Aqueous Systems at Elevated Temperatures and Pressures

Aqueous Systems at Elevated Temperatures and Pressures PDF Author: Roberto Fernandez-Prini
Publisher: Elsevier
ISBN: 0080471994
Category : Science
Languages : en
Pages : 767

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Book Description
The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds

Aqueous Systems at Elevated Temperatures and Pressures

Aqueous Systems at Elevated Temperatures and Pressures PDF Author: Roberto Fernandez-Prini
Publisher: Elsevier
ISBN: 0080471994
Category : Science
Languages : en
Pages : 767

Get Book Here

Book Description
The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds

Hydrothermal Properties of Materials

Hydrothermal Properties of Materials PDF Author: Vladimir Valyashko
Publisher: John Wiley & Sons
ISBN: 0470094664
Category : Science
Languages : en
Pages : 312

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Book Description
Hydrothermal Properties of Materials: Experimental Data on Aqueous Phase Equilibria and Solution Properties at Elevated Temperatures and Pressures is designed for any scientists and engineer who deals with hydrothermal investigations and technologies. The book is organized into eight chapters, each dealing with a key physical property of behavior of solutions, so that a reader can obtain information on: hydrothermal experimental methods; available experimental data and the main features of properties behavior in a wide range of temperatures and pressures; and possible ways of experimental data processing for obtaining the derivative properties.

Aqueous Systems at Elevated Temperatures and Pressures

Aqueous Systems at Elevated Temperatures and Pressures PDF Author: Donald Alan Palmer
Publisher:
ISBN: 9780126555615
Category : Feed-water
Languages : en
Pages : 753

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Book Description


Thermodynamics of Geothermal Fluids

Thermodynamics of Geothermal Fluids PDF Author: Andri Stefánsson
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 1501508296
Category : Science
Languages : en
Pages : 360

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Book Description
Volume 76 of Reviews in Mineralogy and Geochemistry presents an extended review of the topics conveyed in a short course on Geothermal Fluid Thermodynamics held prior to the 23rd Annual V.M. Goldschmidt Conference in Florence, Italy (August 24-25, 2013). It covers Thermodynamics of Geothermal Fluids, The Molecular-Scale Fundament of Geothermal Fluid Thermodynamics, Thermodynamics of Aqueous Species at High Temperatures and Pressures: Equations of State and Transport Theory, Mineral Solubility and Aqueous Speciation Under Hydrothermal Conditions to 300 °C – The Carbonate System as an Example, Thermodynamic Modeling of Fluid-Rock Interaction at Mid-Crustal to Upper-Mantle Conditions, Speciation and Transport of Metals and Metalloids in Geological Vapors, Solution Calorimetry Under Hydrothermal Conditions, Structure and Thermodynamics of Subduction Zone Fluids from Spectroscopic Studies and Thermodynamics of Organic Transformations in Hydrothermal Fluids.

Thermodynamics and Kinetics of Water-Rock Interaction

Thermodynamics and Kinetics of Water-Rock Interaction PDF Author: Eric H. Oelkers
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 1501508466
Category : Science
Languages : en
Pages : 588

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Book Description
Volume 70 of Reviews in Mineralogy and Geochemistry represents an extensive review of the material presented by the invited speakers at a short course on Thermodynamics and Kinetics of Water-Rock Interaction held prior to the 19th annual V. M. Goldschmidt Conference in Davos, Switzerland (June 19-21, 2009). Contents: Thermodynamic Databases for Water-Rock Interaction Thermodynamics of Solid Solution-Aqueous Solution Systems Mineral Replacement Reactions Thermodynamic Concepts in Modeling Sorption at the Mineral-Water Interface Surface Complexation Modeling: Mineral Fluid Equilbria at the Molecular Scale The Link Between Mineral Dissolution/Precipitation Kinetics and Solution Chemistry Organics in Water-Rock Interactions Mineral Precipitation Kinetics Towards an Integrated Model of Weathering, Climate, and Biospheric Processes Approaches to Modeling Weathered Regolith Fluid-Rock Interaction: A Reactive Transport Approach Geochemical Modeling of Reaction Paths and Geochemical Reaction Networks

Frontiers in Geofluids

Frontiers in Geofluids PDF Author: Bruce W. D. Yardley
Publisher: John Wiley & Sons
ISBN: 1444394894
Category : Science
Languages : en
Pages : 639

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Book Description
Frontiers in Geofluids is a collection of invited papers chosen to highlight recent developments in our understanding of geological fluids in different parts of the Earth, and published to mark the first ten years of publication of the journal Geofluids. The scope of the volume ranges from the fundamental properties of fluids and the phase relationships of fluids encountered in nature, to case studies of the role of fluids in natural processes. New developments in analytical and theoretical approaches to understanding fluid compositions, fluid properties, and geological fluid dynamics across a wide range of environments are included. A recurrent theme of research published in Geofluids is the way in which similar approaches can be applied to geological fluids in very different settings and this is reflected in the diverse range of applications of fluid studies that are included here. They include deep groundwater flow, hydrocarbons in faulted sedimentary basins, hydrothermal ores, and multiphase flow in mid-ocean ridge systems. Other topics covered are geothermal waters, crustal metamorphism, and fluids in magmatic systems. The book will be of great interest to researchers and students interested in crustal and mantle fluids of all sorts.

Thermodynamic Data

Thermodynamic Data PDF Author: Surendra K. Saxena
Publisher: Springer Science & Business Media
ISBN: 1461228425
Category : Science
Languages : en
Pages : 380

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Book Description
With the rapid development of fast processors, the power of a mini-super computer now exists in a lap-top box. Quite sophisticated techniques are be coming accessible to geoscientists, thus making disciplinary boundaries fade. Chemists and physicists are no longer shying away from computational mineral ogical and material science problems "too complicated to handle." Geoscientists are willing to delve into quantitative physico-chemical methods and open those "black boxes" they had shunned for several decades but with which had learned to live. I am proud to present yet another volume in this series which is designed to break the disciplinary boundaries and bring the geoscientists closer to their chemist and physicist colleagues in achieving a common goal. This volume is the result of an international collaboration among many physical geochemists (chemists, physicists, and geologists) aiming to understand the nature of material. The book has one common theme: namely, how to determine quantitatively through theory the physico-chemical parameters of the state of a solid or fluid.

The Environmental Chemistry of Aluminum

The Environmental Chemistry of Aluminum PDF Author: Garrison Sposito
Publisher: CRC Press
ISBN: 0429612486
Category : Science
Languages : en
Pages : 477

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Book Description
The Environmental Chemistry of Aluminum provides a comprehensive, fundamental account of the aqueous chemistry of aluminum within an environmental context. An excellent reference for environmental chemists and scientific administrators of environmental programs, this book contains material reflecting the many recent changes in this rapidly developing discipline. The first three chapters discuss the most fundamental aspects of aluminum chemistry: its quantitation in soils and natural waters, including speciation measurements, and its stable chemical forms, both as a dissolved solute and in a solid phase. These chapters emphasize both critical assessments of and definitive recommendations for laboratory methodologies and measured thermodynamic properties relating to aluminum chemistry. The next four chapters in The Environmental Chemistry of Aluminum build on this foundation to provide details of the polymeric chemistry of aluminum: its polynuclear and colloidal hydrolytic species in aqueous solution, its complexes with natural organic ligands, including humic substances, and its role as an adsorptive and adsorbent in surface reactions. These chapters are grounded in experimental results rather than conceptual modeling. The final three chapters describe the chemistry of aluminum in soils, waters, and watersheds. These chapters illustrate the problems of spatial and temporal variability, metastability, and scale that continue to make aluminum geochemistry one of the great challenges in modern environmental science.

Electrochemical Materials Science

Electrochemical Materials Science PDF Author: John Bockris
Publisher: Springer Science & Business Media
ISBN: 1475748256
Category : Science
Languages : en
Pages : 579

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Book Description
It is now time for a comprehensive treatise to look at the whole field of electrochemistry. The present treatise was conceived in 1974, and the earliest invitations to authors for contributions were made in 1975. The completion of the early been delayed by various factors. volumes has There has been no attempt to make each article emphasize the most recent situation at the expense of an overall statement of the modern view. This treatise is not a collection of articles from Recent Advances in Electrochemistry or Modern Aspects of Electrochemistry. It is an attempt at making a mature statement about the present position in the vast area of what is best looked at as a new interdisciplinary field. Texas A & M University J. O'M. Bockris University of Ottawa B. E. Conway Case Western Reserve University Ernest Yeager Texas A & M University Ralph E. White Preface to Volume 4 The science of degradation of materials involves a vast area of science and technology, the economic importance of which rivals that of any other clearly defined area affecting the standard of life. The basis of the corrosion process is the electrochemical charge-transfer reaction, and the center of the subject of the degradation of materials is electrochemical material science.

Hydrothermal and Supercritical Water Processes

Hydrothermal and Supercritical Water Processes PDF Author: Gerd Brunner
Publisher: Elsevier
ISBN: 0444594183
Category : Science
Languages : en
Pages : 683

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Book Description
Hydrothermal and Supercritical Water Processes presents an overview on the properties and applications of water at elevated temperatures and pressures. It combines fundamentals with production process aspects. Water is an extraordinary substance. At elevated temperatures (and pressures) its properties change dramatically due to the modifications of the molecular structure of bulk water that varies from a stable three-dimensional network, formed by hydrogen bonds at low and moderate temperatures, to an assembly of separated polar water molecules at high and supercritical temperatures. With varying pressure and temperature, water is turned from a solvent for ionic species to a solvent for polar and non-polar substances. This variability and an enhanced reactivity of water have led to many practical applications and to even more research activities, related to such areas as energy transfer, extraction of functional molecules, unique chemical reactions, biomass conversion and fuel materials processing, destruction of dangerous compounds and recycling of useful ones, growth of monolithic crystals, and preparation of metallic nanoparticles. This book provides an introduction into the wide range of activities that are possible in aqueous mixtures. It is organized to facilitate understanding of the main features, outlines the main applications, and gives access to further information - Summarizes fundamental properties of water for engineering applications - Compares process and reactor designs - Evaluates processes from thermodynamic, economic, and social impact viewpoints