Ammonia Conversion and NOx Formation in Laminar Coflowing Nonpremixed Methane-air Flames PDF Download
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Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
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Book Description
This paper reports on a combined experimental and modeling investigation of NOx formation in nitrogen-diluted laminar methane diffusion flames seeded with ammonia. The methane-ammonia mixture is a surrogate for biomass fuels which contain significant fuel-bound nitrogen. The experiments use flue-gas sampling to measure the concentration of stable species in the exhaust gas, including NO, O2, CO, and CO2. The computations evolve a two-dimensional low Mach number model using a solution-adaptive projection algorithm to capture fine-scale features of the flame. The model includes detailed thermodynamics and chemical kinetics, differential diffusion, buoyancy, and radiative losses. The model shows good agreement with the measurements over the full range of experimental NH3 seeding amounts. As more NH3 is added, a greater percentage is converted to N2 rather than to NO. The simulation results are further analyzed to trace the changes in NO formation mechanisms with increasing amounts of ammonia in the fuel.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 5
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Book Description
This paper reports on a combined experimental and modeling investigation of NOx formation in nitrogen-diluted laminar methane diffusion flames seeded with ammonia. The methane-ammonia mixture is a surrogate for biomass fuels which contain significant fuel-bound nitrogen. The experiments use flue-gas sampling to measure the concentration of stable species in the exhaust gas, including NO, O2, CO, and CO2. The computations evolve a two-dimensional low Mach number model using a solution-adaptive projection algorithm to capture fine-scale features of the flame. The model includes detailed thermodynamics and chemical kinetics, differential diffusion, buoyancy, and radiative losses. The model shows good agreement with the measurements over the full range of experimental NH3 seeding amounts. As more NH3 is added, a greater percentage is converted to N2 rather than to NO. The simulation results are further analyzed to trace the changes in NO formation mechanisms with increasing amounts of ammonia in the fuel.
Author: Medhat A. Nemitallah
Publisher: Springer Nature
ISBN: 303044077X
Category : Technology & Engineering
Languages : en
Pages : 426
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Book Description
This book focuses on the development of novel combustion approaches and burner designs for clean power generation in gas turbines. It shows the reader how to control the release of pollutants to the environment in an effort to reduce global warming. After an introduction to global warming issues and clean power production for gas turbine applications, subsequent chapters address premixed combustion, burner designs for clean power generation, gas turbine performance, and insights on gas turbine operability. Given its scope, the book can be used as a textbook for graduate-level courses on clean combustion, or as a reference book to accompany compact courses for mechanical engineers and young researchers around the world.
Author: Jun Li
Publisher: Frontiers Media SA
ISBN: 2832503454
Category : Technology & Engineering
Languages : en
Pages : 119
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Book Description
Author: Cameron Tropea
Publisher: Springer Science & Business Media
ISBN: 3540251413
Category : Science
Languages : en
Pages : 1570
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Book Description
Accompanying DVD-ROM contains ... "all chapters of the Springer Handbook."--Page 3 of cover.
Author: V. I. Naoumov
Publisher: Cambridge University Press
ISBN: 1108427049
Category : Science
Languages : en
Pages : 449
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Book Description
Introduces advanced mathematical tools for the modeling, simulation, and analysis of chemical non-equilibrium phenomena in combustion and flows, following a detailed explanation of the basics of thermodynamics and chemical kinetics of reactive mixtures. Researchers, practitioners, lecturers, and graduate students will find this work valuable.
Author: Robert J. Kee
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 896
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Book Description
Table of contents
Author: Howard G. Maahs
Publisher:
ISBN:
Category : Combustion
Languages : en
Pages : 62
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Book Description
Author: W. C. Jr. Gardiner
Publisher: Springer Science & Business Media
ISBN: 1468401866
Category : Science
Languages : en
Pages : 515
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Book Description
Detailed study of the rates and mechanisms of combustion reactions has not been in the mainstream of combustion research until the recent recognition that further progress in optimizing burner performance and reducing pollutant emission can only be done with fundamental understanding of combustion chemistry. This has become apparent at a time when our understanding of the chemistry, at least of small-molecule combustion, and our ability to model combustion processes on large computers have developed to the point that real confidence can be placed in the results. This book is an introduction for outsiders or beginners as well as a reference work for people already active in the field. Because the spectrum of combustion scientists ranges from chemists with little computing experience to engineers who have had only one college chemistry course, everything needed to bring all kinds of beginners up to the level of current practice in detailed combustion modeling is included. It was a temptation to include critical discussions of modeling results and computer programs that would enable outsiders to start quickly into problem solving. We elected not to do either, because we feel that the former are better put into the primary research literature and that people who are going to do combustion modeling should either write their own programs or collaborate with experts. The only exception to this is in the thermochemical area, where programs have been included to do routine fitting operations. For reference purposes there are tables of thermochemical, transport-property, and rate coefficient data.
Author: Sudarshan Kumar
Publisher: Springer Nature
ISBN: 981970507X
Category :
Languages : en
Pages : 399
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Book Description
Author: Vivek Siwatch
Publisher:
ISBN:
Category :
Languages : en
Pages :
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Book Description
Emissions of oxides of nitrogen (NOx) from combustion devices is a topic of tremendous current importance. The bulk of the review of NOx emissions has been in the field of turbulent jet flames. However laminar jet flames have provided much insight into the relative importance of NOx reaction pathways in non premixed combustion for various flame conditions. The existing models include detailed chemistry kinetics for various species involved in the flame. These detailed models involve very complex integration of hundreds of chemical reactions of various species and their intermediates. Hence such models are highly time consuming and also normally involve heavy computational costs. This work proposes a numerical model to compute the total production of NOx in a non-premixed isolated circular laminar jet flame. The jet consists of the fuel rich inner region and the O2 rich outer region. The model estimates both thermal NOx and prompt NOx assuming single step kinetics for NOx formation and a thin flame model. Further the amount of air entrainment by jet depends upon the Sc number of fuel. The higher the Sc number, the higher is the air entrained which lowers the flame temperature and hence NOx formation. With increasing Sc number, flame volume increases which leads to an increase in the NOx formation. The effect of the Sc number variation on the net production of NOx and flame structure is also investigated. The effect of equilibrium chemistry for CO2 - CO + 1/2 O2 and H2O - H2 +1/2 O2 on total NOx emission is studied. Also the effect of both CO2 and H2O equilibrium is considered simultaneously and the net NOx formation for propane is 45 ppm. The splitbetween pre-flame and post-flame regions is also investigated. For Propane, 96% of NOx emissions occur in the pre-flame region and about 4% in the post-flame region. The model predictions are compared with experimental values of NOx missions reported elsewhere.
