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Author: Avinash Kumar
Publisher: Springer Nature
ISBN: 3031132807
Category : Science
Languages : en
Pages : 135
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Book Description
The thesis presents a systematic study of the Mpemba effect in a colloidal system with a micron-sized particle diffusing in a water bath. While the Mpemba effect, where a system’s thermal relaxation time is a non-monotonic function of the initial temperature, has been observed in water since Aristotle’s era, the underlying mechanism of the effect is still unknown. Recent studies indicate that the effect is not limited to water and has been studied both experimentally and numerically in a wide variety of systems. By carefully designing a double-well potential using feedback-based optical tweezers, the author demonstrates that an initially hot system can sometimes cool faster than an initially warm system. The author also presents the first observation in any system of another counterintuitive effect—the inverse Mpemba effect—where the colder of the two samples reaches the thermal equilibrium at a hot temperature first. The results for both the observations agree with theoretical predictions based on the Fokker-Planck equation. The experiments reveal that, for carefully chosen conditions, a strong version of both of the effects are observed where a system can relax to the bath temperature exponentially faster than under typical conditions.
Author: Avinash Kumar
Publisher: Springer Nature
ISBN: 3031132807
Category : Science
Languages : en
Pages : 135
Get Book Here
Book Description
The thesis presents a systematic study of the Mpemba effect in a colloidal system with a micron-sized particle diffusing in a water bath. While the Mpemba effect, where a system’s thermal relaxation time is a non-monotonic function of the initial temperature, has been observed in water since Aristotle’s era, the underlying mechanism of the effect is still unknown. Recent studies indicate that the effect is not limited to water and has been studied both experimentally and numerically in a wide variety of systems. By carefully designing a double-well potential using feedback-based optical tweezers, the author demonstrates that an initially hot system can sometimes cool faster than an initially warm system. The author also presents the first observation in any system of another counterintuitive effect—the inverse Mpemba effect—where the colder of the two samples reaches the thermal equilibrium at a hot temperature first. The results for both the observations agree with theoretical predictions based on the Fokker-Planck equation. The experiments reveal that, for carefully chosen conditions, a strong version of both of the effects are observed where a system can relax to the bath temperature exponentially faster than under typical conditions.
Author: Avināśa Kumāra
Publisher:
ISBN: 9788303113283
Category : Colloids
Languages : en
Pages : 0
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Book Description
The thesis presents a systematic study of the Mpemba effect in a colloidal system with a micron-sized particle diffusing in a water bath. While the Mpemba effect, where a system's thermal relaxation time is a non-monotonic function of the initial temperature, has been observed in water since Aristotle's era, the underlying mechanism of the effect is still unknown. Recent studies indicate that the effect is not limited to water and has been studied both experimentally and numerically in a wide variety of systems. By carefully designing a double-well potential using feedback-based optical tweezers, the author demonstrates that an initially hot system can sometimes cool faster than an initially warm system. The author also presents the first observation in any system of another counterintuitive effect-the inverse Mpemba effect-where the colder of the two samples reaches the thermal equilibrium at a hot temperature first. The results for both the observations agree with theoretical predictions based on the Fokker-Planck equation. The experiments reveal that, for carefully chosen conditions, a strong version of both of the effects are observed where a system can relax to the bath temperature exponentially faster than under typical conditions.
Author: Vladimir Vasilʹevich Uchaĭkin
Publisher: World Scientific
ISBN: 9814355429
Category : Mathematics
Languages : en
Pages : 274
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Book Description
The standard (Markovian) transport model based on the Boltzmann equation cannot describe some non-equilibrium processes called anomalous that take place in many disordered solids. Causes of anomality lie in non-uniformly scaled (fractal) spatial heterogeneities, in which particle trajectories take cluster form. Furthermore, particles can be located in some domains of small sizes (traps) for a long time. Estimations show that path length and waiting time distributions are often characterized by heavy tails of the power law type. This behavior allows the introduction of time and space derivatives of fractional orders. Distinction of path length distribution from exponential is interpreted as a consequence of media fractality, and analogous property of waiting time distribution as a presence of memory. In this book, a novel approach using equations with derivatives of fractional orders is applied to describe anomalous transport and relaxation in disordered semiconductors, dielectrics and quantum dot systems. A relationship between the self-similarity of transport, the Levy stable limiting distributions and the kinetic equations with fractional derivatives is established. It is shown that unlike the well-known Scher Montroll and Arkhipov Rudenko models, which are in a sense alternatives to the normal transport model, fractional differential equations provide a unified mathematical framework for describing normal and dispersive transport. The fractional differential formalism allows the equations of bipolar transport to be written down and transport in distributed dispersion systems to be described. The relationship between fractional transport equations and the generalized limit theorem reveals the probabilistic aspects of the phenomenon in which a dispersive to Gaussian transport transition occurs in a time-of-flight experiment as the applied voltage is decreased and/or the sample thickness increased. Recent experiments devoted to studies of transport in quantum dot arrays are discussed in the framework of dispersive transport models. The memory phenomena in systems under consideration are discussed in the analysis of fractional equations. It is shown that the approach based on the anomalous transport models and the fractional kinetic equations may be very useful in some problems that involve nano-sized systems. These are photon counting statistics of blinking single quantum dot fluorescence, relaxation of current in colloidal quantum dot arrays, and some others.
Author: Alberto Fernandez-Nieves
Publisher: John Wiley & Sons
ISBN: 3527633014
Category : Science
Languages : en
Pages : 475
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Book Description
Providing a vital link between chemistry and physics on the nanoscale, this book offers concise coverage of the entire topic in five major sections, beginning with synthesis of microgel particles and continuing with their physical properties. The phase behavior and dynamics of resulting microgel suspensions feature in the third section, followed by their mechanical properties. It concludes with detailed accounts of numerous industrial, commercial and medical applications. Edited by David Weitz, Professor at Harvard and one of the world's pre-eminent experts in the field.
Author: Roque Hidalgo-Alvarez
Publisher: CRC Press
ISBN: 142008447X
Category : Science
Languages : en
Pages : 506
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Book Description
Integrating fundamental research with the technical applications of this rapidly evolving field, Structure and Functional Properties of Colloidal Systems clearly presents the connections between structure and functional aspects in colloid and interface science. It explores the physical fundamentals of colloid science, new developments of synthesis
Author: J.K.G. Dhont
Publisher: Elsevier
ISBN: 0080535070
Category : Science
Languages : en
Pages : 661
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Book Description
One of the few textbooks in the field, this volume deals with several aspects of the dynamics of colloids. A self-contained treatise, it fills the gap between research literature and existing books for graduate students and researchers. For readers with a background in chemistry, the first chapter contains a section on frequently used mathematical techniques, as well as statistical mechanics.Some of the topics covered include:• diffusion of free particles on the basis of the Langevin equation•the separation of time, length and angular scales;• the fundamental Fokker-Planck and Smoluchowski equations derived for interacting particles• friction of spheres and rods, and hydrodynamic interaction of spheres (including three body interactions)• diffusion, sedimentation, critical phenomena and phase separation kinetics• experimental light scattering results.For universities and research departments in industry this textbook makes vital reading.
Author: G A Webb
Publisher: Royal Society of Chemistry
ISBN: 1847555233
Category : Science
Languages : en
Pages : 587
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Book Description
As a spectroscopic method, nuclear magnetic resonance (NMR) has seen spectacular growth, both as a technique and in its applications. Today's applications of NMR span a wide range of scientific disciplines, from physics to biology to medicine. Each volume of Nuclear Magnetic Resonance comprises a combination of annual and biennial reports which together provide comprehensive coverage of the literature on this topic. This Specialist Periodical Report reflects the growing volume of published work involving NMR techniques and applications, in particular NMR of natural macromolecules, which is covered in two reports: NMR of Proteins and Nucleic Acids; and NMR of Carbohydrates, Lipids and Membranes. For those wanting to become rapidly acquainted with specific areas of NMR, Nuclear Magnetic Resonance provides unrivalled scope of coverage. Seasoned practitioners of NMR will find this an invaluable source of current methods and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Author: Felix Franks
Publisher: Springer Science & Business Media
ISBN: 147576961X
Category : Science
Languages : en
Pages : 379
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Book Description
This volume is the last in the series comprising "Water-A Comprehensive Treatise. " It was originally planned to combine aqueous solutions of macro molecules and disperse systems in one volume, but largely because of the extensive coverage required by recent developments in aqueous solutions of proteins and synthetic polymers I decided to separate topics dealing with water in disperse systems. The systems treated in the present volume are of a complex nature so that the theoretical frameworks established earlier in Volume 1 and utilized in Volumes 2 and 3 cannot at the present time be applied. On the other hand the systems discussed in Volumes 4 and 5 in particular, border on the many biological and technological areas where important attributes are related to the common factor-water. Included among such diverse problem areas are food processing and preservation, cryopreservation, paper and textile finishing, membrane processes, hemodynamics, etc. It is to be hoped that in days to come some of the results and principles discussed in these five volumes can be applied to improve our understanding of the complex in teractions in medically and industrially important spheres of scientific ac tivity. An age seems to have passed since the concept of creating this treatise was first discussed, and since work began on Volume 1, much has happened in the science of Water; some of the recent developments were highlighted at this year's Gordon Research Conference in Plymouth, N. H.
Author: Carmen Miguel
Publisher: Springer Science & Business Media
ISBN: 3540300287
Category : Science
Languages : en
Pages : 221
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Book Description
This collection of ten tutorial reviews by leading researchers in the field introduces and renews recent advances on irreversible deformation phenomena in solid state and soft condensed matter physics. The focus in applications is on amorphous materials, crystalline solids under stress and, more generally, elastic manifolds driven by external processes. This book addresses in particular nonspecialists and graduate students wishing to enter the field.
Author:
Publisher: Royal Society of Chemistry
ISBN:
Category : Science
Languages : en
Pages : 444
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Book Description
Recent developments in the multi-disciplinary field of colloidal systems are discussed. The topics considered include: * Long-lived non-equilibrium states; colloidal aggregates, glasses, and gels * Relaxation to equilibrium; phase transition kinetics; ageing * The effects of shear and other external fields; rheology * Hydrodynamic interactions; diffusion * The construction of specific colloidal structures by depletion forces, templating, and laser tweezers (assisted self assembly). Faraday Discussions documents a long-established series of Faraday Discussion meetings which provide a unique international forum for the exchange of views and newly acquired results in developing areas of physical chemistry, biophysical chemistry and chemical physics. The papers presented are published in the Faraday Discussion volume together with a record of the discussion contributions made at the meeting. Faraday Discussions therefore provide an important record of current international knowledge and views in the field concerned.
