Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods

Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods PDF Author: Hülya Arslan
Publisher:
ISBN:
Category : Science
Languages : en
Pages :

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Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods.

Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods

Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods PDF Author: Hülya Arslan
Publisher:
ISBN:
Category : Science
Languages : en
Pages :

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Book Description
Block and Graft Copolymerization by Controlled/Living Radical Polymerization Methods.

Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations

Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations PDF Author: Kelly A. Davis
Publisher: Springer Science & Business Media
ISBN: 3540458069
Category : Technology & Engineering
Languages : en
Pages : 202

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Book Description
The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.

Controlled/living Radical Polymerization

Controlled/living Radical Polymerization PDF Author: Krzysztof Matyjaszewski
Publisher: Academic
ISBN:
Category : Language Arts & Disciplines
Languages : en
Pages : 444

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Book Description
Recent progress in the field of controlled/living radical polymerization.

Handbook of Radical Polymerization

Handbook of Radical Polymerization PDF Author: Krzysztof Matyjaszewski
Publisher: John Wiley & Sons
ISBN: 047139274X
Category : Technology & Engineering
Languages : en
Pages : 934

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Book Description
* Provides a concise source of information on synthetic techniques, purification, and characterization methods for free-radical polymers. * Presents information on future trends in the synthesis of free-radical polymers.

Block and Graft Copolymerization

Block and Graft Copolymerization PDF Author: R. J. Ceresa
Publisher:
ISBN: 9780835773232
Category : Block copolmers
Languages : en
Pages : 0

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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations

Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations PDF Author: Kelly A. Davis
Publisher: Springer Science & Business Media
ISBN: 3540458069
Category : Technology & Engineering
Languages : en
Pages : 202

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Book Description
The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers.

Controlled and Living Polymerizations

Controlled and Living Polymerizations PDF Author: Krzysztof Matyjaszewski
Publisher: John Wiley & Sons
ISBN: 9783527629107
Category : Science
Languages : en
Pages : 634

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Book Description
Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Handbook of Vinyl Polymers

Handbook of Vinyl Polymers PDF Author: Munmaya Mishra
Publisher: CRC Press
ISBN: 0824725956
Category : Technology & Engineering
Languages : en
Pages : 784

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Book Description
Radical polymerization is one of the most widely used means of producing vinyl polymers, supporting a myriad of commercial uses. Maintaining the quality of the critically acclaimed first edition, the Handbook of Vinyl Polymers: Radical Polymerization, Process, and Technology, Second Edition provides a fully updated, single-volume source on the chemistry, technology, and applications of vinyl polymers. Emphasizes radical initiating systems and mechanisms of action... Written by renowned researchers in the field, this handbook is primarily concerned with the physical and organic chemistry of radical vinyl polymerization. The authors survey the most recent advances, processing methods, technologies, and applications of free radical vinyl polymerization. The book features thorough coverage of polymer functionalization, photo initiation, block and graft copolymers, and polymer composites. Analyzes living/controlled radical polymerization, one of the latest developments in the field... Combining fundamental aspects with the latest advances, processing methods, and applications in free radical vinyl polymerization and polymer technology, this invaluable reference provides a unified, in-depth, and innovative perspective of radical vinyl polymerization.

Block and Graft Copolymers

Block and Graft Copolymers PDF Author: R. J. Ceresa
Publisher:
ISBN:
Category : Block copolymers
Languages : en
Pages : 224

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Design and Synthesis of Functional Graft Copolymers with Complex Architecture by Controlled Radical Polymerization Methods

Design and Synthesis of Functional Graft Copolymers with Complex Architecture by Controlled Radical Polymerization Methods PDF Author: Alper Nese
Publisher:
ISBN:
Category :
Languages : en
Pages : 0

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Book Description