most successful courses in catalysis and as such is tried-and-tested by generations of graduate and PhD students, i.e. the Catalysis-An-Integrated-Approach (CAIA) course organized by NIOK, the Dutch Catalysis research school. It covers all essential aspects of this important topic, including homogeneous, heterogeneous and biocatalysis, but also kinetics, catalyst characterization and preparation, reactor design and engineering. The perfect source of information for graduate and PhD students in chemistry and chemical engineering, as well as for scientists wanting to refresh their knowledge
Author: Julian R.H. Ross
Publisher: Elsevier
ISBN: 008095684X
Category : Technology & Engineering
Languages : en
Pages : 233
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Book Description
Heterogeneous catalysis plays a part in the production of more than 80% of all chemical products. It is therefore essential that all chemists and chemical engineers have an understanding of the fundamental principles as well as the applications of heterogeneous catalysts. This book introduces the subject, starting at a basic level, and includes sections on adsorption and surface science, catalytic kinetics, experimental methods for preparing and studying heterogeneous catalysts, as well as some aspects of the design of industrial catalytic reactors. It ends with a chapter that covers a range of examples of important catalytic processes.The book leads the student to carrying out a series of "tasks" based on searches of the internet and also on the use of web-based search tools such as Scopus or Web of Science. These tasks are generally based on the text; they can be used entirely for self-study but they can also be tailored to the requirements of a particular course by the instructor/lecturer giving the course.The author has had over 40 years of experience in catalytic research as well as in lecturing on the principles of catalysis. He was for more than 20 years the Editor of Catalysis Today. Coverage of all aspects of catalysis in carefully organised text Inclusion of material on the historical development of the subject and the personalities involved All concepts illustrated by practical examples Inclusion of a wide range of problems and solutions, case studies, and supplementary web based material which will be regularly updated Author has over 40 years research experience of almost all covered subjects Provides companion materials webiste
