Biocompatible Porous Coordination Polymers and Their Application in Catalysis and Environmental Remediation PDF Download
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Author: Paula Sara Escamilla Berenguer
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Author: Paula Sara Escamilla Berenguer
Publisher:
ISBN:
Category :
Languages : en
Pages : 0
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Author: Nolan Wayne Waggoner
Publisher:
ISBN:
Category :
Languages : en
Pages : 658
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Book Description
Porous coordination polymers (PCPs) have emerged as a novel and versatile class of crystalline materials since the late 1990’s due to their high porosity and tunable reactivity. Applications for these materials have spread to areas including gas storage and separations, sensing, magnetism, and more recently, catalysis. However, designing a PCP-based material for a specific application remains a struggle within this field due to their unpredictable self-assembly. In order to overcome this hurdle, linker design has become paramount to the process. The Humphrey Group has developed a new class of PCPs called Phosphine Coordination Materials (PCMs). These materials incorporate one or more phosphorous sites within the linker to act as a point of functionalization. The lone pair of each P(III) site can act as a tunable handle, which allows for access to increased chemical versatility. With this larger goal in mind, the research discussed herein has been focused on the development of novel materials on three fronts: catalytically active linkers, employment of structure directing agents, and examination of PCMs in magnetism. Several catalytically active organic linkers were developed for the purpose of taking known homogenous reactivity and applying that knowledge to a heterogeneous framework. The linker systems described herein include trans-RuCl2(1,2-C6H4-((P-C6H4-p-CO2H)2)2, the ferrocene backbone system Fe(C5H4)2-(P-(C6H4-p-CO2H)2)2, and the extended building block 1,2-C6H4-(P-(¬p-C6H4-p-C6H4-CO2H)2)2. The second study examined a [Me-P-(C6H4-p-CO2H)3]+ Cl- linker to create a series of frameworks through variation of only the alkali hydroxide added during synthesis. This resulted in five frameworks, four of which were non-isostructural. Designated PCMs 6-9, the frameworks demonstrated unusual pore topology as well as the highest cryogenic oxygen uptake to date for a saturated metal site material. Next, two isostructural materials termed Ln-PCM-21 were synthesized and their experimental bulk magnetic properties were studied. Afterwards, three theoretical models were considered in relation to this experimental data and their relatability was reported. The final study explored the magnetic behavior of a set of 1-dimensional coordination polymers that conversely employed thiolate groups; referred to as Thiolate Coordination Materials (TCMs). One material, Fe-TCM-1, was extensively studied and two isostructural materials were attempted (CoII, MnII), with interest in single-chain magnetic behavior.
Author: Navinchandra Gopal Shimpi
Publisher: Woodhead Publishing
ISBN: 0081010583
Category : Technology & Engineering
Languages : en
Pages : 460
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Book Description
Biodegradable and Biocompatible Polymer Composites: Processing, Properties and Applications begins by discussing the current state-of-the-art, new challenges and opportunities for various biodegradable and biocompatible polymer composite systems. Interfacial characterization of composites and the structure-property relationships in various composite systems are explained in detail via a theoretical model. Processing techniques for various macro and nanocomposite systems and the influence of processing parameters on properties of the composite are also reviewed in detail. The characterization of microstructure, elastic, visco-elastic, static and dynamic mechanical, thermal, rheological, optical, and electrical properties are highlighted, as are a broad range of applications. The book is a useful reference resource for both researchers and engineers working in composites materials science, biotechnology and nanotechnology, and is also useful for students attending chemistry, physics, and materials science and engineering courses. - Presents recent outcomes and highlights the going importance of biodegradable and biocompatible polymer composites and their impact on the environment - Analyzes all the main processing techniques, characterization and applications of biodegradable composites - Written by leading international experts working in the field of biodegradable and biocompatible polymer composites - Covers a broad range of application fields, including medical and pharmaceutical, agricultural, packaging and transport
Author: Sujit K. Ghosh
Publisher: Elsevier
ISBN: 0128146346
Category : Science
Languages : en
Pages : 465
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Book Description
Metal-Organic Frameworks for Environmental Applications examines this important topic, looking at potential materials and methods for the remediation of pressing pollution issues, such as heavy-metal contaminants in water streams, radioactive waste disposal, marine oil-spillage, the treatment of textile and dye industry effluents, the clean-up of trace amounts of explosives in land and water, and many other topics. This survey of the cutting-edge research and technology of MOFs is an invaluable resource for researchers working in inorganic chemistry and materials science, but it is also ideal for graduate students studying MOFs and their applications. - Examines the applications of metal-organic frameworks for the remediation of environmental pollutants - Features leading experts who research the applications of MOFs from around the world, including contributions from the United States, India and China - Explores possible solutions to some of today's most pressing environmental challenges, such as heavy-metal contamination in bodies of water, oil spills and clean-up of explosives hidden in land and water - Provides an excellent reference for researchers and graduate students studying in the areas of inorganic chemistry, materials chemistry and environmental science
Author: Minghua Zhou
Publisher: Springer
ISBN: 9811064067
Category : Science
Languages : en
Pages : 437
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Book Description
This volume discusses the theoretical fundamentals and potential applications of the original electro-Fenton (EF) process and its most innovative and promising versions, all of which are classified as electrochemical advanced oxidation processes. It consists of 15 chapters that review the latest advances and trends, material selection, reaction and reactor modeling and EF scale-up. It particularly focuses on the applications of EF process in the treatment of toxic and persistent organic pollutants in water and soil, showing highly efficient removal for both lab-scale and pre-pilot setups. Indeed, the EF technology is now mature enough to be brought to market, and this collection of contributions from leading experts in the field constitutes a timely milestone for scientists and engineers.
Author: Ghulam Yasin
Publisher: CRC Press
ISBN: 1040124607
Category : Technology & Engineering
Languages : en
Pages : 326
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Book Description
As an emerging material platform, multifunctional coordination materials offer many advantages such as remarkable porosity, structural flexibility, crystallinity, and modifiable functionalities that render them highly suited to generate and store green energy. This book covers the design and fabrication approaches of multifunctional coordination materials for green energy-related technologies, including batteries, supercapacitors, solar cells, and nanogenerators. • Discusses fundamentals of multifunctional coordination materials. • Explains vital synthesis and design techniques as well as theoretical modeling. • Offers a comprehensive overview of preparation, structural and morphological properties, and applications in a wide variety of energy production, energy storage, and energy device technologies. • Assesses environmental impacts, recycling, challenges, and future perspectives. Multifunctional Coordination Materials for Green Energy Technologies is an ideal reference for advanced students and researchers working in materials engineering, including new catalyst development, battery design, and related areas.
Author: Mohamed Abou El-Fetouh Barakat
Publisher: CRC Press
ISBN: 1000532852
Category : Technology & Engineering
Languages : en
Pages : 365
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Book Description
Nanomaterials for Environmental Applications offers a comprehensive review of the latest advances in nanomaterials-based technologies for the treatment of emerging contaminants in wastewater. It describes the latest developments in the synthesis protocols, including the synthesis of different kinds of nanostructure materials using various physical and chemical methods. Features Discusses the synthesis and characterization of important nanomaterials such as carbon nanostructures, metal and metal oxide nanostructures, polymer nanostructures, and smart 1D-–3D nanomaterials Presents the latest techniques used in the characterization of nanomaterials Covers environmental applications including the remediation of pollutants in wastewater and water purification and disinfection Examines the sources, fate, transport, and ecotoxicology of nanomaterials in the environment. Aimed at researchers and industry professionals, this work will be of interest to chemical, environmental, and materials engineers concerned with the application of advanced materials for environmental and water remediation. Mohamed Abou El-Fetouh Barakat is a Professor of Environmental Sciences at both King Abdulaziz University (KAU)- Saudi Arabia, and Central Metallurgical R&D Institute (CMRDI)- Egypt. He is highly qualified in the fields of industrial waste management and pollution control as well as catalysis and nanotechnology. His experience includes academic research works in Japan, Germany, the United States and Saudi Arabia, as well as initiating and leading industrial research projects in Egypt jointly with the United States. Rajeev Kumar is an Associate Professor in the Environmental Science Department, King Abdulaziz University, Jeddah, Saudi Arabia. His research activities are in the areas of wastewater treatment and materials science. He studies the adsorption and photocatalytic properties of nanomaterials for the removal of contaminants from wastewater.
Author: Flavio Pendolino
Publisher: Springer
ISBN: 3319604295
Category : Technology & Engineering
Languages : en
Pages : 56
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Book Description
This book discusses the remediation process using graphene oxide as removal agent from a chemical point of view. State of the art, properties of graphene oxide and its preparation methods are reported in the introduction. Environmental issues and regulations are presented in view of applying graphene oxide dispersion to the purification of aqueous medium, especially for industrial wastewater. The remediation process, for removal organic molecules, inorganic/metallic ions, covers the last part of the book. Future prospective for graphene oxide in the environmental remediation approach is commented.
Author: Mattia Bartoli
Publisher: BoD – Books on Demand
ISBN: 1789845866
Category : Science
Languages : en
Pages : 190
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Book Description
Carbon-Based Material for Environmental Protection and Remediation presents an overview of carbon-based technologies and processes, and examines their usefulness and efficiency for environmental preservation and remediation. Chapters cover topics ranging from pollutants removal to new processes in materials science. Written for interested readers with strong scientific and technological backgrounds, this book will appeal to scientific advisors at private companies, academics, and graduate students.
Author: Arbind Prasad
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3111321533
Category : Science
Languages : en
Pages : 372
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Book Description
The sustainability of any process lies in the eco-friendly and economical production of products for applications. Bio-based materials are emerging as raw materials for different products and applications. The book covers cellulose, chitosan, silk, collagen and gelatin bio-based materials. It describes their use in biomedical applications, such as orthopaedic implant, drug delivery, tissue culture, biosensor and engineering applications such as fuel cells, energy storage and packaging. It concludes with the use of bio-based materials as precursors for biorefinery, biolubricants, membranes and adsorbents.
