Applications of Lanthanide Luminescence Spectroscopy as a Probe of Solution Structure and Dynamics PDF Download
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Author: Christine L. Maupin
Publisher:
ISBN:
Category :
Languages : en
Pages : 148
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Book Description
Author: Christine L. Maupin
Publisher:
ISBN:
Category :
Languages : en
Pages : 148
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Book Description
Author: J.-C. G. Bünzli
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 456
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Book Description
Lanthanide elements were first used some thirty years ago in the optical glass industry, followed shortly by their use as NMR shift reagents in organic chemistry. Since then, the application of lanthanides in studies of organic and biochemical systems by use of their NMR and spectroscopic properties has created a rapidly growing interest in the physics and chemistry of these elements. Their use in industrial catalysts, electronic and optical components, high-temperature superconductors, in medicine as X-ray intensifying materials, relaxation agents for imaging techniques or radioisotopes for pharmaceutical applications, have combined with their utilisation in science as probes of a wide variety of phenomena giving them a prominent place in modern science. In this book, leading experts describe the various facets of the application of lanthanides as probes in life, chemical and earth sciences. The aim is to provide guidance to scientists who may wish to use the unique advantages of lanthanide probes in their own fields.To supplement the chapters on the basic concepts of the application of lanthanides, chapters are provided on the basic chemistry of these elements and on the synthetic and analytical aspects of lanthanides and their compounds. The book thus provides a great deal of useful information which will no doubt assist scientists in using these fascinating and valuable elements in their research.
Author: Pekka Hänninen
Publisher: Springer Science & Business Media
ISBN: 3642210236
Category : Science
Languages : en
Pages : 392
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Book Description
Lanthanides have fascinated scientists for more than two centuries now, and since efficient separation techniques were established roughly 50 years ago, they have increasingly found their way into industrial exploitation and our everyday lives. Numerous applications are based on their unique luminescent properties, which are highlighted in this volume. It presents established knowledge about the photophysical basics, relevant lanthanide probes or materials, and describes instrumentation-related aspects including chemical and physical sensors. The uses of lanthanides in bioanalysis and medicine are outlined, such as assays for in vitro diagnostics and research. All chapters were compiled by renowned scientists with a broad audience in mind, providing both beginners in the field and advanced researchers with comprehensive information on on the given subject.
Author: Qianqian Su
Publisher: Frontiers Media SA
ISBN: 2889667723
Category : Science
Languages : en
Pages : 125
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Book Description
Author: Joseph A. Cotruvo
Publisher: Elsevier
ISBN: 0323910858
Category : Science
Languages : en
Pages : 412
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Book Description
Spectrophotometric methods to probe the solution chemistry of lanthanide complexes with macromolecules / Gauthier J.-P. Deblonde -- Determination of affinities of lanthanide-binding proteins using chelator-buffered titrations / Joseph A. Mattocks, Jonathan L. Tirsch, and Joseph A. Cotruvo, Jr. -- Electron paramagnetic resonance of lanthanides / Joseph E. McPeak, Sandra S. Eaton, and Gareth R. Eaton -- Characterization of lanthanoid-binding proteins using NMR spectroscopy / Enrico Ravera, Linda Cerofolini, Marco Fragai, Giacomo Parigi, and Claudio Luchinat -- Macromolecular crystallography for f-element complex characterization / Roger M. Pallares, Korey P. Carter, David Faulkner, and Rebecca J. Abergel -- Infrared spectroscopy probes ion binding geometries / Sean C. Edington, Stephanie Liu, and Carlos R. Baiz -- Predicting lanthanide coordination structures in solution with molecular simulation / David C. Cantu -- Characteristics of Gd(III) spin labels for the study of protein conformations / Angeliki Giannoulis, Yasmin Ben-Ishay, and Daniella Goldfarb - Lanthanide-based resonance energy transfer biosensors for live-cell applications / Ha Pham and Lawrence W. Miller -- 86Y PET imaging / Mariane Le Fur and Peter Caravan -- Aqueous chemistry of the smallest rare earth : Comprehensive characterization of radioactive and non-radioactive scandium complexes for biological applications / Brett A. Vaughn, Angus J. Koller, and Eszter Boros -- In vitro selection and application of lanthanide-dependent DNAzymes / Po-Jung Jimmy Huang and Juewen Liu.
Author: Ana de Bettencourt-Dias
Publisher: John Wiley & Sons
ISBN: 1118682815
Category : Science
Languages : en
Pages : 408
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Book Description
This comprehensive book presents the theoretical principles, current applications and latest research developments in the field of luminescent lanthanide complexes; a rapidly developing area of research which is attracting increasing interest amongst the scientific community. Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials begins with an introduction to the basic theoretical and practical aspects of lanthanide ion luminescence, and the spectroscopic techniques used to evaluate the efficiency of luminescence. Subsequent chapters introduce a variety of different applications including: • Circularly polarized luminescence • Luminescence bioimaging with lanthanide complexes • Two-photon absorption of lanthanide complexes • Chemosensors • Upconversion luminescence • Excitation spectroscopy • Heterometallic complexes containing lanthanides Each chapter presents a detailed introduction to the application, followed by a description of experimental techniques specific to the area and an extensive review of recent literature. This book is a valuable introduction to the literature for scientists new to the field, as well as providing the more experienced researcher with a comprehensive resource covering the most relevant information in the field; a ‘one stop shop’ for all key references.
Author: Nina Berova
Publisher: John Wiley & Sons
ISBN: 1118012933
Category : Science
Languages : en
Pages : 824
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Book Description
This book provides an introduction to the important methods of chiroptical spectroscopy in general, and circular dichroism (CD) in particular, which are increasingly important in all areas of chemistry, biochemistry, and structural biology. The book can be used as a text for undergraduate and graduate students and as a reference for researchers in academia and industry, with or without the companion volume in this set. Experimental methods and instrumentation are described with topics ranging from the most widely used methods (electronic and vibrational CD) to frontier areas such as nonlinear spectroscopy and photoelectron CD, as well as the theory of chiroptical methods and techniques for simulating chiroptical properties. Each chapter is written by one or more leading authorities with extensive experience in the field.
Author: Karl A. Gschneidner
Publisher: Elsevier
ISBN: 9780444515872
Category : Juvenile Nonfiction
Languages : en
Pages : 548
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Book Description
This volume of the Handbook adds five new chapters to the science of rare earths. Two of the chapters deal with intermetallic compounds. An overview of ternary systems containing rare earths, transition metals and indium - Chapter 218 - opens the volume. It is followed by Chapter 219 sorting out relationships between superconductivity and magnetism. The next two chapters are dedicated to complex compounds of rare earths: Chapter 220 describes structural studies using circularly polarized luminescence spectroscopy of lanthanide systems, while Chapter 221 examines rare-earth metal-organic frameworks, also known as coordination polymers. The final Chapter 222 deals with the catalytic activity of rare earths in site-selective hydrolysis of DNA and RNA. Ya. Kalychak, V. Zaremba, R. Pöttgen, M. Lukachuk, and R.-D. Hoffmann review the synthesis conditions, isothermal sections of phase diagrams, crystallography and basic physical properties of ternary intermetallic compounds consisting of the rare-earth metals, transition metals and indium. P. Thalmeier and G. Zwicknagl revisit the last decade of research uncovering some of the mysteries of the superconducting state, especially those related to heavy fermion superconductivity and the co-existence of the superconducting and exotic magnetically ordered states. J. P. Riehl and G. Muller review how the molecular stereochemistry of lanthanide complexes both in pure forms and in mixtures can be probed using circularly polarized luminescence. O. Guillou and C. Daiguebonne assess rare earth-containing metal-organic frameworks, also known as coordination polymers, which hold a potential as working bodies for opto-electronic and magnetic devices, microporous materials for a variety of uses, such as size- and shape-selective separations, catalyst support and hydrogen storage materials. Concluding the volume, M. Komiyama argues that future biotechnology may well rely on the use of rare-earth ions as unique catalysts that can slice DNA and RNA in order to allow their reprogramming, and thus lead to more effective bioengineered processes.
Author: Joseph R. Lakowicz
Publisher: Springer Science & Business Media
ISBN: 146157658X
Category : Science
Languages : en
Pages : 487
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Book Description
Fluorescence methods are being used increasingly in biochemical, medical, and chemical research. This is because of the inherent sensitivity of this technique. and the favorable time scale of the phenomenon of fluorescence. 8 Fluorescence emission occurs about 10- sec (10 nsec) after light absorp tion. During this period of time a wide range of molecular processes can occur, and these can effect the spectral characteristics of the fluorescent compound. This combination of sensitivity and a favorable time scale allows fluorescence methods to be generally useful for studies of proteins and membranes and their interactions with other macromolecules. This book describes the fundamental aspects of fluorescence. and the biochemical applications of this methodology. Each chapter starts with the -theoreticalbasis of each phenomenon of fluorescence, followed by examples which illustrate the use of the phenomenon in the study of biochemical problems. The book contains numerous figures. It is felt that such graphical presentations contribute to pleasurable reading and increased understand ing. Separate chapters are devoted to fluorescence polarization, lifetimes, quenching, energy transfer, solvent effects, and excited state reactions. To enhance the usefulness of this work as a textbook, problems are included which illustrate the concepts described in each chapter. Furthermore, a separate chapter is devoted to the instrumentation used in fluorescence spectroscopy. This chapter will be especially valuable for those perform ing or contemplating fluorescence measurements. Such measurements are easily compromised by failure to consider a number of simple principles.
Author: Helen C. Aspinall
Publisher: Routledge
ISBN: 135146115X
Category : Science
Languages : en
Pages : 176
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Book Description
Visual Spatial Enquiry explores visual and textual ways of working within spatial research. Architects and spatial thinkers from the arts, social sciences and humanities present rich case studies from remote and regional settings in Australia to the suburbs of Los Angeles, and from gallery and university settings to community collaborations in Mongolia. Through these case studies the authors reappraise and reconsider research approaches, methods and processes within and across their fields. In spatial research diagramming can be used as a method to synthesise complex concepts into a succinct picture, whereas metaphors can add the richness of lived experiences. Drawing on the editors' own architectural backgrounds, this volume is organised into three key themes: seeing, doing and making space. In seeing space chapters consider observational research enquiries where developing empathy for the context and topic is as important as gathering concrete data. Doing space explores generative opportunities that inform new and innovative propositions, and making space looks at ways to rethink and reshape spatial and relational settings. Through this volume Creagh and McGann invite readers to find their own understandings of the value and practices of neighbouring fields including planning, geography, ethnography, architecture and art. This exploration will be of value to researchers looking to develop their cross-disciplinary literacy, and to design practitioners looking to enhance and articulate their research skills.
