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Author: Naohiko Yoshikai
Publisher: Thieme Chemistry
ISBN: 9783132453807
Category :
Languages : en
Pages : 0
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Book Description
Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis. Volume 1 is focused on recent advances in copper and nickel catalysis, including Ullmann-type coupling, reductive coupling and cross-coupling reactions, CH activation and functionalization, and alkene hydrofunctionalization and difunctionalization. Methods for the installation of important functional groups such as trifluoromethyl and carboxyl, and for the aerobic oxidation of alcohols are also covered.
Author: Naohiko Yoshikai
Publisher: Thieme Chemistry
ISBN: 9783132453807
Category :
Languages : en
Pages : 0
Get Book Here
Book Description
Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis. Volume 1 is focused on recent advances in copper and nickel catalysis, including Ullmann-type coupling, reductive coupling and cross-coupling reactions, CH activation and functionalization, and alkene hydrofunctionalization and difunctionalization. Methods for the installation of important functional groups such as trifluoromethyl and carboxyl, and for the aerobic oxidation of alcohols are also covered.
Author: Xiao-Feng Wu
Publisher: Springer Nature
ISBN: 3031328671
Category : Science
Languages : en
Pages : 403
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Book Description
This volume presents recent progress on 3d base metal catalyzed C-C cross coupling reactions. The contributions provide detailed discussions on the use of cheap metal catalysts such as Cr, Mn, Fe, Co, Ni, Cu, and Zn to construct Csp2-Csp2, Csp2-Csp3 and Csp3-Csp3 bonds with a variety of substrates. These non-noble metal catalyst have many advantages such as being inexpensive, having low toxicity and are environmentally benign. Therefore the use of cheap metal catalysts in organic synthesis has gained much attention in efforts to develop more sustainable synthetic green chemistry. Each chapter is written by international experts in the field and is a great resource for students, researchers and chemists working in industry to gain an overview on the latest developments.
Author: Naohiko Yoshikai
Publisher: Georg Thieme Verlag
ISBN: 3132455040
Category : Science
Languages : en
Pages : 876
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Book Description
Recent advances in catalytic methods based on earth-abundant metals are discussed. Catalysis with earth-abundant metals, often referred to as base metals, is having a transformative impact on synthetic chemistry. Research in this area is driven not only by the common interest in the sustainability of chemical synthesis but also by the vast opportunity to discover and develop novel reaction chemistry that is not attainable with rare and precious metal catalysts. This work provides representative developments in base-metal catalysis, specifically catalysis with 3d-transition metals, in a format suitable for practitioners of organic synthesis. Volume 2 is focused on recent advances in catalysis involving cobalt, iron, manganese, and chromium. Topics covered include various types of cross-coupling processes, hydrofunctionalization of alkenes and alkynes, C-H functionalizations, and catalytic Nozaki–Hiyama–Kishi-type reactions.
Author: Silvia Diez-Gonzalez
Publisher: Royal Society of Chemistry
ISBN: 1782626816
Category : Science
Languages : en
Pages : 637
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Book Description
In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.
Author: Sjoerd Harder
Publisher: John Wiley & Sons
ISBN: 3527344489
Category : Technology & Engineering
Languages : en
Pages : 400
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Book Description
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
Author: James Arthur Anderson
Publisher: World Scientific
ISBN: 184816677X
Category : Science
Languages : en
Pages : 581
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Book Description
With contributions from experts in supported metal catalysis, from both the industry and academia, this book presents the latest developments in characterization and application of supported metals in heterogeneous catalysis. In addition to a thorough and updated coverage of the traditional aspects of heterogeneous catalysis such as preparation, characterization and use in well-established technologies such as Naphtha reforming, the book also includes emerging areas where supported metal catalysis will make significant contributions in future developments, such as fuel cells and fine chemicals synthesis. The second edition of Supported Metals in Catalysis comes complete with new and updated chapters containing important summaries of research in a rapidly evolving field. Very few other books deal with this highly pertinent subject matter, and as such, it is a must-have for anyone working in the field of heterogeneous catalysis.
Author: Ivica Cepanec
Publisher: Elsevier
ISBN: 0080474535
Category : Science
Languages : en
Pages : 365
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Book Description
Organic chemistry is one of the most rapidly growing sciences. There is a wide variety of applications of organic compounds, for instance, pharmaceutically active substances, agrochemicals, optoelectronics, etc. Within this group there are hundereds and thousands of new compounds synthesized or isolated from natural sources. Such important organic chemistry developments are accompanied by the profound break-through of new reactions, increasingly efficient methodologies, reagents and catalysts. The chemistry of biaryls is one of the most interesting fields in organic chemistry, this book looks at these reactions both new and old. Synthesis of Biaryls presents the description of a given method for the synthesis of biaryls: short introduction, reaction mechanism, application, representative synthetic procedures, conclusion and literature references. This book will be of interest to organic chemists in industry and academia. - A topic of growing importance in organic synthesis - The FIRST book to cover all reactions for the synthesis of biaryls, including the most recent - The book provides detailed applications of each method described
Author: Peng-Fei Xu
Publisher: John Wiley & Sons
ISBN: 1118016025
Category : Science
Languages : en
Pages : 440
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Book Description
Demonstrates the advantages of catalytic cascade reactions for synthesizing natural products and pharmaceuticals Riding the wave of green chemistry, catalytic cascade reactions have become one of the most active research areas in organic synthesis. During a cascade reaction, just one reaction solvent, one workup procedure, and one purification step are needed, thus significantly increasing synthetic efficiency. Featuring contributions from an international team of pioneers in the field, Catalytic Cascade Reactions demonstrates the versatility and application of these reactions for synthesizing valuable compounds. The book examines both organocatalysis and transition-metal catalysis reactions, bringing readers up to date with the latest discoveries and activities in all major areas of catalytic cascade reaction research. Catalytic Cascade Reactions begins with three chapters dedicated to organocatalytic cascade reactions, exploring amines, Brønsted acids, and the application of organocatalytic cascade reactions in natural product synthesis and drug discovery. Next, the book covers: Gold-catalyzed cascade reactions Cascade reactions catalyzed by ruthenium, iron, iridium, rhodium, and copper Palladium-catalyzed cascade reactions of alkenes, alkynes, and allenes Application of transition-metal catalyzed cascade reactions in natural product synthesis and drug discovery Engineering mono- and multifunctional nanocatalysts for cascade reactions Multiple-catalyst-promoted cascade reactions All chapters are thoroughly referenced, providing quick access to important original research findings and reviews so that readers can explore individual topics in greater depth. Drawing together and analyzing published findings scattered across the literature, this book provides a single source that encapsulates our current understanding of catalytic cascade processes. Moreover, it sets the stage for the development of new catalytic cascade reactions and their applications.
Author: Jiro Tsuji
Publisher: John Wiley & Sons
ISBN: 9780471560272
Category : Science
Languages : en
Pages : 500
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Book Description
Im Laufe der vergangenen 35 Jahre wurden unzahlige Synthesewege entwickelt, bei denen Ubergangsmetallkomplexe entweder als Reagenzien oder als Katalysatoren fungieren. Dieses Buch bietet besonders denjenigen Synthesechemikern interessante und moderne Einblicke, die bisher noch nicht mit den vielfaltigen Moglichkeiten der Organometallchemie mit Ubergangsmetallen vertraut sind. Zu wichtigen ubergangsmetallkatalysierten Reaktionen werden Anwendungsbeispiele diskutiert. (01/00)
Author: Robertus J. M. Klein Gebbink
Publisher: John Wiley & Sons
ISBN: 3527340610
Category : Technology & Engineering
Languages : en
Pages : 610
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Book Description
An expert overview of current research, applications, and economic and environmental advantages The study and development of new homogeneous catalysts based on first-row metals (Mn, Fe, Co, Ni, and Cu) has grown significantly due to the economic and environmental advantages that non-noble metals present. Base metals offer reduced cost, greater supply, and lower toxicity levels than noble metals?enabling greater opportunity for scientific investigation and increased development of practical applications. Non-Noble Metal Catalysis provides an authoritative survey of the field, from fundamental concepts and computational methods to industrial applications and reaction classes. Recognized experts in organometallic chemistry and homogeneous catalysis, the authors present a comprehensive overview of the conceptual and practical aspects of non-noble metal catalysts. Examination of topics including non-innocent ligands, proton-coupled electron transfer, and multi-nuclear complexes provide essential background information, while areas such as kinetic lability and lifetimes of intermediates reflect current research and shifting trends in the field. This timely book demonstrates the efficacy of base metal catalysts in the pharmaceutical, fine-chemical, and agrochemical industries, addressing both environmental and economic concerns. Providing essential conceptual and practical exploration, this valuable resource: -Illustrates how unravelling new reactivity patterns can lead to new catalysts and new applications -Highlights the multiple advantages of using non-noble metals in homogenous catalysis -Demonstrates how the availability of non-noble metal catalysis reduces costs and leads to immense savings for the chemical industry -Reveals how non-noble metal catalysis are more sustainable than noble metals such as palladium or platinum Non-Noble Metal Catalysis: Molecular Approaches and Reactions is an indispensable source of up-to-date information for catalytic chemists, organic chemists, industrial chemists, organometallic chemists, and those seeking to broaden their knowledge of catalytic chemistry.
